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A high-capacity magnesium seawater battery cuprous chloride positive electrode sheet molding process and an obtained battery

A technology of cuprous chloride and positive electrode sheet, which is applied to the electrodes of primary batteries, battery electrodes, immersed batteries, etc., can solve the problems of complex preparation methods, low battery energy density, poor performance, etc., and achieves a variety of , Easy to process, easy to use and quick effect

Active Publication Date: 2019-01-18
南京径祥新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] Aiming at the problems that the preparation method of the existing magnesium cuprous chloride battery is complicated, and the energy density of the battery is low, and the use performance is not good, the present invention provides a high-capacity magnesium seawater battery cuprous chloride positive electrode piece forming process and the resulting battery , using a convenient and easy-to-operate pole piece preparation process, with high production efficiency, high pole piece strength and long life; the prepared pole pieces are assembled into seawater batteries, and their energy density is relatively high, which meets the requirements of performance

Method used

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  • A high-capacity magnesium seawater battery cuprous chloride positive electrode sheet molding process and an obtained battery

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Effect test

Embodiment 1

[0039] A high-capacity magnesium seawater battery cuprous chloride positive pole piece forming process of the present embodiment comprises the following steps:

[0040] (1) Preparation of raw materials: take 80% cuprous chloride powder by mass fraction, then weigh 8% conductive graphite and 2% carbon nanotubes respectively by mass fraction, put them into a high-speed mixer together, and stir for 10 minutes; Add deionized water to the mixed raw materials, stir for 10 minutes, and solidify the mixed raw materials; take out the mixed raw materials, put them into the material kneading equipment, add deionized water, and knead at a low speed for 40 minutes; weigh 10% poly Tetrafluoroethylene: add polytetrafluoroethylene into the kneading equipment for kneading, and add 20% deionized water according to the mass fraction of the mixed material, and continue kneading for a certain period of time to obtain a mixture with a certain viscosity;

[0041] (2) Electrode preparation: set the o...

Embodiment 2

[0046] Raw material preparation and diaphragm preparation are the same as other steps in Example 1; except that 95% cuprous chloride powder is weighed by mass fraction, and then 2% KS-6 and 1% carbon nanotubes are weighed by mass fraction, and Fractions were weighed out of 3% PTFE.

[0047] The cuprous chloride electrode that obtains in embodiment 2 is cut into size and is 45mm*55mm*1.5mm (thick), forms the Mg-CuCl seawater battery with the magnesium alloy of the same size magnesium sheet and AZ series Mg-Al-Zn, The electrolyte is 3% sodium chloride solution, and the battery is made into a positive and negative power generation device, and the test results are consistent with those in Example 1.

Embodiment 3

[0049] Raw material preparation and diaphragm preparation are the same as the other steps of Example 1; except that 70% cuprous chloride powder is weighed by mass fraction, and then 12% SP and 3% carbon nanotubes are weighed by mass fraction, and put into research together. In the bowl, continue to grind for 40 minutes; add deionized water to the mixed raw materials, grind for 20 minutes, weigh 15% polytetrafluoroethylene according to the mass fraction, and solidify the mixed raw materials.

[0050] The cuprous chloride electrode that obtains in embodiment 3 is cut size to be 45mm*55mm*1.5mm (thick), and the magnesium alloy of magnesium sheet and AZ series Mg-Al-Zn of the same size forms Mg-CuCl seawater battery, The electrolyte is 3% sodium chloride solution, and the battery is made into a positive and negative power generation device, and the test results are consistent with those in Example 1.

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Abstract

The invention discloses a high-capacity magnesium seawater battery cuprous chloride positive electrode sheet molding process and a battery, and belongs to the technical field of battery materials. 70to 95 percent of cuprous chloride power and 3 to 20 percent of conductive carbon material are weighed according to that mass fraction of the cuprous chloride positive electrode sheet molding process of the high-capacity magnesium seawater battery, 2 to 15 percent of bind material is weighed according to that mass fraction after stirring and solidification, and added into the mixed material to obtain a mixture with a certain viscosity, and the cuprous chloride positive electrode sheet is prepared through a rolling and baking process. The production efficiency is improved to a great extent by adopting the convenient and easy-to-operate production technology. The active material content in the positive electrode sheet is relatively high, and proper amount of conductive agent and binder are added to the positive electrode sheet, and the processes such as high-speed mixing, powder state solidification, raw material mixing, membrane preparation and electrode sheet molding are carried out, sothat the electrode sheet has high strength and long service life, and the energy density of the battery electrode sheet and the performance of the battery electrode sheet are improved.

Description

technical field [0001] The invention belongs to the technical field of battery materials, and more specifically relates to a forming process of a cuprous chloride positive pole piece of a high-capacity magnesium seawater battery and the resulting battery. Background technique [0002] At present, the global demand for energy is increasing day by day, causing massive consumption of non-renewable energy, and the problems of environmental pollution and energy shortage are becoming more and more prominent. Research and development of cleaner and more efficient green energy has become a national solution to energy, environment, society and economy. important means of problem. At present, the development of marine equipment and the field of water rescue are booming in China, and seawater batteries are gradually getting attention. The positive electrode materials of seawater batteries mainly use noble metal salt electrodes such as silver chloride, cuprous chloride, and cuprous iodi...

Claims

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Application Information

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IPC IPC(8): H01M4/08H01M4/58H01M6/34
CPCH01M4/08H01M4/582H01M6/34
Inventor 宋广生丁波
Owner 南京径祥新材料科技有限公司