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75 results about "Solar fuel" patented technology

A solar fuel is a synthetic chemical fuel produced directly/indirectly from solar energy sunlight/solar heat through photochemical/photobiological (i.e., artificial photosynthesis, experimental as of 2013), thermochemical (i.e., through the use of solar heat supplied by concentrated solar thermal energy to drive a chemical reaction), and electrochemical reaction. Light is used as an energy source, with solar energy being transduced to chemical energy, typically by reducing protons to hydrogen, or carbon dioxide to organic compounds. A solar fuel can be produced and stored for later usage, when sunlight is not available, making it an alternative to fossil fuels. Diverse photocatalysts are being developed to carry these reactions in a sustainable, environmentally friendly way.

Low emission energy source

A power generator provides power with minimal CO2, NOx, CO, CH4, and particulate emissions and substantially greater efficiency as compared to traditional power generation techniques. Specifically nitrogen is removed from the combustion cycle, either being replaced by a noble gas as a working gas in a combustion engine. The noble gas is supplemented with oxygen and fuel, to provide a combustion environment substantially free of nitrogen or alternatively working in 100% oxygen-fuel combustion environments. Upon combustion, Very little to no nitrogen is present, and thus there is little production of NOx compounds. Additionally, the exhaust constituents are used in the production of power through work exerted upon expansion of the exhaust products, and the exhaust products are separated into their constituents of noble gas, water and carbon dioxide. The carbon dioxide may be used in conjunction with a biomass to accelerate the biomass growth and to recover the oxygen enriched air resulting from algae photosynthesis for enhancing the operation of the power generator using the as Biomass for processing into methanol / ethanol and biological oils as fuel for the power generator. The biomass fuel is seen as a solar fuel and may be used in conjunctions with other solar fuels like heated thermal oil and others, as well as clean fossil fuels to optimize to clean, and efficient operation of the power generator in various regulatory contexts.
Owner:BRIGHTSOURCE ENERGY

Hybrid generation with alternative fuel sources

A generating facility is provided for generating electricity from both solar and non-solar energy sources. The solar generating portion of the facility includes capability to directly generate electricity from solar insolation, or to store the solar energy in a tangible medium, including stored heat, or solar generating fuel. The generating facility is configured to generate electricity simultaneously from both solar and non-solar sources, as well a solely from immediate solar insolation and from solar energy stored in a tangible medium. Additionally, the solar generating capacity may be segregated; such that separate spectra of solar insolation are used to capture heat for steam turbine based electrical generation, capture light energy for photovoltaic based electrical generation, and to grow biomass to generate a solar fuel.
Owner:LOS ANGELES ADVISORY SERVICES +1

Technology for preparing organic fuel through directly converting carbon dioxide by using sunlight and photothermal catalyst

The invention discloses a technology for preparing organic fuel through directly converting carbon dioxide by using sunlight and a photothermal catalyst. Sunlight is utilized to supply light and heat for the synthesis and catalytic process of the photothermal catalyst, and the photothermal catalyst can simultaneously absorb and utilize ultraviolet light, visible light and infrared light parts in sunlight, so that a phtothermal catalytic reaction is induced to prepare the organic fuel through reducing carbon dioxide by using hydrogen. The photothermal catalyst comprises the following components: an active component which is a 2-30 nano-scale non-stoichiometric oxide belonging to a VIII-family element in a transition family and a carrier material which is an oxide or carbon material with the specific surface area of 30-1000cm<2> / g, alkaline resistance, high heat conductivity or photocatalytic activity. A steeping and in-situ sintering method or photodepositing and in-situ sintering method is used as a synthesis method so that the energy consumption is low, and the photothermal catalyst has high activity and long service life by using a solar-assisted in-situ sintering technology. The technology for preparing organic fuel through directly converting carbon dioxide by using sunlight and the photothermal catalyst is low in energy consumption in the catalytic process, high in organic fuel production efficiency and stable in catalyst activity.
Owner:TIANJIN UNIV

Carbon doped tin disulphide and methods for synthesizing the same

Disclosed herein are carbon doped tin disulphide (C—SnS2) and other SnS2 composites as visible light photocatalyst for CO2 reduction to solar fuels. The in situ carbon doped SnS2 photocatalyst provide higher efficiency than the undoped pure SnS2. Also disclosed herein are methods for preparing the catalysts.
Owner:ACAD SINIC +1

