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Button type total battery consisting of lithium titanate pole piece and graphite pole piece as well as preparation method of button type total battery

A lithium titanate and full battery technology, which is applied in secondary battery manufacturing, electrolyte battery manufacturing, battery electrodes, etc., can solve the problems of not being able to provide lithium sources, lithium titanate pole pieces and graphite can not be directly made into batteries, etc., to achieve Good high temperature resistance, excellent fast charging performance, and long cycle life

Active Publication Date: 2018-11-13
KEDA (ANHUI) NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, lithium titanate is used as the negative electrode material of the battery; since lithium titanate itself cannot provide lithium source, it can only be matched with electrode materials containing lithium, so lithium titanate pole pieces and graphite cannot be directly made Battery

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] The preparation method of the button-type full battery described in this embodiment comprises the following steps:

[0028] Preparation of lithium titanate pole piece: add lithium titanate, conductive agent, and binder solution into a beaker in a weight ratio of 80:10:10, and add NMP to obtain 5g of a mixed solution. The amount of NMP added is lithium titanate, conductive agent, and 5% to 10% of the total mass of the binder; put the beaker into a high-speed disperser and rotate at a high speed of 2000r / min for 8 minutes; apply the mixed solution evenly on the copper foil with an automatic coater; Put the coated copper foil into the oven and bake at 90°C for 60 minutes; roll the dried pole piece with an electric roller press until the compacted density is 1.1g / cm3; The pressed pole piece was punched with a punching machine to obtain a lithium titanate pole piece with a diameter of 10 mm, and the lithium titanate pole piece was vacuum-dried at 80° C. for 24 hours.

[002...

Embodiment 2

[0034] The preparation method of the button-type full battery described in this embodiment comprises the following steps:

[0035]Preparation of lithium titanate pole piece: add lithium titanate, conductive agent, and binder solution into a beaker in a weight ratio of 83:7:10, and add NMP to obtain 6g of mixed solution. The amount of NMP added is lithium titanate, conductive agent and 10% of the total mass of the binder; put the beaker into a high-speed disperser and rotate at a high speed of 2000r / min for 10 minutes; apply the mixed solution evenly on the copper foil with an automatic coating machine; Put the copper foil in the oven and bake it at 100°C for 70 minutes; roll the dried pole piece with an electric roller press until the compacted density is 1.2g / cm3; The pole piece was punched with a punching machine to obtain a lithium titanate pole piece with a diameter of 11 mm, and the lithium titanate pole piece was vacuum-dried at 100° C. for 36 hours.

[0036] Preparatio...

Embodiment 3

[0041] The preparation method of the button-type full battery described in this embodiment comprises the following steps:

[0042] Preparation of lithium titanate pole piece: Add lithium titanate, conductive agent, and binder solution into a beaker in a weight ratio of 82:8:10, and add NMP to obtain 5g of mixed solution. The amount of NMP added is lithium titanate, conductive agent and 8% of the total mass of the binder; put the beaker into a high-speed disperser, and rotate at a high speed of 1500r / min for 10 minutes; apply the mixed solution evenly on the copper foil with an automatic coating machine; Put the good copper foil into the oven and bake at 80°C for 80 minutes; roll the dried pole pieces with an electric roller press until the compaction density is 1.3g / cm3; The pole piece was punched with a punching machine to obtain a lithium titanate pole piece with a diameter of 12 mm, and the lithium titanate pole piece was vacuum-dried at 100° C. for 48 hours.

[0043] Prep...

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Abstract

The invention discloses a button type total battery consisting of a lithium titanate pole piece and a graphite pole piece as well as a preparation method of the button type total battery. The preparation method of the button type total battery comprises the following steps: preparing the lithium titanate pole piece and the graphite pole piece, and preparing a metal lithium piece; taking the graphite pole piece as a positive pole piece and taking the metal lithium piece as a negative pole piece, assembling a button type total battery I in a glove box and performing discharging treatment; disassembling the button type total battery subjected to discharging treatment to obtain a lithium graphite embedded pole piece, taking the lithium graphite embedded pole piece as a negative pole piece, taking the lithium titanate pole piece as a positive pole piece, and assembling a button type total battery II in the glove box; and performing standing on the button type total battery II to obtain a finished product. Lithium ions are embedded in the graphite pole piece, so that the button type total battery taking the lithium titanate pole piece as the positive pole piece and taking the graphite pole piece as the negative pole piece is obtained; and furthermore, the button type total battery has high safety and stability, excellent rapid charging performance, long cycle life and excellent high-temperature resistance.

Description

technical field [0001] The invention relates to the technical field of batteries, in particular to a button-type full battery composed of lithium titanate pole pieces and graphite pole pieces and a preparation method thereof. Background technique [0002] When lithium titanate batteries are charged and discharged, the intercalation and deintercalation of lithium ions will not cause changes in the crystal structure of lithium titanate, so it has little effect on the structure of lithium titanate materials. Because of this, lithium titanate is also called "zero strain material". Lithium titanate batteries have outstanding advantages compared with the current lithium iron phosphate batteries that can be used for up to 5 years with slow charging and up to 2 years for fast charging. According to the test data, the average cycle life of ordinary batteries is 3,000 times, while the number of full charge and discharge cycles of lithium titanate batteries can reach more than 30,000 ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/131H01M4/133H01M10/058H01M10/04
CPCH01M4/131H01M4/133H01M10/0427H01M10/058Y02E60/10Y02P70/50
Inventor 朱敏付健黄绍丰姜建成张怡
Owner KEDA (ANHUI) NEW MATERIAL CO LTD