A kind of preparation method of normal temperature self-repairing water-based polyurethane car cover with self-extinguishing effect
A technology of water-based polyurethane and production method, applied in the direction of polyurea/polyurethane coatings, coatings, etc., can solve the problems of inability to meet the individual needs of different consumers, damaged appearance, unfriendly environment, etc., and achieve good normal temperature self-healing function , The effect of excellent weather resistance
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Embodiment 1
[0025] [Example 1] Pour 50 parts of vacuum dehydrated polycarbonate diol into a three-necked flask, blow nitrogen into it, add 35 parts of isophorone diisocyanate, 10 parts of hexamethylene diisocyanate trimer, 0.2 Dibutyltin dilaurate catalyst, react at 85°C for 2h, cool down to 50°C, add 4 parts of dimethylolpropionic acid, 30 parts of acetone, 5 parts of N-methylpyrrolidone, heat up to 65°C, react for 1h, keep the temperature No change, add 2 parts of 1,4-butanediol, 5.5 parts of diaminodiphenyl disulfide, 1.5 parts of trimethylolpropane, react for 3 hours, cool down to 45°C, pour into a high-speed disperser, add 30 parts Dilute with acetone, add 3 parts of triethylamine to neutralize for 3 minutes, adjust the speed of the disperser to 2500r / min, quickly add deionized water to emulsify and disperse, and then add 3 parts of deionized water diluted ethylenediamine aqueous solution. After reacting for 30 minutes, heat to 50°C to evaporate excess solvent under reduced pressure ...
Embodiment 2
[0027] [Example 2] Pour 40 parts of vacuum dehydrated polycarbonate diol into a three-necked flask, blow nitrogen into it, add 30 parts of 4,4'-dicyclohexylmethane diisocyanate, 19 parts of hexamethylene diisocyanate Trimer, 0.3 parts of organic bismuth catalyst, react at 85°C for 2 hours, cool down to 50°C, add 4.5 parts of dimethylolpropionic acid, 30 parts of acetone, 5 parts of N-methylpyrrolidone, heat up to 65°C, react for 1 hour, Keep the temperature constant, add 1.5 parts of 1,4-butanediol, 4 parts of dihydroxy diethylthiuram disulfide, 2 parts of trimethylolpropane, react for 3 hours, cool down to 45 ° C, pour into a high-speed disperser Inside, add 30 parts of acetone for dilution, add 3.3 parts of triethylamine for neutralization for 3 minutes, adjust the speed of the disperser to 2500r / min, quickly add deionized water for emulsification and dispersion, and then add 1.5 parts of deionized water diluted ethylenediamine aqueous solution. After reacting for 40 minutes...
Embodiment 3
[0029][Example 3] Pour 70 parts of vacuum dehydrated polycarbonate diol into a three-necked flask, blow nitrogen into it, add 40 parts of isophorone diisocyanate, 15 parts of hexamethylene diisocyanate trimer, 0.3 Parts of organic bismuth catalyst, reacted at 85°C for 2 hours; cooled to 50°C, added 5 parts of dimethylolpropionic acid, 30 parts of acetone, 5 parts of N-methylpyrrolidone, raised the temperature to 65°C, reacted for 1 hour; kept the temperature unchanged, Add 1.5 parts of 1,4-butanediol, 2 parts of trimethylolpropane, and 9 parts of dihydroxy diethylthiuram disulfide to react for 3 hours; cool down to 45°C, pour into a high-speed disperser, and add 30 parts of acetone Dilute, add 4 parts of triethylamine to neutralize for 3 minutes, adjust the speed of the disperser to 2500r / min, quickly add deionized water to emulsify and disperse, and then add 2 parts of diethylenetriamine aqueous solution diluted with deionized water. After reacting for 50 minutes, heat to 50°...
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