Ore floatation collecting agent for oxidized ore

A technology for mineral flotation and collectors, applied in flotation, solid separation and other directions, can solve the problems of unacceptable enterprises, complicated preparation methods, and high production costs, and achieve enhanced selectivity, improved collection efficiency, and increased ore loading. amount of effect

Active Publication Date: 2019-01-04
河南天鸿新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patent CN102962144A discloses a kind of oleic acid with a degree of saponification of about 50% as a collector, and a method for flotation and separation of bauxite; A method for enriching fluorite by segmental flotation with oleic acid; Chinese patent CN102600985A discloses a method for flotation of ilmenite and iron oxide ore using a collector mixed with oleic acid, oxidized paraffin soap and fatty acid; The Chinese application CN107922993A of Heinkel Company adopts alkyl sulfosuccinate of alkoxy fatty alcohol as the flotation agent in non-sulfurized ore flotation, which can improve the flotation efficiency and reduce the cost of flotation agent to a certain extent. usage, but the preparation method of this flotation agent is complicated, the producti

Method used

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  • Ore floatation collecting agent for oxidized ore

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Weigh the corresponding components according to the proportion, wherein: the weight percentage proportion of dibutyl ammonium dithiophosphate is 1%, the weight percentage proportion of oxidized paraffin wax soap is 30%, the weight percentage proportion of sodium edetate Ratio is 21%, the weight percent distribution ratio of disodium maleate dihydrate is 10%, and the balance is water.

[0026] First, mix dibutyl ammonium dithiophosphate, oxidized paraffin wax soap and part of water, heat to 60-80°C and stir for 0.5-1.5h to obtain component A. Add salt and disodium maleate dihydrate to the remaining water and stir for 2-4 hours to obtain component B, add the prepared component A to component B and stir evenly to obtain the oxidized ore mineral flotation collection Agent 1.

Embodiment 2

[0028] Weigh the corresponding components according to the proportion, wherein: the weight percentage proportion of dibutyl ammonium dithiophosphate is 5%, the weight percentage proportion of oxidized paraffin wax soap is 31%, the weight percentage proportion of sodium edetate Ratio is 25%, the weight percent distribution ratio of disodium maleate dihydrate is 10%, and the balance is water.

[0029] First, mix dibutyl ammonium dithiophosphate, oxidized paraffin wax soap and part of water, heat to 60-80°C and stir for 0.5-1.5h to obtain component A, and ethylenediaminetetraacetic acid at 50-60°C Sodium and disodium maleate dihydrate are added to the remaining water and stirred for 2-4 hours to obtain component B, and the prepared component A is added to component B and stirred evenly to obtain the oxidized ore mineral flotation collector 2.

Embodiment 3

[0031] Weigh the corresponding components according to the proportion, wherein: the weight percentage proportion of dibutyl ammonium dithiophosphate is 10%, the weight percentage proportion of oxidized paraffin wax soap is 31%, the weight percentage proportion of sodium edetate Ratio is 25%, the weight percent distribution ratio of disodium maleate dihydrate is 15%, and the balance is water.

[0032] First, mix dibutyl ammonium dithiophosphate, oxidized paraffin wax soap and part of water, heat to 60-80°C and stir for 0.5-1.5h to obtain component A, and ethylenediaminetetraacetic acid at 50-60°C Sodium and disodium maleate dihydrate are added to the remaining water and stirred for 2-4 hours to obtain component B, and the prepared component A is added to component B and stirred evenly to obtain the oxidized ore mineral flotation collector 3.

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Abstract

The invention provides an ore collecting agent for collecting oxidized ore such as ilmenite and a preparing method of the ore collecting agent for collecting oxidized ore such as ilmenite and belongsto the technical field of oxidized ore floatation collecting agents. The ore collecting agent for oxidized ore such as ilmenite is used after ammonium dibutoxy dithiophosphate, edentate, maleate, oxidized paraffin soap and the like are mixed, has the beneficial effects of being good in water solubility, good in dispersibility and high in preferential adsorption capability on aimed ore and is mainly used for floatation separation of valuable ore in oxidized ore such as ilmenite, scheelite and wolframite. The preparing method of the re floatation collecting agent for oxidized ore is simple in process, operation is easy to control, and the prepared collecting agent has the beneficial effects of being high in selectivity, good in dispersibility, small in agent dosage, high in beneficiation comprehensive efficiency and the like and has very important significance in promoting beneficiation of ore such as oxidized ore.

Description

technical field [0001] The invention relates to a flotation collector for oxidized minerals such as ilmenite, and belongs to the technical field of mineral flotation collectors. Background technique [0002] There are about 20 proven minerals containing tungsten on the earth, but the ones with economic development value are scheelite and wolframite. Due to the relatively high weight of tungsten ore, with a specific gravity between about 6-8, high grade and recovery can be achieved through gravity separation when only coarse particles are released. However, tungsten ores typically occur at points of contact between tungsten-bearing ores in the form of granite, in quartz ore, and in the form of carbonate sedimentary rocks. However, in actual mining, it will be found that scheelite is produced as fine particles. When gravity separation is used, many fine particles are generated due to high brittleness during crushing or grinding, so the recovery rate is greatly reduced. There...

Claims

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Application Information

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IPC IPC(8): B03D1/018B03D101/02B03D103/04
CPCB03D1/018B03D2201/02B03D2203/04
Inventor 张好君张鸣然
Owner 河南天鸿新材料科技有限公司
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