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A kind of preparation method of normal temperature self-repairing water-based polyurethane car cover with self-extinguishing effect

A technology of water-based polyurethane and production method, applied in the direction of polyurea/polyurethane coatings, coatings, etc., can solve the problems of inability to meet the individual needs of different consumers, damaged appearance, unfriendly environment, etc., and achieve good normal temperature self-healing function , The effect of excellent weather resistance

Active Publication Date: 2020-11-03
成都德科立高分子材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the car cover can only be used to protect the car paint. When the car has scratches and other problems, the appearance will be damaged, and it cannot provide repair and other functions.
The Chinese patent with publication number CN108059896A discloses a method for preparing high-temperature self-repairing car coverings. The method uses acrylic resin as a matrix and adds microcapsules containing liquid acrylic resin to realize the self-repairing function. However, the microcapsules used in this invention Technology can only achieve a single repair of the same part
The Chinese patent with publication number CN108084861A discloses a protective film with self-repairing and oil-proof function. The protective film is coated with solvent-based polyurethane on the release film, and the ultraviolet blocking pressure-sensitive adhesive is used to realize the pasting function. The method is prepared Although the protective film has a good repair function, a lot of solvents are used in the construction process, which is very unfriendly to the environment
In addition, the current car covering materials are basically transparent and high-gloss protective films, which are glaring under natural light and cannot meet the individual needs of different consumers.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] [Example 1] Pour 50 parts of vacuum dehydrated polycarbonate diol into a three-necked flask, blow nitrogen into it, add 35 parts of isophorone diisocyanate, 10 parts of hexamethylene diisocyanate trimer, 0.2 Dibutyltin dilaurate catalyst, react at 85°C for 2h, cool down to 50°C, add 4 parts of dimethylolpropionic acid, 30 parts of acetone, 5 parts of N-methylpyrrolidone, heat up to 65°C, react for 1h, keep the temperature No change, add 2 parts of 1,4-butanediol, 5.5 parts of diaminodiphenyl disulfide, 1.5 parts of trimethylolpropane, react for 3 hours, cool down to 45°C, pour into a high-speed disperser, add 30 parts Dilute with acetone, add 3 parts of triethylamine to neutralize for 3 minutes, adjust the speed of the disperser to 2500r / min, quickly add deionized water to emulsify and disperse, and then add 3 parts of deionized water diluted ethylenediamine aqueous solution. After reacting for 30 minutes, heat to 50°C to evaporate excess solvent under reduced pressure ...

Embodiment 2

[0027] [Example 2] Pour 40 parts of vacuum dehydrated polycarbonate diol into a three-necked flask, blow nitrogen into it, add 30 parts of 4,4'-dicyclohexylmethane diisocyanate, 19 parts of hexamethylene diisocyanate Trimer, 0.3 parts of organic bismuth catalyst, react at 85°C for 2 hours, cool down to 50°C, add 4.5 parts of dimethylolpropionic acid, 30 parts of acetone, 5 parts of N-methylpyrrolidone, heat up to 65°C, react for 1 hour, Keep the temperature constant, add 1.5 parts of 1,4-butanediol, 4 parts of dihydroxy diethylthiuram disulfide, 2 parts of trimethylolpropane, react for 3 hours, cool down to 45 ° C, pour into a high-speed disperser Inside, add 30 parts of acetone for dilution, add 3.3 parts of triethylamine for neutralization for 3 minutes, adjust the speed of the disperser to 2500r / min, quickly add deionized water for emulsification and dispersion, and then add 1.5 parts of deionized water diluted ethylenediamine aqueous solution. After reacting for 40 minutes...

Embodiment 3

[0029][Example 3] Pour 70 parts of vacuum dehydrated polycarbonate diol into a three-necked flask, blow nitrogen into it, add 40 parts of isophorone diisocyanate, 15 parts of hexamethylene diisocyanate trimer, 0.3 Parts of organic bismuth catalyst, reacted at 85°C for 2 hours; cooled to 50°C, added 5 parts of dimethylolpropionic acid, 30 parts of acetone, 5 parts of N-methylpyrrolidone, raised the temperature to 65°C, reacted for 1 hour; kept the temperature unchanged, Add 1.5 parts of 1,4-butanediol, 2 parts of trimethylolpropane, and 9 parts of dihydroxy diethylthiuram disulfide to react for 3 hours; cool down to 45°C, pour into a high-speed disperser, and add 30 parts of acetone Dilute, add 4 parts of triethylamine to neutralize for 3 minutes, adjust the speed of the disperser to 2500r / min, quickly add deionized water to emulsify and disperse, and then add 2 parts of diethylenetriamine aqueous solution diluted with deionized water. After reacting for 50 minutes, heat to 50°...

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PUM

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Abstract

The invention discloses a method for making a normal-temperature self-repairing water-based polyurethane car covering with a self-extinction effect. First, polycarbonate diol is poured into a reaction container, and polyisocyanate and a catalyst are slowly added to obtain a prepolymer I; Add hydrophilic chain extender and solvent, add small molecule chain extender and crosslinking agent, and react to obtain prepolymer II; pour into high-speed disperser, add neutralizer, add deionized water to disperse and emulsify, and quickly pour into Polyamine post-chain extender diluted with ionized water to obtain polyurethane emulsion. Add defoamer, leveling agent, wetting agent, film-forming aid, and thickener to the disperser, and slowly add water-based polyurethane emulsion to obtain water-based polyurethane car coating emulsion, and the spraying is completed. The car cover of the present invention has a good normal temperature self-repair function, and at the same time provides different gloss levels and excellent weather resistance. After the resin is compounded with additives, it is sprayed on the surface of the car, which can protect the paint surface of the car for a long time. Can be stripped.

Description

technical field [0001] The invention relates to the field of self-repairing materials, in particular to the synthesis of a normal-temperature self-repairing water-based polyurethane emulsion with a self-extinction effect, and also to a preparation method of a self-delustering normal-temperature self-repairing car cover. Background technique [0002] With the improvement of the domestic economic level and the accelerated urban expansion year by year, more and more people choose to buy private cars as a means of travel. By the end of 2017, the number of cars in the country was 217 million. Passenger cars (private cars) reached 170 million, accounting for 91.89% of passenger cars. The huge automobile market has also brought huge business opportunities for automobile clothing. [0003] At present, the car covers on the market mainly use the film method to protect the car. By brushing the pressure-sensitive adhesive on the film materials (PVC, PU and PU) for pasting, the prepare...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D175/04C08G18/66C08G18/44C08G18/10C08G18/34C08G18/32
CPCC08G18/10C08G18/44C09D175/04C08G18/348C08G18/3206C08G18/3868
Inventor 盖静刘世勇戴江臻
Owner 成都德科立高分子材料有限公司
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