The invention belongs to the technical field of
mineral flotation, and discloses a flotation collecting agent for non-
ferrous metal sulfide ore and a preparation method and application thereof.O, O dialkyl dithiophosphate serves as an initial
raw material of the collecting agent, and the target product O, O dialkyl dithiophosphate, halogenated
carboxylic ester, hydrazine
hydrate,
potassium hydroxide and
carbon disulfide are sequentially subjected to three-step reaction in absolute ethyl
alcohol to prepare O, O dialkyl dithiophosphate; the molecular structure of the N, O-dialkyl
phosphorodithioic acid hydrazide-N '-
potassium dithioformate simultaneously contains three active groups, namely a phosphorodithioate group, a
hydrazide group and dithioformate. By optimizing the material ratio, temperature and time of each step of reaction, efficient connection and stable transition of the process are realized, and the method has the advantages of mild
reaction conditions, simplicity and convenience in operation, few side reactions, high yield, stable product and the like. And the prepared collecting agent shows excellent collecting performance and good selectivity on non-
ferrous metal sulfide ores such as
chalcopyrite, and is suitable for popularization and application in a
sulfide ore flotation process.