Method of isolating and detecting related components of Shenqi Fuzheng injection
A technology of Shenqi Fuzheng and injection, applied in the fields of analytical chemistry and natural product chemistry, to achieve the effects of fast reaction, simple operation and stable repeatability
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Embodiment 1
[0075] Example 1 Codonopsis pilosula extract (including alcohol) total ion current chromatogram (TIC) and extracted ion diagram (EIC)
[0076] Take about 10g of Codonopsis pilosula and extract with 100ml, 80ml, 70ml of water, heating for 1h, 1h, 0.5h. Combine the three extracts and concentrate them with 75% and 85% ethanol and two alcohol precipitation to obtain.
[0077] Weigh about 5 g of polyamide, degas with 95% ethanol, and pack it into a column (the column height is about 10 cm, and the inner diameter is 1 cm). After activation with 40 ml of 5% sodium hydroxide and 80 ml of 10% glacial acetic acid in turn, wash with water for injection until it is neutral. Precisely measure 25ml of the above-prepared Codonopsis pilosula extract and load the sample onto the activated polyamide chromatography column, and eluate with 80ml of water, 80ml of 20% ethanol, and 80ml of 60% ethanol. Receive the 60% ethanol eluate, evaporate to dryness in a water bath, and dissolve the residue with...
Embodiment 2
[0090] Example 2 Mass spectrum total ion chromatogram (TIC) and extracted ion diagram (EIC) of Astragalus extract
[0091] Take about 10g of Astragalus medicinal material, and extract with 100ml, 80ml, 70ml of water, heating for 1h, 1h, 0.5h. Combine the three extracts and concentrate them with 75% and 85% ethanol and two alcohol precipitation to obtain.
[0092] Weigh about 5 g of polyamide, degas with 95% ethanol, and pack it into a column (the column height is about 10 cm, and the inner diameter is 1 cm). After activation with 40 ml of 5% sodium hydroxide and 80 ml of 10% glacial acetic acid in turn, wash with water for injection until it is neutral. Precisely measure 25ml of the above-prepared astragalus extract and apply it to the activated polyamide chromatography column, eluting with 80ml of water, 80ml of 20% ethanol and 80ml of 60% ethanol. Receive the 60% ethanol eluate, evaporate to dryness in a water bath, and dissolve the residue with 60% ethanol and dilute to 25ml...
Embodiment 3
[0096] Example 3 TIC and EIC profiles of representative components of Astragalus and Codonopsis
[0097] Accurately weigh about 5 mg of Codonopsis, 12.5 mg of Isoflavone Glucoside and 10 mg of Astragaloside IV in water, 30% methanol, and methanol to prepare 1 mg / ml, 5 μg / ml, and 0.01 mg / ml solutions. Component analysis using LC-MS:
[0098] Chromatographic conditions, mass spectrometry conditions and determination methods: the same as in Example 1;
[0099] See the maps separately image 3 , Figure 4 with Figure 5 .
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