The invention discloses a water-based paint capable of safely releasing anions. The water-based paint utilizes hexacyclic stone, Qingshui stone, opal, tourmaline, volcanic rock, ancient sea rock and the like containing nanometer micropore structures, wherein the above ores contain germanium, aluminum, iron, boron, cobalt, nickel, alum, calcium, magnesium, sodium, potassium, selenium, zinc, strontium, titanium, silicon and other elements, and each micropore has a potential difference of 0.06 MA; and the water-based paint has a bioelectricity effect, produces a synergistic effect together with purified rare earth oxide, can decompose water in the air to form hydroxyl water anions, and can safely, efficiently and continuously generate anions. When the paint is used for indoor wall surface painting, indoor air quality can reach negative ion air quality level 1 or above. A formula of the water-based paint comprises 5.0 to 20.0 parts of hexacyclic stone, 5.0 to 20.0 parts of Qingshui stone,5.0 to 20.0 parts of opal, 5.0 to 20.0 parts of karst rock, 5.0 to 20.0 parts of tourmaline, 5.0 to 10.0 parts of volcanic rock, 5.0 to 10.0 parts of ancient sea rock, 0.5 to 5.0 parts of purified rare earth oxide and 5.0 to 10.0 parts of mineral bonding powder.