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In situ synthesis method for palladium-loaded titanium dioxide base nanometer heterojunction material

A titanium dioxide, in-situ synthesis technology, applied in chemical instruments and methods, metal/metal oxide/metal hydroxide catalysts, chemical/physical processes, etc., can solve the lack of visible light-responsive catalytic materials, photo-generated electrons and holes recombination high photocatalytic activity and stability, low cost, and enhanced visible light absorption

Inactive Publication Date: 2019-01-01
NANTONG UNIVERSITY
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Problems solved by technology

However, the realization of large-scale industrial applications still needs to solve the bottleneck problems of the lack of visible light-responsive catalytic materials and the low photocatalytic efficiency caused by the high recombination rate of photogenerated electrons and holes.
[0003] Titanium dioxide is the best commercial application so far, and it is also a promising photocatalytic material in the future. It has strong photocatalytic redox ability, high stability, resistance to light and chemical corrosion, low cost, reusable, and harmless to the human body. It is non-toxic and environmentally friendly, but it also has the problems of high recombination rate of photogenerated electrons and holes and low utilization rate of visible light

Method used

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  • In situ synthesis method for palladium-loaded titanium dioxide base nanometer heterojunction material
  • In situ synthesis method for palladium-loaded titanium dioxide base nanometer heterojunction material
  • In situ synthesis method for palladium-loaded titanium dioxide base nanometer heterojunction material

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Embodiment Construction

[0020] A method for in-situ synthesis of palladium-loaded titania-based nano-heterojunction materials, comprising the following steps:

[0021] (1) Preparation of blue titanium dioxide:

[0022] Add white titanium dioxide (anatase phase or rutile phase or a mixture of both) and 10%~37% formaldehyde solution into the quartz photocatalytic reactor, ultrasonically disperse, the ratio of titanium dioxide to formaldehyde solution is 0.08~80g / L (that is, titanium dioxide The concentration in the formaldehyde solution is 0.08~80g / L), 250~400W high-pressure mercury lamp or xenon lamp ultraviolet light for 8~30min, the blue titanium dioxide is prepared; the solid is obtained by centrifugation, washed with water and ethanol;

[0023] (2) In situ synthesis of palladium-supported titania-based nano-heterojunction materials

[0024] Add 2~25mmol / L PdCl to the blue titanium dioxide prepared by the above method 2 solution, ultrasonic dispersion, titanium dioxide and PdCl 2 The molar ratio...

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Abstract

The invention discloses an in situ synthesis method for a palladium-loaded titanium dioxide base nanometer heterojunction material. The in situ synthesis method comprises the following steps of the preparation of blue titanium dioxide and the in situ synthesis of the palladium-loaded titanium dioxide base nanometer heterojunction material. By use of the own reducibility of the blue titanium dioxide, palladium nano particles are directly grown on the surface of the blue titanium dioxide, a tightly combined heterojunction interface is formed so as to be favorable for electronic transmission, theeffective separation of photo-induced electrons and holes is realized, the absorption of visible light is enhanced, the palladium-loaded titanium dioxide base nanometer heterojunction material has the advantages of low cost, high photocatalytic activity and stability and the like, and can be widely applied to the energy and environment fields of photocatalytic solar fuel preparation, photocatalytic degradation of pollutants and the like.

Description

technical field [0001] The invention relates to an in-situ synthesis method of a palladium-supported titanium dioxide-based nano-heterojunction material. Background technique [0002] Energy crisis and environmental pollution are two major challenges facing human society, and photocatalytic technology provides an ideal way to solve energy and environmental problems. Photocatalytic solar fuels and photocatalytic degradation of pollutants have shown important applications in the fields of energy and the environment prospect. However, the realization of large-scale industrial application still needs to solve the bottleneck problems such as the lack of visible light-responsive catalytic materials and the low photocatalytic efficiency caused by the high recombination rate of photogenerated electrons and holes. [0003] Titanium dioxide is the best commercial application so far, and it is also a photocatalytic material with great development prospects in the future. It has strong...

Claims

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Application Information

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IPC IPC(8): B01J23/44B01J35/02
CPCB01J23/44B01J35/00B01J35/30B01J35/393B01J35/39
Inventor 赵勤卢星雨蒲昊贤贾雪平行孟超丁莹
Owner NANTONG UNIVERSITY
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