Method for preparing ZnIn2S4 visible-light activated photocatalyst at low temperature

The invention relates to a method for preparing a visible light photocatalyst, specifically to a method for preparing a ZnIn2S4 visible-light activated photocatalyst at low temperature. The preparation method provided by the invention comprises the following steps of: adding zinc salt, indium salt and a sulfur source according to mol ratio into deionized water with uniformly mixing, placing the mixed solution into a reaction vessel, performing a hydrothermal reaction at the temperature of 30-80 DEG C; cooling, centrifuging, washing the precipitate with anhydrous ethanol and deionized water; drying to obtain the ZnIn2S4 visible-light activated photocatalyst powder. According to the invention, the ZnIn2S4 visible-light activated photocatalyst is synthesized at low temperature by using deionized water as the solvent without the addition of any other solvent, a surfactant or a template. The method provided by the invention needs mild condition as well as simple equipment and technology, and is easy to accomplish. The prepared material has a great industrial application prospect in the fields of photocatalysis, solar cells, wastewater degradation and the like.
Owner:DALIAN MARITIME UNIVERSITY

Preparation and application of plasma gold/zinc oxide composite nanosheet array device

The invention discloses preparation and an application of a plasma gold / zinc oxide composite nanosheet array device. The preparation of the composite nanosheet array device is that gold nanoparticles are deposited on a zinc oxide nanorod array with an in-situ photodeposition method, and the morphology of the zinc oxide array is gradually converted into a nanosheet structure from a nanorod structure. The synthesized plasma gold / zinc oxide composite nanosheet array device is adopted for efficient photocatalytic reduction of carbon dioxide, illumination is carried out for 3 hours, and the yields of methane and ethane reach up to 95%. The preparation method of the device is simple, experimental conditions are easy to control, and the device is low in energy consumption, low in raw material price, suitable for large-batch production, very friendly to environment, high in carbon dioxide reduction rate under sunlight illumination, good in photocatalytic activity and stability and expectedly applied to actual production of solar fuel.
Owner:FUZHOU UNIV

Process and method of making space-solar fuels and other chemicals

Processes and methods of making fuels and other chemicals, in conjunction with electricity production, using energy from a powerbeam (120) from an orbiting satellite (100), radiant energy receivers (310) and thermochemical process systems. Includes methods of directing the powerbeam so that, when solar energy 110) is available to drive the concentrators (170), the powerbeam is chiefly focused on rectenna structures (220) for the production of electricity, and then is reconfigured so that it powers the concentrator structures when solar energy is not available.
Owner:MANKINS JOHN CARLTON +1

Autogenic reaction synthesis of photocatalysts for solar fuel generation

In one preferred embodiment, a photocatalyst for conversion of carbon dioxide and water to a hydrocarbon and oxygen comprises at least one nanoparticulate metal or metal oxide material that is substantially free of a carbon coating, prepared by heating a metal-containing precursor compound in a sealed reactor under a pressure autogenically generated by dissociation of the precursor material in the sealed reactor at a temperature of at least about 600° C. to form a nanoparticulate carbon-coated metal or metal oxide material, and subsequently substantially removing the carbon coating. The precursor material comprises a solid, solvent-free salt comprising a metal ion and at least one thermally decomposable carbon- and oxygen-containing counter-ion, and the metal of the salt is selected from the group consisting of Mn, Ti, Sn, V, Fe, Zn, Zr, Mo, Nb, W, Eu, La, Ce, In, and Si.
Owner:UCHICAGO ARGONNE LLC

