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Preparation method of hydrophilic anti-pollution plant particle blended membrane

A plant particle and anti-pollution technology, applied in the direction of chemical instruments and methods, membranes, membrane technology, etc., can solve the problems of complex preparation process of organic hydrophilic macromolecules, harm and limitation of inorganic particles to human body, etc., and achieve good hydrophilic anti-pollution Pollution performance, easy industrial implementation, and low equipment requirements

Inactive Publication Date: 2018-11-06
FUZHOU UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, inorganic nanoparticles are easy to agglomerate during the blending process, and the escaped inorganic particles are harmful to the human body, and the preparation process of organic hydrophilic macromolecules is complicated, which limits the application of these technologies to a certain extent.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] 1) Preparation of plant granules: Boil papaya stems and leaves in boiling water for 2 hours, filter to remove impurities, dry at 80°C, crush the plants with a mixer, sieve out 100-mesh granules with a standard inspection sieve, filter, wash and dry to obtain spare plant granules ;

[0022] 2) Preparation of plant particle blend film: Dissolve 1.9 g of polyvinylidene fluoride powder in a mixture of 12.5 mL of dimethylacetamide and 1.3 g of polyvinylpyrrolidone, add 0.1 g of 100-mesh plant particles, and stir evenly at 70 °C , the solution was defoamed, the film was scraped at 60°C, the solvent was removed and dried to obtain a plant particle blend film.

[0023] In the comparison experiment, the contact angle between the original PVDF film and water without blending modification reached 89°, and the contact angle between the PVDF film and water after the blending modification in this example dropped to 65°, and the contact angle decreased rapidly with time. Only 20° to ...

Embodiment 2

[0025] 1) Preparation of plant granules: Boil palm stems and leaves in boiling water for 3 hours, filter to remove impurities, dry at 80°C, crush the plants with a mixer, sieve out 200-mesh granules with a standard inspection sieve, filter, wash and dry to obtain spare plant granules ;

[0026] 2) Preparation of plant particle blend film: Dissolve 1.9 g of polyvinylidene fluoride powder in a mixture of 12.5 mL of dimethylacetamide and 1.3 g of polyvinylpyrrolidone, add 0.1 g of 200-mesh plant particles, and stir well at 70 °C , the solution was defoamed, the film was scraped at 60°C, the solvent was removed and dried to obtain a plant particle blend film.

[0027] After testing, the contact angle between the PVDF membrane and water dropped to 55° after blending and modification in this example, and the contact angle dropped rapidly with time to only 17° in 150 seconds. Using bovine serum albumin (BSA) as a pollutant, the antifouling performance of the measured membrane is gre...

Embodiment 3

[0029] 1) Preparation of plant granules: Boil longan stems and leaves in boiling water for 3 hours, filter to remove impurities, dry at 80°C, crush the plants with a mixer, sieve out 400-mesh granules with a standard inspection sieve, filter, wash and dry to obtain spare plant granules ;

[0030] 2) Preparation of plant particle blend film: Dissolve 1.9 g of polyvinylidene fluoride powder in a mixture of 12.5 mL of dimethylacetamide and 1.3 g of polyvinylpyrrolidone, add 0.1 g of 400-mesh plant particles, and stir well at 70 °C , the solution was defoamed, the film was scraped at 60°C, the solvent was removed and dried to obtain a plant particle blend film.

[0031] After testing, the contact angle between the PVDF membrane and water dropped to 50° after blending and modification in this example, and the contact angle decreased rapidly with time, to only 15° in 150 seconds. Using bovine serum albumin (BSA) as a pollutant, the antifouling performance of the measured membrane i...

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Abstract

The invention discloses a preparation method of a hydrophilic anti-pollution plant particle blended membrane and belongs to the field of polymer modification. The method comprises the steps of preparing plant particles with different sizes, blending the plant particles and polyvinylidene fluoride, and preparing the hydrophilic anti-pollution plant particle blended membrane by an immersion precipitation phase inversion technology. The preparation method is green, environmentally friendly, simple in technology, easy in operation and industrial implementation and has low equipment requirements; the prepared hydrophilic anti-pollution plant particle blended membrane has good hydrophilic and anti-pollution performance; and permeability of the membrane can be greatly improved.

Description

technical field [0001] The invention relates to a preparation method of a hydrophilic anti-pollution plant particle blend film, belonging to the field of polymer modification. Background technique [0002] Polyvinylidene fluoride (PVDF) is a commonly used film-forming material for synthetic polymer films, which has good mechanical properties, thermal stability, solvent resistance, and microbial corrosion resistance. However, due to its low surface energy and strong hydrophobic nature, its anti-fouling and biocompatibility are poor, and the polymer porous membrane prepared by it is easy to cause non-specific protein adsorption in practical applications, which limits the versatility of the membrane. aspects of application. There are many modification methods for PVDF membranes, and physical blending modification is one of the most important methods. At present, physical blending modification is mainly divided into two categories: one is to blend inorganic hydrophilic particl...

Claims

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Application Information

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IPC IPC(8): B01D71/34B01D69/02B01D67/00
CPCB01D67/0002B01D69/02B01D71/34B01D2325/36
Inventor 李建华张德彬郑徽张博鑫倪惺惺张其清
Owner FUZHOU UNIVERSITY