Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Benzophenone purity standard substance and preparation method thereof

A technology for reference material and benzophenone, applied in the field of benzophenone purity reference material and its preparation, can solve the problems of differences in delivery, difficulty in arbitration of disputed data, and difficulty in data comparison, etc., to improve the consistency of comparison , fill in the research gap, reduce the effect of uncertainty

Active Publication Date: 2021-02-02
ZHENGZHOU TOBACCO RES INST OF CNTC
View PDF11 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Photoinitiator content in paper packaging materials can be tested by applying relevant method standards for photoinitiator content testing, but due to the lack of a unified and traceable standard substance as a reference, there are the following problems: (1) Directly affect photoinitiator content. The accuracy of the initiator content makes it difficult to compare the data obtained by different units, which leads to differences between the supply and demand sides in the delivery of materials; (2) From the perspective of quality monitoring of production enterprises, due to the lack of standard substances, the data fluctuates greatly. It is difficult to conduct long-term horizontal comparisons of the content levels in products, thereby making it difficult to guide process adjustments; (3) due to the authenticity of the standard substance, it is difficult to trace the test data, and it is difficult to arbitrate disputed data; (4) for the purchaser, it is impossible Comprehensively assess and evaluate the level of photoinitiator content in the products supplied by different suppliers
[0004] So far, there is no precedent for the development of photoinitiator standard materials in China, and there are no reports on the development of such standard materials abroad, and the development of photoinitiator standard materials is in a blank state.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Benzophenone purity standard substance and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] (1) Purchase the crude product of benzophenone from the market, take 50 grams of acetonitrile to make a nearly saturated solution, and prepare sample crystals by freezing and crystallization. Cool down to -18°C at a rate of / h and keep for 48 hours. Select the single crystal particles generated in it, and make a total of about 20 grams of pure product batch by batch; dissolve it in acetonitrile, add 20-100 micrograms of BHT stabilizer at the same time, and obtain a pure product with uniform content after removing the solvent by rotary evaporation; in powder form , weighed under nitrogen protection, packed into brown storage bottles, and prepared 200 bottles in one batch;

[0026] (2) Determination and uncertainty evaluation of pure benzophenone; determine the evaporation residue a of each pure product according to GB / T 9740-2008 "General Method for Determination of Evaporation Residue of Chemical Reagents"; according to GB / T 6283 "Chemical Determination of moisture con...

Embodiment 2

[0047] (1) Purchase the crude product of benzophenone from the market, take 50 grams of ethyl acetate to make a nearly saturated solution, and prepare sample crystals by freezing and crystallization. The specific conditions are: keep the refrigerator at 10°C for 2 hours, Cool at a rate of 0.2°C / h to -18°C and keep for 48 hours. Select the single crystal particles generated in it, and make a total of about 20 grams of pure products batch by batch; dissolve them in ethyl acetate, add 20-100 micrograms of BHT stabilizer at the same time, and obtain pure products with uniform content after removing the solvent by rotary evaporation; Weigh under protection, pack into brown storage bottles, and prepare 200 bottles in one batch;

[0048] (2) Determination and uncertainty evaluation of pure benzophenone; with embodiment 1.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a benzophenone purity reference material and a preparation method thereof, and relates to analysis and test of a photoinitiator used in various packaging materials, wherein thebenzophenone purity reference material can be used as a reference material in food packaging, cigarette packaging, workshop air detection and other tests. The preparation method of the benzophenone purity reference material comprises the following steps: (1) purification of a crude product of benzophenone; and (2) evaluation of a certified value and uncertainty of the benzophenone purity reference material. The benzophenone purity reference material provided by the invention has good stability under a storage condition of 0 DEG C, accurate certificating method, reliable traceability and relatively small synthesis uncertainty (0.1%-0.3%), can solve a problem that a current test method cannot trace a quantity value, can improve comparison consistency of test results of various units, and fills a blank of development of the benzophenone purity reference material at home and abroad.

Description

technical field [0001] The present invention relates to the technical field of measuring and testing standard value transfer, specifically, the present invention relates to a standard substance of benzophenone purity used in various packaging materials and a preparation method thereof, which can be used as food packaging, cigarette case packaging, Standard substances in workshop air monitoring and other tests. Background technique [0002] UV printing is a printing process that dries and cures ink by ultraviolet light. It needs to match ink containing photoinitiator with UV curing lamp. At present, this process is widely used in the printing of paper packaging materials. Studies in recent years have found that after the ink is cured, the residual photoinitiator will migrate under certain conditions, which will bring safety risks to the packaging materials and cause potential harm to human health. In 2007, in the European Union's "Res AP (2002) resolution 1 of some member s...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): G01N1/28G01N30/06G01N30/78
CPCG01N1/28G01N30/06G01N30/78
Inventor 牛佳佳范黎陈连芳陈宸
Owner ZHENGZHOU TOBACCO RES INST OF CNTC
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products