Photosensitive fuel for dye-sensitized solar cell and preparation method thereof

InactiveCN102408744AReduced transition energyImprove absorption ratePorphines/azaporphinesPorphyrinSolar cell
The invention belongs to the technical field of solar cell materials, and particularly relates to a sensitizer for a dye-sensitized solar cell and a preparation method thereof. The preparation method of the photosensitizer provided by the invention comprises the following steps of: taking 5-(4-nitrophenyl)-10,15,20-tris(4-hydroxyphenyl)porphyrin as an initiator; under nitrogen conditions, dissolving the initiator in concentrated hydrochloric acid, and reducing the initiator into 5-(4-aminophenyl)-10,15,20-tris(4-hydroxyphenyl)porphyrin by using stannous chloride; then, dissolving the reduced porphyrin and zinc acetate in an inert organic solvent for coordination; finally, dissolving the generated zinc protoporphyrin and 4-carboxybenzaldehyde in a dichloromethane solvent, and heating and refluxing; and after the reaction is finished, adding petroleum ether or absolute methanol for precipitating products, and recrystallizing to obtain a corresponding product N-(5-p-phenyl)-10,15,20-tris-p-hydroxyphenyl zinc protoporphyrin-p-carboxyl benzimide. The product provided by the invention has the advantages of high molar extinction coefficient, low cost and the like.
Owner:ZHONGBEI UNIV

Solar cell modules with improved backsheet

Disclosed is a polyamide-ionomer composition suitable for use in a backsheet in a photovoltaic module comprising a polymer component a polyamide and an anhydride ionomer comprising a copolymer of ethylene, an alpha, beta-unsaturated C3-C8 carboxylic acid and an ethylenically unsaturated dicarboxylic acid or derivative thereof selected from the group consisting of maleic acid, fumaric acid, itaconic acid, maleic anhydride, and a C1-C1 alkyl half ester of maleic acid, wherein the carboxylic acid functionalities present are at least partially neutralized to carboxylate salts of one or more alkali metal, transition metal, or alkaline earth metal cations; 0 to 20 weight % of pigment; and 0 to 40 weight % of filler; preferably wherein the combination of pigment and filler comprises 10 to 50 weight % of the composition; and 0 to 5 weight % of weatherability additives.
Owner:PERFORMANCE MATERIALS NA INC

Method for preparing Cu2ZnSn(S,Se)4 solar cell absorbing layer film by using mercaptan-based ink

The invention provides a method for preparing Cu2ZnSn(S,Se)4 solar cell absorbing layer film by using mercaptan-based ink, belonging to the technical field of a solar cell absorbing layer film. The method comprises the steps of (a) stable precursor solution preparation under an air condition, (b) the preparation of a precursor film by using a spinning coating method, (c) drying, (d) multiple times of spinning coating and drying and (e) annealing processing. According to the film preparation method, the use of expensive original materials and devices is not needed, mercaptan which is a volatile, low carbon organic compound is taken as a solvent, and a problem of the introduction of carbon and oxygen elements in the previous copper zinc tin sulfide nanocrystal synthesis process can be overcome. The controllability of each process step is good, the preparation of the absorbing layer film with large grains, density and good photoelectric performance is facilitated, the process is simple, the repeatability is strong, and the large-scale production is easy to realize.
Owner:BEIJING UNIV OF TECH

Mid-and-low temperature solar and fossil fuel thermo-chemical complementary power generation system and method

ActiveCN103803491AImprove net power generation efficiencyHigh energyHydrogenInternal combustion piston enginesThermal energyHigh energy
The invention discloses a mid-and-low temperature solar and fossil fuel thermo-chemical complementary power generation system and method. The system comprises a raw material supply device for storing a fossil fuel, a raw material mixing device for mixing a raw material and non-reacted materials, a raw material metering device for controlling the quantity of the raw material entering a pre-heater within unit time, the pre-heater for pre-heating the raw material, a solar absorption reactor for driving the fossil fuel by using absorbed solar heat to perform decomposition or reforming reaction so as to convert solar energy into hydrogen-rich fuel chemical energy and produce a solar fuel, a solar heat collector for gathering solar energy with low energy flow density into mid-and-low temperature heat energy with high energy flow density and supplying heat to the decomposition or reforming reaction, a condenser for cooling a reaction product, a gas-liquid separator for gas-liquid separation of a mixture, a fuel diversion device for adjusting the proportion of the solar fuel for energy storage or power generation, a gasholder for storing the solar fuel, and power generation equipment for burning the solar fuel and outputting power to the outside. The system and the method realize efficient power generation utilization of the solar energy.
Owner:INST OF ENGINEERING THERMOPHYSICS - CHINESE ACAD OF SCI

