A method for controlling heavy metals in river sludge
A heavy metal and sludge technology, which is applied in the direction of sludge treatment, alkali metal compounds, chemical instruments and methods, etc., can solve the problems of strict growth environment requirements, high cost, and short stabilization time, so as to prevent secondary pollution and improve Effect of specific surface area and improvement of adsorption rate
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Embodiment 1
[0025] A method for combined treatment of river sludge heavy metals, comprising the following steps:
[0026] (1) Mix peanut shells and straw at a ratio of 1:1, soak in river water at a temperature of 25°C, and an oscillation speed of 20 r min -1 , sealed and shaken for 30 days; filtered, dried, and ground to obtain a mixed residue.
[0027] (2) Take 50g of clay minerals passed through a 100-mesh sieve and 150ml of 0.1mol / L HCl in a 500ml volumetric flask, so that the hydrochloric acid and the mixed residue can be fully mixed, sealed and shaken for 30min, centrifugally dried and ground; take 3ml Chlorosulfonic acid was dropped into 5ml of chloroform at a constant pressure, and then 1g of the above-mentioned clay mineral was added thereto, stirred on a constant magnetic stirrer for 2h at a temperature of 30°C, and subjected to sulfonation modification treatment; the filtrate was removed, and Washing with ionic water three times, drying, and grinding to obtain modified clay min...
Embodiment 2
[0035] Take by weight the modified clay mineral that is 20 parts by weight, the modified fly ash of 50 parts by weight, the modified residue of 20 parts by weight, and the cross-linking agent of 10 parts by weight and fully mix with a ball mill to obtain river sludge Heavy metal adsorbent pellets;
[0036] Take 1g of adsorbent pellets and add them to 10ml of 100mg / L Cd, Cu, Cr, Pb contamination solution respectively, 100r min -1 Rotate for 2 hours, filter, and measure the concentration of heavy metals in the contaminated solution after adsorption. The removal rates of Cd, Cu, Cr, and Pb are 88.6%, 80.3%, 60.1%, and 75.4%, respectively.
Embodiment 3
[0038] Take by weight the modified clay mineral that is 25 parts by weight, the modified fly ash of 40 parts by weight, the modified residue of 25 parts by weight, and the cross-linking agent of 10 parts by weight and utilize ball mill to fully mix to make river sludge Heavy metal adsorbent pellets;
[0039] Take 1g of adsorbent pellets and add them to 10ml of 100mg / L Cd, Cu, Cr, Pb contaminated solution respectively, 100r min -1 Rotate for 2 hours, filter, and measure the heavy metal concentration of the contaminated solution after adsorption. The removal rates of Cd, Cu, Cr, and Pb are 92.1%, 86.7%, 90.5%, and 88.9%, respectively.
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