Mask blank, phase shift mask, half-tone mask, mask blank manufacturing method, and phase shift mask manufacturing method
A manufacturing method and a phase-shift mask technology, which are applied in the field of mask blanks, can solve the problems of increased number of manufacturing processes, decreased production efficiency, high-volume manufacturing of phase-shift masks, etc., so as to reduce the number of manufacturing processes and shorten the The effect of reducing production time and workload
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[0175] Next, examples according to the present invention will be described.
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[0177] In order to confirm the above-mentioned effect, the following experiments were performed. That is, on the glass substrate S, a chromium oxynitride film constituting the phase shift layer 11 was formed to a thickness of 122.0 nm by sputtering, and a Ni—Ti—Nb— The Mo film was formed to have a total thickness of about 105.0 nm, and a film composed of a layer mainly composed of chromium oxynitride and a layer mainly composed of chromium oxynitride carbide constituting the light shielding layer 13 was formed to obtain a mask blank MB.
[0178] At this time, the etching stop layer 12 is formed to contain carbon, and the film is formed under the condition that methane and carbon dioxide are contained as the sputtering gas, and the sputtering gas contains NiO x Tr method for film formation.
[0179] In addition, nitrogen gas (N 2 )conditions of.
[0180] A resist pattern PR1 is formed on the mask blank MB, and the light shielding layer 13, the etching stopper layer 12, and t...
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