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A kind of manufacturing method of rare earth heat-resistant steel plate

A manufacturing method and technology of heat-resistant steel, applied in the field of rare-earth heat-resistant steel, can solve the problems of large fluctuation of rare-earth content and poor deoxidation effect, and achieve the effects of good surface quality, good internal quality and lower production cost

Active Publication Date: 2020-04-21
LUOYANG SUNRUI SPECIAL EQUIP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The patent "High Performance Corrosion Resistant Rare Earth Super Duplex Stainless Steel and Its Smelting Process" provides a smelting method of rare earth duplex stainless steel (Re≤0.2%), which uses Re-Mg-Ca treatment in the smelting of consumable electrodes molten steel, and use ReO in electroslag remelting 2 :MgO:CaO:CaF 2 :Al 2 o 3 =10%:10%:10%:50%:20% five-element slag system for remelting, and continuously add active Re-Mg-Ca reducing agent to the slag pool evenly during electroslag remelting to control rare earth burning loss, However, judging from the actual smelting effect, the deoxidation effect is not good ([O]=30~50ppm), and the rare earth content in the steel after electroslag fluctuates greatly (Re=0.0096%~0.055%), so it is only suitable for the upper limit requirement of rare earth If it is a steel type that has an upper and lower limit range for rare earths, there will be a great risk

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  • A kind of manufacturing method of rare earth heat-resistant steel plate
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  • A kind of manufacturing method of rare earth heat-resistant steel plate

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Effect test

Embodiment 1

[0043] When the Ce content in the consumable electrode is at the lower limit level (0.10% ~ 0.12%), the production method of the present invention is used to produce the rare earth heat-resistant steel 253MA electroslag slab, comprising the following steps:

[0044] The first step is to use the "8T medium frequency induction furnace + 8TAOD furnace" method to smelt consumable electrodes. In order to achieve full deoxidation of molten steel, 2.0Kg / t of crystalline silicon is added for pre-deoxidation, and then 1.0Kg / t of Al wire is added for deep deoxidation. , adjust the Si in the steel to 1.6% before tapping, control [O] below 30ppm, control the tapping temperature at 1580±10°C, and add 1Kg / t SiAlBaCa alloy (Si35%, Ca10%, Ba10 %, Al12%, Fe balance) deoxidation, and then add rare earth Ce-La alloy to the steel stream according to 2.8Kg / t.

[0045] The electrode specification is 180mm×1170mm×L, and the unit weight is about 6 tons. The chemical composition of the electrode meets...

Embodiment 2

[0060] When the Ce content in the consumable electrode is at the middle limit level (0.125% ~ 0.135%), the production method of the present invention is used to produce the rare earth heat-resistant steel 253MA electroslag slab, comprising the following steps:

[0061] The first step is to use the "8T intermediate frequency induction furnace + 8TAOD" method to smelt the consumable electrode. In order to achieve full deoxidation of molten steel, 2.2Kg / t of crystalline silicon is added for pre-deoxidation, and then 1.2Kg / t of Al wire is added for deep deoxidation. Before tapping, adjust the Si in the steel to 1.65%, [O] is controlled below 30ppm, and the tapping temperature is controlled at 1580±10°C. When tapping, the ladle is first added with 1Kg / t SiAlBaCa alloy for deoxidation, and then according to 2.8Kg / t to Rare earth Ce-La alloy is added to the steel flow.

[0062] The electrode specification is 180mm×1170mm×L, and the unit weight is about 6 tons. The chemical compositio...

Embodiment 3

[0077] When the Ce content in the consumable electrode is at the upper limit level (0.14% ~ 0.15%), the production method of the present invention is used to produce the rare earth heat-resistant steel 253MA electroslag slab, comprising the following steps:

[0078] The first step is to use the "8T intermediate frequency induction furnace + 8TAOD" method to smelt the consumable electrode. In order to achieve full deoxidation of molten steel, 2.3Kg / t of crystalline silicon is added for pre-deoxidation, and then 1.5Kg / t of Al wire is added for deep deoxidation. Before tapping, adjust the Si in the steel to 1.65%, [O] is controlled below 30ppm, and the tapping temperature is controlled at 1580±10°C. When tapping, the ladle is first added with 1Kg / t SiAlBaCa alloy for deoxidation, and then according to 2.8Kg / t to Rare earth Ce-La alloy is added to the steel flow.

[0079] The electrode specification is 180mm×1170mm×L, and the unit weight is about 6 tons. The chemical composition o...

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Abstract

A method for manufacturing rare-earth heat-resistant steel plates. The rare-earth heat-resistant steel is firstly smelted with an intermediate frequency induction furnace and an AOD furnace for self-consumable electrodes, and then undergoes electroslag remelting to obtain qualified electroslag slabs. The slag slab is hot-rolled into a plate of specified specifications. During smelting, the rare earth Ce content in the consumable electrode is controlled at 0.10% to 0.15%. Electroslag remelting is carried out with five-element electroslag system. The rare earth content in the slag remelting process is stable and controllable, and the electroslag remelting slab can be directly fed into the rolling mill to be rolled into a plate. Compared with the production of general-standard steel ingots, not only can the chemical composition of the plates be guaranteed, but also the performance of the products is more excellent due to the improvement of the solidification quality of the electroslag ingots; It shortens the production period and has good economic benefits.

Description

technical field [0001] The invention relates to the technical field of rare-earth heat-resistant steel, in particular to a method for manufacturing a rare-earth heat-resistant steel plate. Background technique [0002] Rare earth elements in steel have many beneficial effects such as purification of molten steel, denaturation of inclusions, grain refinement, microalloying, etc., and can significantly improve the oxidation resistance, high temperature strength and plasticity, fatigue life, corrosion resistance and corrosion resistance of steel. fissure etc. However, rare earth elements are extremely active, and their yield is related to many factors such as the degree of deoxidation of molten steel, the temperature of tapping, and the timing of adding them. Therefore, it is difficult to accurately control the content of rare earth elements. [0003] At present, most rare earth steels only provide the upper limit range of rare earth content, and rare earth is added to steel a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C33/06C22B9/18C21C7/06
CPCC21C7/06C22B9/18C22C33/06Y02P10/25
Inventor 陈帅超罗利阳张春林
Owner LUOYANG SUNRUI SPECIAL EQUIP