Method for producing high octane gasoline through naphtha

A high-octane gasoline and naphtha technology, which is applied in the petroleum industry, hydrocarbon oil treatment products, and hydrocarbon oil treatment, can solve unrelated problems and achieve the goal of increasing gasoline yield, optimizing gasoline composition, and increasing content Effect

Active Publication Date: 2019-04-26
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

But none of the above methods involves the original methylcyclopentane (RON=91.3), 2,2-dimethylpentane (RON=92.8), 2,4-dimethylpentane (

Method used

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  • Method for producing high octane gasoline through naphtha
  • Method for producing high octane gasoline through naphtha
  • Method for producing high octane gasoline through naphtha

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[0029] In one embodiment, the catalytic reforming catalyst is prepared by a conventional method. Specifically, a shaped inorganic oxide support may be prepared first, such as a spherical or striped type, and then impregnated to introduce the first metal component and halogen. The catalyst contains the second metal component and / or the third metal component. Preferably, the second metal component and / or the third metal component are introduced into the carrier first, and finally the first metal component and halogen are introduced to introduce all The carrier after the metal components is dried and calcined at 450-650°C to obtain the catalytic reforming catalyst in the oxidation state. The oxidized catalytic reforming catalyst needs to be reduced in a hydrogen-containing atmosphere at 315-650°C before use to obtain a reduced catalytic reforming catalyst.

[0030] In the present invention, the second fractionation in step (4) is used to obtain a second light fraction, a methylcyclo...

Example Embodiment

[0050] Instance

[0051] (1) Hydrorefining of naphtha raw materials.

[0052] In a 20 ml fixed-bed continuous flow reactor, 20 ml of hydrorefining catalyst A is charged. On a dry basis, the hydrorefining catalyst A contains 0.03% by mass of CoO, 2.0% by mass of NiO, and 18.5% by mass of WO 3 , 0.5% by mass of Cl and 78.97% by mass of Al 2 O 3 .

[0053] The composition and properties of the naphtha feedstock shown in Table 1 are set at 290℃, pressure 2.0MPa, hydrogen / hydrocarbon volume ratio 200:1, and feed volume space velocity is 8.0h -1 Under the above conditions, it is passed into the reactor filled with catalyst A for hydrorefining. The reaction product is sent to a water cooler, separated into two phases of gas and liquid, respectively measured and analyzed for composition. The composition and properties of the hydrorefined naphtha obtained after hydrorefining are shown in Table 2.

[0054] (2) The first fractionation of hydrofining naphtha.

[0055] The hydrorefined naphtha in s...

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Abstract

The invention relates to the method for producing high octane gasoline through naphtha. The method includes the steps that a naphtha raw material is subjected to hydrorefining, first fractionation andsecond fractionation, methyl cyclopentane, cyclohexane and multi-branched alkane in the naphtha are directly separated to be used as gasoline components, then a first heavy fraction obtained in firstfractionation is subjected to catalytic reforming, and a second light fraction obtained in second fractionation is subjected to an isomerization reaction to obtain gasoline components. According to the method for producing the high octane gasoline through the naphtha, the gasoline yield can be increased, gasoline compositions are optimized, the contents of iso-alkane and cycloalkane in the gasoline are increased, and the contents of arene and normal-alkane are decreased.

Description

technical field [0001] The invention relates to a method for producing high-octane gasoline from naphtha. Background technique [0002] Modern car engines require gasoline with a high octane rating. Aromatics and olefins are important high-octane gasoline blending components, but aromatics and olefins are not easy to burn completely, and will enter the atmosphere with vehicle exhaust, which is one of the important factors causing air pollution. Due to environmental issues, the restrictions on olefins and aromatics in high-octane gasoline are becoming more and more stringent. Multi-branched isoparaffins and certain cycloalkanes such as methylcyclopentane not only have a higher octane number, but also burn relatively completely. As the "ultimate blending component" for future gasoline upgrades, their role is becoming increasingly prominent. [0003] Naphtha is a mixture of various hydrocarbons such as normal paraffins, isoparaffins, naphthenes and aromatics. Naphtha can be ...

Claims

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Application Information

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IPC IPC(8): C10G67/16
CPCC10G67/16C10G2300/305C10G2400/02
Inventor 刘洪全马爱增张秋平于中伟
Owner CHINA PETROLEUM & CHEM CORP
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