Solar fuel cell

ActiveUS20110278176A1CellsHydrocarbon from carbon oxidesPhotoelectrochemical oxidationSolar cell
The present teachings are directed to a method of converting water and a carbon-containing compound, such as CO2, into a hydrocarbon through a process of absorbing sunlight on a light-absorbing component to photoelectrochemically oxidize water and reacting the products from that water oxidation reaction over a catalyst with the carbon-containing compound to produce the desired hydrocarbon compound.
Owner:HONDA MOTOR CO LTD

Solar cell

The present invention provides a solar cell having high photovoltaical conversion efficiency and being excellent in the light transmissivity and weather resistance such as solarization resistance. The present invention relates to a solar cell comprising a double tube composed of two glass tubes differing in the diameter and a photovoltaic conversion layer formed between the two glass tubes, the double tube being sealed at both ends of a part in which the photovoltaic conversion layer is formed, wherein at least one of the two glass tubes is composed of a glass comprising, in mass % based on the oxides, from 60 to 75% of SiO2, from 4 to 10% of Al2O3, from 0 to 5% of B2O3, from 0 to 5% of MgO, from 0.5 to 5% of CaO, from 0 to 0.5% of SrO, from 0 to 11% of BaO, from 10 to 16% of Na2O, from 0 to 10% of K2O, and from 0.5 to 10% of ZrO2.
Owner:ASAHI GLASS CO LTD

System and method for improving preparation speed and efficiency of solar thermo-chemical fuel

The invention discloses a system and method for improving the preparation speed and efficiency of a solar thermo-chemical fuel. The system comprises a condensation device (a), a contact heat exchange device (b), a reactor (c), an oxygen collecting device (d), a heat exchanger (e) and a gas separation and collecting device (f). Compared with a solar thermo-chemical isothermal method, the system and method for improving the speed and efficiency of preparing the fuel by solar thermo-chemical circulation have the advantages that the two methods are devoted to eliminating the loss of energy for heating a catalyst, but the temperature of the isothermal method is unchanged, and the oxidation reaction temperature is higher than that of a dual-temperature method, so that the oxygen vacancy change is relatively low when the reduced cerium oxide and H2O undergo oxidation reaction, which is unfavorable for fuel production. Through active cooling of the catalyst, the time required for each cycle of the reactor can be greatly shortened, meanwhile, more hydrogen is produced in each cycle compared with the isothermal method, moreover, the reaction rate of the oxidation step can be improved, the heat of the high-temperature reduction step is reasonably utilized, the conversion efficiency of the solar fuel is improved, use of a solid-solid heat exchanger is avoided, and the mechanical properties of the reactor are improved.
Owner:INST OF ENGINEERING THERMOPHYSICS - CHINESE ACAD OF SCI

Composite photocatalyst for photolyzing water and degrading pollutants and preparation method thereof

The invention provides a composite photocatalyst for photolyzing water and degrading pollutants and a preparation method thereof. The composite photocatalyst can realize efficient transformation fromsolar energy to chemical energy, and is mainly prepared by compounding a mesoporous template and photocatalytic active components in the aspect of a nano-scale; the photocatalytic active components are nanoparticles of compound metal salt; the compounding is realized by uniformly dispersing the photocatalytic active components in a pore channel framework of the mesoporous template; the compoundingis realized through the following steps: complexing a soluble metal salt precursor and a complexing agent and dispersing into a pore channel of the mesoporous template; then carrying out high-temperature calcination under a limited area environment. The catalyst provided by the invention is mainly used for photocatalytically decomposing water to produce hydrogen or photocatalytically degrading organic pollutants including VOC (Volatile Organic Compound), s-VOC (semi-Volatile Organic Compound) and the like in the water or air under sunlight. The catalyst provided by the invention has good stability and good dispersity; platinum or other co-catalysts are loaded, so that the composite photocatalyst has very high activity on photocatalytic complete decomposition on the water and photocatalytic degradation on organic matters.
Owner:SHANGHAI JIAO TONG UNIV

