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Flame-retardant HIPS material and preparation method thereof

An antimony-based flame retardant and auxiliary flame retardant technology is applied in the field of flame retardant HIPS materials and their preparation, which can solve the problems of high material cost and processing energy consumption, restrictions on wide use and promotion, poor thermal stability of materials, etc. Halogen content, low density, less corrosive effect

Active Publication Date: 2019-05-03
KINGFA SCI & TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] There are two types of flame-retardant HIPS technology at present, one is a halogen-free flame-retardant system, and the other is a halogen-free flame-retardant system. The halogen-free flame-retardant system is more environmentally friendly, less corrosive to molds, and has less gas. However, it has high material cost and processing energy consumption, which limits the wide use and promotion in the market; the usual halogenated flame retardant HIPS materials contain HIPS resin halogenated flame retardants, antimony oxides or salts, anti-dripping agents , as well as necessary processing aids such as antioxidant lubricants, can produce products with a balance of rigidity, fluidity and toughness
However, due to the high content of halogen-based flame retardants, the thermal stability of the material is poor, resulting in the thermal decomposition of the material during the molding process will produce more hydrogen halide gas, this acid gas will have a greater impact on the mold Corrosive, causing molds to be replaced frequently, thus increasing production costs

Method used

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  • Flame-retardant HIPS material and preparation method thereof
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  • Flame-retardant HIPS material and preparation method thereof

Examples

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Embodiment 1-6 and comparative example 1-3

[0041] Examples 1-6 and Comparative Examples 1-3: Preparation of Flame Retardant HIPS Materials

[0042] a. Fully mix the raw materials of each component in a high-speed mixer for 3-6 minutes to obtain a mixture;

[0043] b. The above-mentioned mixture is conveyed to the twin-screw extruder through a precisely metered feeding device. The temperature of each section of the extruder screw is controlled between 170 and 220 °C, and the aspect ratio of the twin-screw extruder is 30 to 35. The screw speed is 300-800 rpm. Under the shearing, mixing and conveying of the screw, the material can be fully melted, mixed, then extruded, granulated and dried to obtain flame-retardant HIPS particles;

[0044] c. Add flame-retardant HIPS particles to the injection molding machine to form the required test sample. The injection molding conditions are barrel temperature 185-220°C, injection pressure 40-60MPa, and flow rate 40-70cm 3 / s.

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Abstract

The invention discloses a flame-retardant HIPS material and a preparation method thereof. The flame-retardant HIPS material comprises the following components: 79-91 parts of HIPS resin, 2-8 parts ofa brominated flame retardant, and 3-7 parts of an auxiliary flame retardant, wherein the auxiliary flame retardant is a 1,3,5-triazine compound. According to the flame-retardant HIPS material and preparation method provided by the invention, the bromine-based flame retardant and the auxiliary flame retardant are synergistically compounded, so that the use amount of the brominated flame retardant is effectively reduced, and the flame-retardant HIPS material can achieve a stable UL 94 (1.5 mm) V-2 flame retardant grade; and compared with current brominated flame retardant HIPS, the flame-retardant HIPS material provided by the invention has the advantages of a low halogen content, a low gas content, high cost performance, better thermal stability, and less corrosiveness to molds, and can bewidely used in the fields of thin-walled parts, such as office equipment, film and television multimedia and household appliances.

Description

technical field [0001] The invention relates to the field of flame-retardant polymer materials, in particular to a flame-retardant HIPS material and a preparation method thereof. Background technique [0002] Flame-retardant HIPS resin is widely used in audio-visual equipment casings, office equipment casings, household appliances, power conversion devices and other fields due to its good mechanical properties, processing properties and post-processing properties, good dimensional stability and low molding shrinkage. [0003] There are two types of flame-retardant HIPS technology at present, one is a halogen-free flame-retardant system, and the other is a halogen-free flame-retardant system. The halogen-free flame-retardant system is more environmentally friendly, less corrosive to molds, and has less gas. However, it has high material cost and processing energy consumption, which limits the wide use and promotion in the market; the usual halogenated flame retardant HIPS mat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L51/04C08K13/02C08K5/3492C08K5/03C08K3/22C08K5/50C08K5/5393C08K5/544
CPCC08K5/03C08K5/3492C08K3/2279C08L51/04C08L25/10C08K5/0066C08K5/50C08K5/5393B29C45/48C08K5/5477C08F253/00C08J3/12C08J3/203C08K13/02C09K21/02C09K21/08C09K21/10C09K21/12B29B9/06B29C45/0001B29K2025/06B29K2105/0026C08K2201/014
Inventor 秦旺平付锦锋肖鹏叶南飚黄险波
Owner KINGFA SCI & TECH CO LTD