System and method for improving preparation speed and efficiency of solar thermo-chemical fuel

A chemical fuel, solar thermal technology, applied in solar heating systems, solar thermal energy, solar thermal power generation, etc., can solve the problems of immaturity, disadvantage, and difficulty in heat recovery and utilization of heat exchangers, so as to improve mechanical performance, avoid use, The effect of improving conversion efficiency

Active Publication Date: 2015-06-24
INST OF ENGINEERING THERMOPHYSICS - CHINESE ACAD OF SCI
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Problems solved by technology

[0025] In this case, the huge energy consumed by heating cerium oxide can be eliminated. Although the efficiency is improved compared with the traditional two-temperature method under certain conditions, because the oxidation ste...

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  • System and method for improving preparation speed and efficiency of solar thermo-chemical fuel

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Embodiment Construction

[0057] In order to make the object, technical solution and advantages of the present invention clearer, the present invention will be described in further detail below in conjunction with specific embodiments and with reference to the accompanying drawings.

[0058] The invention provides a system and method for improving the speed and efficiency of solar thermochemical fuel production, using cerium oxide as a catalyst, the process of preparing CO and H 2 The principle is the same, including two main reaction processes: high temperature T H The lower oxygen carrier (such as cerium oxide) absorbs solar heat and undergoes a reduction reaction to release O 2 ; low temperature T L Next, CO is introduced into the reduced oxygen carrier 2 / H 2 O is oxidized to release CO / H 2 . There are two items in the energy input part: the cerium oxide from the low temperature T L Heated to high temperature T H The required heat Q 氧化铈,加热 and high temperature T H The heat Q absorbed by re...

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Abstract

The invention discloses a system and method for improving the preparation speed and efficiency of a solar thermo-chemical fuel. The system comprises a condensation device (a), a contact heat exchange device (b), a reactor (c), an oxygen collecting device (d), a heat exchanger (e) and a gas separation and collecting device (f). Compared with a solar thermo-chemical isothermal method, the system and method for improving the speed and efficiency of preparing the fuel by solar thermo-chemical circulation have the advantages that the two methods are devoted to eliminating the loss of energy for heating a catalyst, but the temperature of the isothermal method is unchanged, and the oxidation reaction temperature is higher than that of a dual-temperature method, so that the oxygen vacancy change is relatively low when the reduced cerium oxide and H2O undergo oxidation reaction, which is unfavorable for fuel production. Through active cooling of the catalyst, the time required for each cycle of the reactor can be greatly shortened, meanwhile, more hydrogen is produced in each cycle compared with the isothermal method, moreover, the reaction rate of the oxidation step can be improved, the heat of the high-temperature reduction step is reasonably utilized, the conversion efficiency of the solar fuel is improved, use of a solid-solid heat exchanger is avoided, and the mechanical properties of the reactor are improved.

Description

technical field [0001] The invention relates to the technical field of fuel preparation by high-temperature solar thermochemical cycle dual-temperature method, especially by converting CO 2 or H 2 O to CO and H 2 A system and method for increasing the speed and efficiency of solar thermochemical fuel production. Background technique [0002] As a clean energy, hydrogen has more and more applications in industry, medicine and so on. The traditional way is to produce hydrogen through electrolysis of water or methane reforming, which undoubtedly indirectly increases the consumption of fossil energy. Today, fossil energy is increasingly depleted, and hydrogen production by combining renewable energy such as solar energy with water splitting has highlighted many advantages. In addition, the process of decomposing carbon dioxide to produce carbon monoxide can reduce greenhouse gas emissions and reduce the consumption of fossil energy, which is a supplementary method of carbon ...

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Application Information

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IPC IPC(8): C01B3/06C01B31/18F24J2/10C01B32/40F24S23/70
CPCY02E10/40Y02E60/36
Inventor 郝勇孔慧
Owner INST OF ENGINEERING THERMOPHYSICS - CHINESE ACAD OF SCI
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