Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Production method of room-temperature self-repairing type waterborne polyurethane car cover with self-extinction effect

A technology of water-based polyurethane and its production method, which is applied in the direction of polyurea/polyurethane coating, coating, etc., can solve the problems of unable to meet the individual needs of different consumers, damaged appearance, glare, etc., and achieve good self-healing function at room temperature and weather resistance excellent effect

Active Publication Date: 2019-03-26
成都德科立高分子材料有限公司
View PDF6 Cites 10 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the car cover can only be used to protect the car paint. When the car has scratches and other problems, the appearance will be damaged, and it cannot provide repair and other functions.
The Chinese patent with publication number CN108059896A discloses a method for preparing high-temperature self-repairing car coverings. The method uses acrylic resin as a matrix and adds microcapsules containing liquid acrylic resin to realize the self-repairing function. However, the microcapsules used in this invention Technology can only achieve a single repair of the same part
The Chinese patent with publication number CN108084861A discloses a protective film with self-repairing and oil-proof function. The protective film is coated with solvent-based polyurethane on the release film, and the ultraviolet blocking pressure-sensitive adhesive is used to realize the pasting function. The method is prepared Although the protective film has a good repair function, a lot of solvents are used in the construction process, which is very unfriendly to the environment
In addition, the current car covering materials are basically transparent and high-gloss protective films, which are glaring under natural light and cannot meet the individual needs of different consumers.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] [Example 1] Pour 50 parts of vacuum dehydrated polycarbonate diol into a three-necked flask, blow nitrogen into it, add 35 parts of isophorone diisocyanate, 10 parts of hexamethylene diisocyanate trimer, 0.2 Dibutyltin dilaurate catalyst, react at 85°C for 2h, cool down to 50°C, add 4 parts of dimethylolpropionic acid, 30 parts of acetone, 5 parts of N-methylpyrrolidone, heat up to 65°C, react for 1h, keep the temperature No change, add 2 parts of 1,4-butanediol, 5.5 parts of diaminodiphenyl disulfide, 1.5 parts of trimethylolpropane, react for 3 hours, cool down to 45°C, pour into a high-speed disperser, add 30 parts Dilute with acetone, add 3 parts of triethylamine to neutralize for 3 minutes, adjust the speed of the disperser to 2500r / min, quickly add deionized water to emulsify and disperse, and then add 3 parts of deionized water diluted ethylenediamine aqueous solution. After reacting for 30 minutes, heat to 50°C to evaporate excess solvent under reduced pressure ...

Embodiment 2

[0027] [Example 2] Pour 40 parts of vacuum dehydrated polycarbonate diol into a three-necked flask, blow nitrogen into it, add 30 parts of 4,4'-dicyclohexylmethane diisocyanate, 19 parts of hexamethylene diisocyanate Trimer, 0.3 parts of organic bismuth catalyst, react at 85°C for 2 hours, cool down to 50°C, add 4.5 parts of dimethylolpropionic acid, 30 parts of acetone, 5 parts of N-methylpyrrolidone, heat up to 65°C, react for 1 hour, Keep the temperature constant, add 1.5 parts of 1,4-butanediol, 4 parts of dihydroxy diethylthiuram disulfide, 2 parts of trimethylolpropane, react for 3 hours, cool down to 45 ° C, pour into a high-speed disperser Inside, add 30 parts of acetone for dilution, add 3.3 parts of triethylamine for neutralization for 3 minutes, adjust the speed of the disperser to 2500r / min, quickly add deionized water for emulsification and dispersion, and then add 1.5 parts of deionized water diluted ethylenediamine aqueous solution. After reacting for 40 minutes...

Embodiment 3

[0029][Example 3] Pour 70 parts of vacuum dehydrated polycarbonate diol into a three-necked flask, blow nitrogen into it, add 40 parts of isophorone diisocyanate, 15 parts of hexamethylene diisocyanate trimer, 0.3 Parts of organic bismuth catalyst, reacted at 85°C for 2 hours; cooled to 50°C, added 5 parts of dimethylolpropionic acid, 30 parts of acetone, 5 parts of N-methylpyrrolidone, raised the temperature to 65°C, reacted for 1 hour; kept the temperature unchanged, Add 1.5 parts of 1,4-butanediol, 2 parts of trimethylolpropane, and 9 parts of dihydroxy diethylthiuram disulfide to react for 3 hours; cool down to 45°C, pour into a high-speed disperser, and add 30 parts of acetone Dilute, add 4 parts of triethylamine to neutralize for 3 minutes, adjust the speed of the disperser to 2500r / min, quickly add deionized water to emulsify and disperse, and then add 2 parts of diethylenetriamine aqueous solution diluted with deionized water. After reacting for 50 minutes, heat to 50°...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a production method of a room-temperature self-repairing type waterborne polyurethane car cover with a self-extinction effect. The production method comprises the following steps: firstly, pouring polycarbonate diol into a reaction container; slowly adding polyisocyanate and a catalyst to obtain a pre-polymer I; adding a hydrophilic chain-extending agent and a solvent; adding a small molecular chain-extending agent and a crosslinking agent and reacting to obtain a pre-polymer II; pouring into a high-speed dispersion device and adding a neutralizing agent; adding de-ionized water and dispersing and emulsifying; rapidly pouring a polyamine chain-extending agent diluted by the de-ionized water to obtain polyurethane emulsion; adding a de-foaming agent, a leveling agent, a wetting agent, a film-forming auxiliary agent and a thickening agent into a dispersion device; slowly adding the waterborne polyurethane emulsion to obtain waterborne polyurethane car cover emulsion and finishing spray coating. The car cover provided by the invention has a good room-temperature self-repairing function and also provides different glossiness and excellent weather resistance; after resin is compounded with the auxiliary agent, a mixture is sprayed on the surface of a car; a paint surface of the car can be protected for a long time and can be stripped at any time.

Description

technical field [0001] The invention relates to the field of self-repairing materials, in particular to the synthesis of a normal-temperature self-repairing water-based polyurethane emulsion with a self-extinction effect, and also to a preparation method of a self-delustering normal-temperature self-repairing car cover. Background technique [0002] With the improvement of the domestic economic level and the accelerated urban expansion year by year, more and more people choose to buy private cars as a means of travel. By the end of 2017, the number of cars in the country was 217 million. Passenger cars (private cars) reached 170 million, accounting for 91.89% of passenger cars. The huge automobile market has also brought huge business opportunities for automobile clothing. [0003] At present, the car covers on the market mainly use the film method to protect the car. By brushing the pressure-sensitive adhesive on the film materials (PVC, PU and PU) for pasting, the prepare...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C09D175/04C08G18/66C08G18/44C08G18/10C08G18/34C08G18/32
CPCC08G18/10C08G18/44C09D175/04C08G18/348C08G18/3206C08G18/3868
Inventor 盖静刘世勇戴江臻
Owner 成都德科立高分子材料有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products