Low fused ring content coal-based anthracene oil and low-temperature coal-based fuel oil containing low fused ring content coal-based anthracene oil

A technology for coal-based anthracene and fuel oil, which is applied in the fields of coal chemical industry and fuel science, can solve the problems of difficulty in transportation, loss of aromatic conjugated structure, loss of low-temperature crystallization properties, etc., and achieves the effect of low cost and easy implementation.

Inactive Publication Date: 2019-05-17
上海众炅新能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The common feature of these methods is to adopt the chemical reaction of hydrogenation, so that the condensed ring molecules in the anthracene oil lose the aromatic conjugated structure, thereby losing the low-temperature crystallization performance and being suitable for the use of fuel oil; but a large amount of hydrogen itself requires a specific Industrial sources, are flammable and explosive products and difficult to transport, in addition, hydrogenation catalysts are generally precious metals

Method used

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  • Low fused ring content coal-based anthracene oil and low-temperature coal-based fuel oil containing low fused ring content coal-based anthracene oil
  • Low fused ring content coal-based anthracene oil and low-temperature coal-based fuel oil containing low fused ring content coal-based anthracene oil

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Experimental program
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Effect test

Embodiment 1

[0027] Coal-based anthracene oil, a fractionation component derived from coal tar, is added with graphene with a mass fraction of 0.02, cooled to 5°C for crystallization, and centrifuged to remove high-fused ring number components (ie, crystallized parts) to obtain low-fused ring number Anthracene oil, after analysis, the average number of fused rings in its aromatic conjugated structure is 1.8, and the yield is 85%. The anthracene oil with low fused ring number is used as fuel oil, which can withstand low temperature down to 3℃.

Embodiment 2

[0029] Coal-based anthracene oil, a fractionation component derived from coal tar, was added with graphene with a mass fraction of 0.5%, cooled to 15°C for crystallization, and centrifuged to remove high-condensed ring number components (ie, crystallized parts) to obtain low-fused rings The number of anthracene oil is analyzed, and the average number of fused rings in its aromatic conjugated structure is 1.2, and the yield is 88%. The anthracene oil with low fused ring number is used as fuel oil, which can withstand low temperature down to 4℃.

Embodiment 3

[0031] Coal-based anthracene oil, a fractionation component derived from coal tar, was added with graphene with a mass fraction of 1%, cooled to 40°C for crystallization, and centrifuged to remove the high-condensed ring number component (ie, the crystalline part) to obtain a low-fused ring The number of anthracene oil is analyzed, and the average number of fused rings in its aromatic conjugated structure is 1.7, and the yield is 95%. The anthracene oil with low fused ring number is used as fuel oil, which can withstand low temperature down to 9℃.

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Abstract

The invention relates to low fused ring content coal-based anthracene oil and low-temperature coal-based fuel oil containing the low fused ring content coal-based anthracene oil. The fused ring content in a fragrant conjugated structure in the coal-based anthracene oil is not greater than 2. A preparation method comprises the following steps that graphene with the mass fraction of 0.01-1% is addedinto the coal-based anthracene oil obtained by fractionation of coal tar, and high fused ring content component with fractional crystallization after cooling is the low fused ring content coal-basedanthracene oil. The low fused ring content coal-based anthracene oil is made into the fuel oil which has very good low temperature resistance, and no solid is precipitated under -20-10 DEG C. According to the low fused ring content coal-based anthracene oil and the low-temperature coal-based fuel oil containing the low fused ring content coal-based anthracene oil, a simple and safe physical methodis adopted, the cost is low, and easy implementation is achieved.

Description

technical field [0001] The invention belongs to the field of coal chemical industry and fuel science, and in particular relates to a coal-based anthracene oil with low fused ring number and a low-temperature-resistant coal-based fuel oil containing it. Background technique [0002] The production of liquid fuels using coal as raw material can be roughly divided into three categories: one is to produce fuel oil with coal as raw material, including direct liquefaction of coal to oil and indirect liquefaction to oil; the other is to produce liquid alternative fuels with coal as raw material , the main forms at this stage are coal methanol and dimethyl ether; the third is the various fractions of coal tar by-products in the steel coke industry (such as pitch, anthracene oil, wash oil and phenol oil, etc.). [0003] Due to the low price, the research on the fuel sourced from coal tar has begun to be paid attention to by energy and power workers. The coal tar pitch is emulsified ...

Claims

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Application Information

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IPC IPC(8): C10G53/02C10G29/02C10L1/04C10L1/02
Inventor 孟庆华贾金平陈登勋李康雄
Owner 上海众炅新能源科技有限公司
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