A kind of red fluorescent material and preparation method thereof
A technology of red fluorescence and incident light, which is applied in the field of fluorescent materials, can solve the problems of complex preparation methods, low color purity, and high cost, and achieve the effects of simple preparation process, high color purity, and long life
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Embodiment 1
[0024] A kind of fluorescent material that emits red light is made by the following method: 0.156g of 2,5-furandicarboxylic acid and 0.453g of europium nitrate are mixed, then added to 40g of DMSO and ethanol mixed solution (the volume of DMSO and ethanol The ratio is 1:1), and after stirring for 10 minutes, put it in an oven at 120°C for 48 hours, and then cool it, so as to obtain a colorless block crystal, which is the red fluorescent material Eu 3 (FDA) 4 (DMSO) 2 (NO 3 )(H 2 O) 2 .
[0025] Specifically, the selected size is 0.26×0.25×0.23mm 3 The single crystal structure analysis of the fluorescent material was carried out, the single crystal diffraction data was collected by Bruker-AXS SMART APEX2CCD diffractometer, and the Mokα ray monochromated by graphite monochromator ( ), 1.7°≤θ≤25.2°, thus the following results are obtained: the fluorescent material belongs to the monoclinic crystal system, the space group is all C2 / c, and the unit cell parameters are approx...
Embodiment 2
[0027] A kind of fluorescent material that emits red light is made by the following method: 0.312g of 2,5-furandicarboxylic acid and 0.906g of europium nitrate are mixed, then added to 80g of DMSO and ethanol mixed solution (the volume of DMSO and ethanol The ratio is 1:1), and after stirring for 10 minutes, put it in an oven at 120°C for 48 hours, and then cool it, so as to obtain a colorless block crystal, which is the red fluorescent material Eu 3 (FDA) 4 (DMSO) 2 (NO 3 )(H 2 O) 2 .
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