Preparation method and application of blue titanium dioxide

The invention discloses a preparation method and application of blue titanium dioxide. The blue titanium dioxide is prepared by: adding white titanium dioxide and 10-37% formaldehyde solution into a quartz photocatalytic reactor, dispersing by ultrasound, and exposing to ultraviolet irradiation of a high-voltage mercury lamp or xenon lamp 250-400 W for 8-30 min, wherein the concentration of the white titanium dioxide in the formaldehyde solution is 0.08-80 g / L. The blue titanium dioxide is prepared in a normal pressure and normal temperature atmosphere; the preparation method has the advantages of low cost, good simplicity and feasibility, suitability for large-scale preparation and application and the like; the prepared blue titanium dioxide is applicable to in-situ synthesis of titaniumdioxide-based nano heterojunction materials and is widely applicable to the energy and environment fields, such as photocatalytic manufacture of solar fuels and photocatalytic degradation of pollutants.
Owner:NANTONG UNIVERSITY

Solar concentrator plant using natural-draught tower technology and operating method

Solar concentrator plant using natural-draught tower technology, in which the tower is, in turn, used as cooling system. The tower houses saturated or superheated steam receivers in cavities with different orientations, with adaptive dynamic control of the heliostat field in order to direct said receivers towards different focusing points, for the production of electricity, process heat or solar fuels or for use in thermochemical processes.
Owner:ABENGOA SOLAR NEW TECH SA

Ferronickel catalytic material and preparation method thereof, and application of ferronickel catalytic material in preparing hydrogen by electrolyzing water and preparation of liquid solar fuel

ActiveCN110197909AReduce energy consumption for hydrogen productionGuaranteed uptimeOrganic compound preparationPV power plantsPtru catalystIron salts
The invention discloses a ferronickel catalytic material and a preparation method thereof, and application of a ferronickel catalytic material in preparing hydrogen by electrolyzing water and preparation of liquid solar fuel. The material is prepared on a modified nickel substrate under mild conditions by using soluble iron salt as a raw material, and the ferronickel catalytic material which can be applied to the harsh conditions of industrial alkaline electrolyzed water is successfully prepared. The ferronickel catalytic material includes a nickel metal substrate and a catalytically active layer containing an iron element and a nickel element. The ferronickel catalyst is adopted to promote the water decomposition reaction, and the energy consumption required by preparing hydrogen per cubic meter by industrial alkaline electrolyzed water can be reduced from 4.4 kilowatt-hour to 4.01 kilowatt-hour, so that the conversion amount of solar energy to methanol is improved by 9.7 percent. Theferronickel catalytic material has the advantages of a simple preparation process, the low cost and easy implementation of industrial requirement amplification preparation. The process can convert solar energy into conventional fuel which is convenient to store and transport, provides a new way for solving the energy problem and the environmental problem, and has great economic benefit and socialbenefit.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Preparation of (C5H5) Ru/TiO2 organic-inorganic hybrid photocatalyst

The invention discloses preparation of a (C5H5) Ru / TiO2 organic-inorganic hybrid photocatalyst, and an application of preparing methane solar fuel by performing photocatalytic reduction on carbon dioxide. According to the invention, a surface organometallic chemistry method is adopted, and dicyclopentadiene-based ruthenium is grafted to the surface of the titanium dioxide by adopting a surface grafting method to obtain a composite material having a similar semi-sandwich structure, wherein the mass percentage of ruthenium is 0.3-5.0%. Compared with dicyclopentadiene-based ruthenium-unmodified titanium dioxide, the (C5H5) Ru / TiO2 composite material prepared by adopting the method not only has relatively wide photoresponse range, but also photon-generated carriers can fast migrate and transmit as surface Ru-O-Ti keys are generated, and therefore, the photocatalytic efficiency of titanium dioxide in a carbon dioxide methanation process can be effectively improved. The method is simple and easy to operate, and has promotion significance on energy crisis mitigation and ecological environment improvement.
Owner:FUZHOU UNIV

A-D-A conjugated molecule, preparation method, application in organic solar cell, and organic solar cell

