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Method for reducing use amount of plasticizer in artificial leather

A technology of artificial leather and plasticizer, which is applied in the direction of textiles and papermaking, etc., can solve the problems of easy migration and leakage of plasticizer, shortened service life, and reduced leather performance, so as to improve market competitiveness, reduce usage, and disperse Improved effect

Active Publication Date: 2019-01-04
安徽省华瑞网业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Excessive use of plasticizers will cause a series of problems. On the one hand, plasticizers are easy to migrate and seep out of the leather surface, reducing the performance of the leather, becoming intolerant to dust, poor wear resistance, and shortened service life. On the one hand, because plasticizers are very harmful and widely exist in the environment, they will also cause great harm to the human body.

Method used

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  • Method for reducing use amount of plasticizer in artificial leather

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Embodiment 1

[0019] A method for reducing the amount of plasticizer used in artificial leather. The inorganic non-metallic nanopowder is compounded with a polymer compound to prepare a polymer-based nanocomposite material, which is added to a synthetic resin as an additive and further plasticized to prepare artificial leather. The preparation method of the polymer-based nanocomposite comprises the following steps:

[0020] (1) Weigh 3.2 grams of nano-silica, dry it in an oven at 80°C for 4 hours, place it in a beaker, add 50 ml of ethanol-isopropanol mixed solvent into the beaker, and place the beaker on a magnetic stirrer to stir Disperse for 40 minutes, heat the water bath to 55°C, add the preheated triethylamine into the beaker, keep stirring for 15 minutes, continue to add 3 ml of hexamethyldisilazane to the beaker under stirring, stir well Transfer to the four-neck flask equipped with thermometer, reflux condenser, stirrer and constant pressure funnel;

[0021] (2) Add 8.5 grams of t...

Embodiment 2

[0030] A method for reducing the amount of plasticizer used in artificial leather. The inorganic non-metallic nanopowder is compounded with a polymer compound to prepare a polymer-based nanocomposite material, which is added to a synthetic resin as an additive and further plasticized to prepare artificial leather. The preparation method of the polymer-based nanocomposite comprises the following steps:

[0031] (1) Weigh 3.3 grams of nano-silicon dioxide, place it in an oven at 85 ° C for 4.5 hours, place it in a beaker, add 55 ml of ethanol-isopropanol mixed solvent into the beaker, and place the beaker on a magnetic stirrer to stir Disperse for 45 minutes, heat the water bath to 58°C, add the preheated triethylamine into the beaker, continue stirring for 18 minutes, continue to add 3.5 ml of hexamethyldisilazane to the beaker under stirring, and stir evenly Transfer to the four-neck flask equipped with thermometer, reflux condenser, stirrer and constant pressure funnel;

[0...

Embodiment 3

[0041] A method for reducing the amount of plasticizer used in artificial leather. The inorganic non-metallic nanopowder is compounded with a polymer compound to prepare a polymer-based nanocomposite material, which is added to a synthetic resin as an additive and further plasticized to prepare artificial leather. The preparation method of the polymer-based nanocomposite comprises the following steps:

[0042] (1) Weigh 3.4 grams of nano-silica, dry in an oven at 90°C for 5 hours, place it in a beaker, add 60 ml of ethanol-isopropanol mixed solvent into the beaker, and place the beaker on a magnetic stirrer to stir Disperse for 50 minutes, heat the water bath to 60°C, add the preheated triethylamine into the beaker, keep stirring for 20 minutes, continue to add 4 ml of hexamethyldisilazane to the beaker under stirring, and stir well Transfer to the four-neck flask equipped with thermometer, reflux condenser, stirrer and constant pressure funnel;

[0043] (2) Add 8.8 grams of ...

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Abstract

The invention relates to the technical field of novel functional materials, and discloses a method for reducing the use amount of a plasticizer in artificial leather. In the method, nanometer silica and tetramethyldisiloxane are used for combining inorganic non-metallic nanometer powder with a high molecular compound, thereby preparing a polymer nanocomposite. After modification treatment, the interfacial size effect of nanometer particles is eliminated, the nanometer particles have improved disperstiveness and strong activity and are capable of maintaining the thermodynamic stable state, andthe wetting property and the binding force between the nanometer particles and organics are greatly increased, thereby improving the operability of the artificial leather plasticizing process, and greatly reducing the use amount of the plasticizer, the nanometer particles have the advantages of excellent surface property, corrosion resistance, oil resistance, abrasion resistance, aging resistance,and the like, and enable the artificial leather to possess higher folding fastness and strong sparseness.

Description

technical field [0001] The invention belongs to the technical field of new functional materials, and in particular relates to a method for reducing the amount of plasticizer used in artificial leather. Background technique [0002] Artificial leather is a plastic product that looks and feels like leather and can be used instead of it. It is usually made of fabric as the base, coated with synthetic resin and various plastics. There are mainly three types of PVC artificial leather, PU artificial leather and PU synthetic leather. In the 1980s, ordinary people could not afford expensive leather clothing. In response to market demand, imitation leather artificial leather became popular and was widely used in clothing and bag making. Such imitation leather artificial leather clothes and bags once flooded the streets, satisfying people's desire to wear leather. Compared with leather, artificial leather is easy to age and wear, and it is harmful to human health because it contain...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06N3/00
CPCD06N3/0059D06N3/0063
Inventor 张腾飞
Owner 安徽省华瑞网业有限公司