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Lithium ion battery self-discharging screening method

A technology of lithium-ion battery and screening method, applied in the field of self-discharge screening of lithium-ion batteries, can solve the problems of low selection accuracy of defective cells, long self-discharge selection cycle, failure to select self-discharge, etc., so as to reduce customer complaints Risk, shortened delivery cycle, and the effect of shortened screening cycle

Active Publication Date: 2018-10-19
HUIZHOU TOPBAND ELECTRICAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Self-discharge is one of the main parameters to measure battery performance. After strict control of the manufacturing process, it is found that the current conventional self-discharge selection method is to use SOC (Sate of Charge, remaining power) as the selection standard of 50%, and the use of this Selection method In the actual production line selection process, the qualified rate of self-discharge selection is almost 100%, and the bad self-discharge cells cannot be selected.
[0003] Or select with the standard △V, and select with the standard △V, the selection accuracy of the bad cells in mass production is less
[0004] In addition, the existing self-discharge selection cycle is too long, resulting in low production capacity, low efficiency, high cost, and also affects the product delivery cycle

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0068] Take the C1865135E-12Ah lithium iron phosphate square cell as an example.

[0069] The existing self-discharge screening SOC standard is 50%, and the self-discharge SOC standard adopted in the present invention is 5%-15%. When using the self-discharge screening SOC standard is 50%, such as figure 2 As shown in the B curve,

[0070] Poor self-discharge screening is based on voltage drop screening, that is, the voltage drop △V will increase with the increase of the capacity C consumed by self-discharge. However, due to the relatively flat discharge platform of lithium iron phosphate batteries, the change in △V with the increase of C is not large at the stage when the remaining SOC is 15%-90%, and it is not easy to select bad batteries; At the stage of 5%-15%, the change of △V is relatively obvious with the increase of C, such as Figure 1 As shown in the middle A curve; but in the area of ​​SOC<5%, the change of △V is too obvious, and it is easy to misjudge the good b...

Embodiment 2

[0073] Take the C1865135E-12Ah lithium iron phosphate square cell as an example.

[0074] The present invention is as follows: after the primary capacity division of the battery to be tested is completed, the value of the first open circuit voltage V1 of the test OCV1 (namely the first open circuit voltage V1) is: 3.180V-3.230V. The preset aging process is: stand at a high temperature of 45°C±3°C for 3 days, and at the same time stand at a normal temperature of 25°C±3°C for 1 day (24h), test OCV2 (that is, the second open circuit voltage V2), the second open circuit voltage The value of V2 is: 3.180V-3.230V.

[0075] The existing scheme is: stand at room temperature for 15 days.

[0076] After comparing the two batteries, the test results are as follows: image 3 shown.

[0077] Depend on image 3 It can be seen from the figure that the second open circuit voltage OCV2 after standing for 3 days at 45°C±3°C and 1 day at room temperature 25°C±3°C has little correlation with ...

Embodiment 3

[0080] Take the C1865135E-12Ah lithium iron phosphate square cell as an example.

[0081] The present invention adopts the K method to screen the self-discharge of the battery to be tested. Wherein, the value of K is: 0-5mV / d (millivolts / day). The existing scheme is to use the △V method to screen. The two are compared and tested, and the test results are as follows Figure 4 shown.

[0082] Depend on Figure 4 It can be seen from the figure that from the point of view of the concentration of voltage distribution, the concentration of constant voltage charging voltage is higher than that of constant current charging. It shows that the pass-through rate of self-discharge screened by the K value method is much higher than that screened by the △V method. That is, using K value to screen self-discharge can improve the accuracy of defective product selection.

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Abstract

The invention relates to a lithium ion battery self-discharging screening method. The lithium ion battery self-discharging screening method comprises the following steps: S1, performing first-time voltage test on to-be-tested batteries according to a first test standard and screening out the to-be-tested batteries meeting the first test standard; S2, ageing the to-be-tested batteries meeting the first test standard by a preset ageing process; S3, performing second-time voltage test on the to-be-tested batteries aged by the preset ageing process according to a second test standard and screeningout the to-be-tested batteries meeting the second test standard; S4, screening the to-be-tested batteries meeting the second test standard and screening out the to-be-tested batteries with self-discharging SOC being 5 to 15 percent; and S5, screening the to-be-tested batteries with the self-discharging SOC being 5 to 15 percent by a K value method and screening out the to-be-tested batteries meeting the K value. By the method, the self-discharging screening cycle can be effectively shortened, the productivity is improved, the cost is further reduced, the efficiency is high and the accuracy degree is high; furthermore, the quality of products can be improved and the customer complaint risk can be reduced; meanwhile, the delivery cycle of the products can be shortened.

Description

technical field [0001] The invention relates to the field of batteries, more specifically, to a screening method for self-discharge of lithium-ion batteries. Background technique [0002] Self-discharge, also known as charge retention capacity, refers to the ability to maintain the stored power of a battery under certain environmental conditions in an open circuit state. Generally speaking, self-discharge is mainly affected by manufacturing process, materials, and storage conditions. Self-discharge is one of the main parameters to measure battery performance. After strict control of the manufacturing process, it is found that the current conventional self-discharge selection method is to use SOC (Sate of Charge, remaining power) as the selection standard of 50%. Selection method In the actual production line selection process, the qualified rate of self-discharge selection is almost 100%, and the bad self-discharge cells cannot be selected. [0003] Or select with the stan...

Claims

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Application Information

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IPC IPC(8): H01M10/42H01M10/0525
CPCH01M10/0525H01M10/4285Y02E60/10
Inventor 余志文
Owner HUIZHOU TOPBAND ELECTRICAL TECH CO LTD
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