Electrolyte and lithium ion battery containing the electrolyte and/or positive electrode
An electrolyte and cathode technology, applied in battery electrodes, secondary batteries, organic electrolytes, etc., can solve the problems of high viscosity, excessive consumption of electrolyte solvent, low conductivity, etc., and achieve the effect of prolonging life.
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[0034] The preparation method of the lithium-ion battery electrolyte provided by the present invention is a common method for those skilled in the art, that is, to mix the components (including lithium salt, electrolyte solvent and additives) uniformly, and the mixing method and sequence of the present invention None of them are particularly limited.
[0035] The electrolyte additive of the present invention may also contain other substances, such as other types of functional additives, which are not limited in the present invention.
[0036] The present invention also provides a lithium-ion battery, comprising a casing, an electric core contained in the casing, and an electrolyte, the electric core includes a positive electrode, a negative electrode, and a separator between the positive electrode and the negative electrode, wherein the electrolyte is The electrolyte solution and / or the positive electrode provided by the present invention is the positive electrode provided by th...
Embodiment 1
[0042] (1) Preparation of electrolyte:
[0043] In an argon glove box, ethylene carbonate (EC), diethyl carbonate (DEC), 12% by weight lithium hexafluorophosphate (LiPF 6 ) is dissolved in 100% by weight of the electrolyte solvent, and then 0.1% by weight of 2-chlorobenzothiazole (the benzothiazole of the structure shown in the application formula (1), wherein R is -Cl) is added to obtain this The lithium ion battery electrolyte of embodiment is denoted as C1;
[0044] (2) Preparation of lithium ion battery:
[0045] The positive active material (LiNi 0.5 mn 1.5 o 4 ), acetylene black, and polyvinylidene fluoride in a ratio of 90:5:5 and then pressed on the aluminum foil to obtain the positive electrode sheet; the metal lithium sheet was used as the negative electrode sheet; the PE / PP composite diaphragm was used as the ion exchange membrane. The electrolyte C1 of the example is made into a button battery S1 by a conventional method in the art.
Embodiment 2
[0047] Adopt the same steps as in Example 1 to prepare electrolyte and button cell, the difference is: in step (1), replace 2-chlorobenzothiazole with 2-aminobenzothiazole of 3% by weight, and prepare lithium ion Battery electrolyte C2 and button cell S2.
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