53results about How to "High thermal and hydrothermal stability" patented technology

The invention discloses a light oil type hydrocracking catalyst with a composite molecular sieve. The hydrocracking catalyst comprises the composite molecular sieve consisting of a modified Y-molecular sieve and a modified ZSM-23 molecular sieve, a carrier composed of micropore aluminum oxides, and a hydrogenation activity component composed of a VIB group metal and a VIII group metal. The hydrocracking catalyst is characterized in that the composite molecular sieve comprises the modified Y-molecular sieve and the modified ZSM-23 molecular sieve, and the Y-molecular sieve is modified and dealuminized, so that heat stability and hydrothermal stability are stably enhanced, the hydrophobicity is enhanced, the absorption and desorption properties of the molecular sieve are improved, and the catalyst achieves a high catalytic cracking property. The pore passages of the modified SM-23 molecular sieve are unobstructed, the number of the acid sites is small, the isomerism property is outstanding, and the octane value of the molecular sieve is increased because of light naphtha components. The modified Y-molecular sieve and the modified ZSM-23 molecular sieve are mixed and used according to a formula ratio of the hydrocracking catalyst, so that both the cracking activity and the isomerism property are considered, and the final catalyst achieves an ideal catalytic effect.

The invention relates to a super-stable Y-type molecular sieve containing phosphorus and rare earth, wherein the Y-type molecular sieve contains 4-11 wt% of rare earth, 0.05-10 wt% of phosphorus and 0.1-0.7 wt% of sodium oxide, and has the pore volume of 0.33-0.39 mL / g, the pore volume of the pores with the pore size of 2-100 nm accounts for 15-30% of the total pore volume, the unit cell constantis 2.440-2.455 nm, the non-framework aluminum accounts for less than 20% of the total aluminum, the lattice collapse temperature is more than 1050 DEG C, and a ratio of the amount of B acid to the amount of L acid is not less than 2.50. The preparation method comprises: preparing a rare earth-containing Y-type molecular sieve having a conventional unit cell size, calcining for 4.5-7 h at a temperature of 350-480 DEG C under 30-90% by volume of steam atmosphere, carrying out phosphorus modification treatment, and carrying out a contact reaction with silicon tetrachloride gas. According to the present invention, the Y-type molecular sieve has advantages of good hydrothermal stability, high heavy oil conversion activity, low coke selectivity, high heavy oil conversion diesel yield, high liquefied gas yield and high total liquid recovery.

A catalytic cracking catalyst has a rare earth modified Y-type molecular sieve, an additive-containing alumina binder, and a clay. The rare earth modified Y-type molecular sieve has a rare earth oxide content of about 4-12 wt %, a phosphorus content of about 0-10 wt %, a sodium oxide content of no more than about 1.0 wt %, a total pore volume of about 0.36-0.48 mL / g, a percentage of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 20-40%, a lattice constant of about 2.440-2.455 nm, a percentage of non-framework aluminum content to the total aluminum content of no more than about 10%, a lattice collapse temperature of not lower than about 1060° C., and a ratio of B acid to L acid in the total acid content of the modified Y-type molecular sieve of no less than about 3.50.

The invention relates to a method for directly synthesizing a multi-stage ordered mesoporous molecular sieve, which comprises the following steps that: a silicon source, an aluminum source, water and template agent are mixed to obtain a mixture; an alkali source and surfactant are added into the mixture, and a gel mixture is obtained; and the gel mixture is moved into a synthesis reactor to be sealed and subjected to crystallization reaction, washed, dried and calcinated, and the multi-stage ordered mesoporous molecular sieve is obtained. The method has the advantages of simple process and reduced production cost, and is applicable to industrialized production. The synthesized molecular sieve has the advantages of high-order mesopores, higher mechanical strength, good hydrothermal stability, and can be used in petroleum chemical industry, fine preparation of chemicals, environmental catalysis and other fields.

The invention relates to a preparation method of a cracking catalyst, which comprises: raw materials and water are mixed to prepare a slurry solution by utilizing the catalyst containing a Y type molecular sieve and a silicon vector; the slurry solution is dried to obtain a catalyst precursor; the catalyst precursor is baked; and a contact reaction is carried out on the catalyst precursor and an acidic ammonium salt solution. The preparation method of the cracking catalyst can enhance the crystallization retaining degree of the Y type molecular sieve in the catalyst and the stability of the catalyst. The catalyst prepared by utilizing the method is used for the catalytic cracking of heavy oil and has the advantages of strong conversion capability of the heavy oil, high yield of gasoline, and low sulphur content in the gasoline.

The invention provides a catalytic cracking catalyst. The catalytic cracking catalyst contains clay, an alumina binder and a modified Y type molecular sieve. The modified Y type molecular sieve comprises 5 to 12 wt% of rare earth and no more than 0.5 wt% of sodium oxide, and has a total pore volume of 0.36 to 0.48 mL / g; the pore volume of secondary pores accounts for 20 to 38% of the total pore volume; a lattice constant is 2.440 nm to 2.455 nm; the content of non-framework aluminum is no more than 10% of total aluminum content; lattice collapse temperature is higher than 1060 DEG C; and a ratio of the amount of acid B to the amount of acid L is no less than 3.50. A preparation method for the catalytic cracking catalyst comprises the following steps: preparing a rare earth-containing Y type molecular sieve with a conventional cell size; carrying out roasting in a water vapor atmosphere with a temperature of 350 to 520 DEG C and a volume percentage of 30 to 95% for 4.5 to 7 h; carryingout a contact reaction with silicon tetrachloride; and carrying out acid treatment. The catalyst has higher heavy oil conversion activity, low coke selectivity, and higher gasoline yield, liquefied gas yield, light oil yield and total liquid yield.