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A dual-energy light-converting glass for promoting plant photosynthesis and preparation method thereof

A photosynthesis and glass technology, applied in glass production and other directions, can solve the problems of environmental pollution, high efficiency absorption of chlorophyll α blue light, application limitations, etc., and achieves simple preparation method, non-radiative energy transfer inhibition, reduction and pesticide use. Effect

Active Publication Date: 2021-05-14
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Because this kind of organic polymer film is easy to cause environmental pollution problems, and only uses the rare earth europium element to convert the ultraviolet band into red light, without considering the efficient absorption of blue light by chlorophyll α and chlorophyll β
Therefore, the application of this fluorescent material in the field of agricultural light-converting materials is limited to a certain extent.

Method used

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  • A dual-energy light-converting glass for promoting plant photosynthesis and preparation method thereof
  • A dual-energy light-converting glass for promoting plant photosynthesis and preparation method thereof
  • A dual-energy light-converting glass for promoting plant photosynthesis and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] (1) Preparation of precursor glass: the molar composition is: SiO 2 :44.875%, Al 2 o 3 :22%, Na 2 O:16%, NaF:9%, YF 3 :8%, Bi 2 o 3 :0.05%, Eu 2 o 3 :0.075%. Take 100g of raw materials and grind them in an agate mortar for 30 minutes to make them fully mixed. Pour the uniformly mixed material into a 200ml corundum crucible, and then put the corundum crucible into a high-temperature furnace. Firstly, the temperature was raised to 1000°C at a rate of 8°C / min, and then to 1550°C at a rate of 5°C / min, and then kept for 1 hour. Then the molten glass is quickly poured into a preheated mold at 250°C, placed in a muffle furnace heated to 500°C for 2.5 hours, and then cooled to below 50°C at a rate of 10°C / h to obtain a precursor Glass.

[0037] (2) Preparation of transparent glass-ceramics: Put the precursor glass in a muffle furnace, raise it from room temperature to 670°C at a rate of 5°C / min and keep it warm for 2 hours to obtain a transparent glass-ceramic, and t...

Embodiment 2

[0040] (1) Preparation of precursor glass: the molar composition is: SiO 2 :33.8%, Al 2 o 3 :24%, Na 2 O:18%, NaF:11%, YF 3 :12%, Yb 2 o 3 :0.5%, Tm2 o 3 : 0.2%, MnO: 0.5%. Take 100g of raw materials and grind them in an agate mortar for 20 minutes to make them fully mixed. Pour the uniformly mixed material into a 200ml corundum crucible, and then put the corundum crucible into a high-temperature furnace. First raise the temperature to 1000°C at a rate of 5°C / min, then raise the temperature to 1400°C at a rate of 3°C / min, and then keep warm for 2 hours. Then the molten glass is quickly poured into a preheated mold at 200°C, placed in a muffle furnace that has been heated to 450°C for 3 hours, and then cooled to below 50°C at a rate of 5°C / h to obtain a precursor glass .

[0041] (2) Preparation of transparent glass-ceramics: Put the precursor glass in a muffle furnace, raise it from room temperature to 650°C at a rate of 3°C / min and keep it warm for 5 hours to obtain...

Embodiment 3

[0044] (1) Preparation of precursor glass: the molar composition is: SiO 2 :50%, Al 2 o 3 :18%, Na 2 O:14%, NaF:7%, YF 3 :10%, Tm 2 o 3 :0.5%, Cr 2 o 3 :0.5%. Take 100g of raw materials and grind them in an agate mortar for 40 minutes to make them fully mixed. Pour the uniformly mixed material into a 200ml corundum crucible, and then put the corundum crucible into a high-temperature furnace. First raise the temperature to 1000°C at a rate of 10°C / min, then raise the temperature to 1600°C at a rate of 4°C / min, and then keep warm for 0.5h. Then the molten glass is quickly poured into a preheated mold at 300°C, placed in a muffle furnace heated to 550°C for 2 hours, and then cooled to below 50°C at a rate of 15°C / h to obtain the precursor glass .

[0045] (2) Preparation of transparent glass-ceramics: Put the precursor glass in a muffle furnace, raise it from room temperature to 700°C at a rate of 4°C / min and keep it warm for 1h to obtain a transparent glass-ceramic, a...

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Abstract

The invention discloses a dual-energy light-converting glass for promoting plant photosynthesis and a preparation method thereof. The molar composition of the raw material is: SiO 2 :33.8~50%, Al 2 o 3 :18~24%, Na 2 O:14~18%, NaF:7~11%, YF 3 :8~12%, Re 2 o 3 :0.05~0.5%, TM 2 o x : 0.05 ~ 0.5%, the Re is a trivalent rare earth ion, and TM is a transition metal ion. The dual-energy light-converting glass for promoting plant photosynthesis of the present invention can promote plant photosynthesis, reduce the use of chemical fertilizers and pesticides, increase crop yields, and is expected to be developed as a green building material for greenhouses.

Description

technical field [0001] The invention relates to the field of solid luminescent materials, in particular to a dual-energy light-converting glass for promoting plant photosynthesis and a preparation method thereof. Background technique [0002] Because chlorophyll has higher absorption efficiency for blue light and red light, it has less absorption for ultraviolet and infrared bands. Therefore, blue light and red light in the solar spectrum have the greatest impact on the photosynthesis of green plants, and are often called the effective spectrum of photosynthesis. [0003] At present, some fluorescent materials doped with luminescent ions have been used to increase the yield and income of crops, convert ultraviolet or green light in sunlight into blue and red light, and improve the photosynthesis efficiency of green plants. Patents CN1105040A, CN1122814A, and CN1132219A disclose the application of rare earth europium organic complexes in agricultural films, and these patent ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C10/16C03B32/02
CPCC03B32/02C03C10/16Y02P40/57
Inventor 董国平蔡振禄康世亮宋晓倩欧阳天昶
Owner SOUTH CHINA UNIV OF TECH