The invention provides an A-D-A conjugated molecule and a preparation method thereof, an organic solar cell and application of the A-D-A conjugated molecule in the organic solar cell. The A-D-A conjugated molecule has the general structure shown in the specification, wherein R1 is 4-alkylphenyl, 4-alkoxyphenyl, 4-alkylthiophenyl, 4-alkylthienyl, 4-alkoxythienyl, 4-alkylthiothienyl, 4-alkylthiothienyl, 4-alkylselenophenyl or 4-alkylthioselenophenyl; ar is thiophene group, thiophene derivative group, bithiophene group, bithiophene derivative group, dithienothiophene group, dithienothiophene derivative group, benzobithiophene group, benzobithiophene derivative group, pyrrolo bithiophene group, pyrrolo bithiophene derivative group, pentane bithiophene group, or pentane bithiophene derivative group; and EG is a capping group. The A-D-A conjugated molecule has stronger light absorption capability, better charge transmission performance and appropriate electron energy level.
Owner:UZHOU QIANXUN NEW ENERGY TECH CO LTD

Hydrogen production system based on solar fuel methanol-water reforming

The invention discloses a hydrogen production system based on solar fuel methanol-water reforming. The system comprises a solar fuel methanol synthesis system, a solar fuel methanol hydrogen production system and a gas collection system, the solar fuel methanol synthesis system comprises a renewable energy power generation module, a water electrolysis hydrogen production module and a methanol synthesis module, the solar fuel methanol hydrogen production system comprises a methanol-water reforming module, a carbon dioxide and hydrogen separation module, a water-vapor conversion module and a carbon dioxide separation module, and the gas collection module comprises a hydrogen collection module and a carbon dioxide collection module. The solar fuel methanol synthesis system, the solar fuel methanol hydrogen production system and the gas collection system are directly or indirectly connected. According to the hydrogen production system based on solar fuel methanol-water reforming, carbon dioxide zero emission of a whole industry chain is achieved, and sustainable development and ecological civilization construction of the human society are achieved.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

In situ synthesis method for palladium-loaded titanium dioxide base nanometer heterojunction material

The invention discloses an in situ synthesis method for a palladium-loaded titanium dioxide base nanometer heterojunction material. The in situ synthesis method comprises the following steps of the preparation of blue titanium dioxide and the in situ synthesis of the palladium-loaded titanium dioxide base nanometer heterojunction material. By use of the own reducibility of the blue titanium dioxide, palladium nano particles are directly grown on the surface of the blue titanium dioxide, a tightly combined heterojunction interface is formed so as to be favorable for electronic transmission, theeffective separation of photo-induced electrons and holes is realized, the absorption of visible light is enhanced, the palladium-loaded titanium dioxide base nanometer heterojunction material has the advantages of low cost, high photocatalytic activity and stability and the like, and can be widely applied to the energy and environment fields of photocatalytic solar fuel preparation, photocatalytic degradation of pollutants and the like.
Owner:NANTONG UNIVERSITY

Solar fuel cell and preparation method thereof

The invention relates to a solar fuel cell formed by enhancing the catalytic reaction of a positive electrode and a negative electrode of a fuel cell via a surface plasmon polariton resonance field, and a preparation method of the solar fuel cell. The solar fuel cell comprises a transparent working electrode, a counter electrode, an electrolyte, a Nafion semipermeable membrane, a fuel inlet, an oxygen inlet and an oxygen outlet, wherein the transparent working electrode and the counter electrode are arranged in a frame, the electrolyte is sealed between the transparent working electrode and the counter electrode, the Nafion semipermeable membrane is arranged between the transparent working electrode and the counter electrode, and the fuel inlet, the oxygen inlet and the oxygen outlet are led into the electrolyte, wherein a metal nanoparticle layer having the granularity within 5nm to 500nm is assembled on the inner side of the transparent working electrode. A metal nanoparticles catalyst with the plasmon polariton resonance characteristic is arranged on the surface of the working electrode, so that the catalytic efficiency of an electrode catalyst of the fuel cell is effectively improved by utilizing the enhancement effect of the generated surface plasmon polariton resonance field under the irradiation of visible light, and the service life of the electrode is prolonged.
Owner:JILIN UNIV

Solar Cell

The present invention relates to a solar cell comprising an anode, a cathode, and an electrolyte, wherein said anode comprises a substrate and a titania layer composed of a mesoporous titania bead having a diameter of 200-1000 nm, specific surface area of 50-100 m2 / g, porosity of 40-60%, pore radius of 5-20 nm, pore volume of 0.20-0.30 cm3 / g, and the titania comprised in the bead is anatase titania.
Owner:NAT CHENG KUNG UNIV

Ferrocene zinc porphyrin compound and synthesis thereof and application thereof as dye sensitizer

The invention provides a ferrocene zinc porphyrin compound. The ferrocene zinc porphyrin is successfully synthesized by taking ferrocene formaldehyde and pyrrole as raw materials through multi-step reactions of condensation, reduction, coordination, zinc substitution and the like. By a soaking method, a nanocrystalline TiO2 / FTO electrode is sensitized, a ferrocene zinc porphyrin coordination compound dye-sensitized solar cell is researched, and photoelectric performance testing results show that the dye-sensitized solar cell prepared in the invention has relatively high current output capability and photoelectric conversion efficiency under irradiation of standard light and has an IPCE quantum conversion rate up to 80%. The synthesis of the ferrocene zinc porphyrin compound is simple in process, short in process route and convenient to operate; the ferrocene zinc porphyrin compound is mild in reaction condition, low in cost and high in yield.
Owner:山东奥达复合材料有限公司

Coating solution for forming a light-absorbing layer of a chalcopyrite solar cell, method of producing a light-absorbing layer of a chalcopyrite solar cell, method of producing a chalcopyrite solar cell and method of producing a coating solution for forming a light-absorbing layer of a chalcopyrite solar cell

A coating solution for forming a light-absorbing layer of a chalcopyrite solar cell, including a hydrazine-coordinated Cu chalcogenide complex, a hydrazine-coordinated In chalcogenide complex and hydrazine-coordinated Ga chalcogenide complex dissolved in dimethylsulfoxide, the hydrazine-coordinated Cu chalcogenide complex being obtained by dissolving Cu or Cu2Se and a chalcogen in dimethylsulfoxide having hydrazine added, and adding a poor solvent to the resulting solution.
Owner:TOKYO OHKA KOGYO CO LTD

Solar cell sealing film and solar cell using the same

The solar cell sealing film according to the present invention includes ethylene-methyl methacrylate copolymer, a crosslinker and a silane coupling agent, wherein the crosslinker is contained in an amount of 0.05 to 0.7 part by weight, based on 100 parts by weight of the ethylene-methyl methacrylate copolymer, and the silane coupling agent is contained in an amount of 0.1 to 0.7 part by weight based on 100 parts by weight of the ethylene-methyl methacrylate copolymer, and wherein the ethylene-methyl methacrylate copolymer has a methyl methacrylate content of 25 to 35% by weight.
Owner:BRIDGESTONE CORP

Method for catalytic ammonia synthesis under concentrated solar energy and catalysts

A method for catalytic ammonia synthesis under concentrated solar energy and related catalysts. The method includes placing a catalyst in a reaction apparatus, feeding nitrogen and hydrogen into the reaction apparatus, and controlling a surface temperature of the catalyst to reach about 300° C. to 550° C. under irradiation of concentrated sunshine, to synthesize ammonia. The catalyst includes an amorphous and electron-rich black nano TiO2-z (0<z<2) with a disordered surface serves as a carrier material, and an elemental nano-crystal of Fe or Ru serves as an active ingredient. The active ingredient is loaded on the carrier material. Sunshine is used as the energy during ammonia synthesis reaction, and light in the whole wave band can be utilized sufficiently. Ammonia can be synthesized under solar energy with a high efficiency, and no fossil energy or electrical energy is needed. A synergetic catalytic effect of optical energy and thermal energy can be obtained.
Owner:HUAZHONG NORMAL UNIV

High efficiency visible and ultraviolet nanowire emitters

GaN-based nanowire heterostructures have been intensively studied for applications in light emitting diodes (LEDs), lasers, solar cells and solar fuel devices. Surface charge properties play a dominant role on the device performance and have been addressed within the prior art by use of a relatively thick large bandgap AlGaN shell covering the surfaces of axial InGaN nanowire LED heterostructures has been explored and shown substantial promise in reducing surface recombination leading to improved carrier injection efficiency and output power. However, these lead to increased complexity in device design, growth and fabrication processes thereby reducing yield / performance and increasing costs for devices. Accordingly, there are taught self-organizing InGaN / AlGaN core-shell quaternary nanowire heterostructures wherein the In-rich core and Al-rich shell spontaneously form during the growth process.
Owner:MCGILL UNIV
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