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A high-efficiency water purifier

A purifying agent and water body technology, applied in the field of water body purification, can solve the problems of no site on the surface, no suspension, single adsorption, etc., and achieve the effects of high stability and timeliness, large bacterial flora advantages, and high purification efficiency.

Active Publication Date: 2021-07-20
浙江友创环境技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, in the cell immobilization technology, the embedding method is to disperse the cells into the porous carrier, or use the polymer to embed the cells inside when the gel is formed, so as to achieve the purpose of fixing the cells, which is currently the most widely used. However, when using the biological metabolic function of sulfur-oxidizing bacteria to treat sulfur-containing wastewater, the metabolic activities of functional microorganisms in the reactor are often inhibited due to the high concentration of sulfide in the influent, resulting in the need for a long time for functional microorganisms. Long adaptation period, and because the adhesion of sulfur oxidizing bacteria is not strong, it is easy to lose with the effluent, so it is not easy to maintain a high concentration of sulfur oxidizing bacteria in the reactor
[0004] Such as CN103951052 A Beijing University of Technology discloses the preparation and application of a polyurethane carrier-based sulfur-oxidizing bacteria immobilized bioactive filler, blocky polyurethane foam is solidified by extruding and absorbing the embedding fluid to absorb and solidify the embedding fluid loaded with sulfur-oxidizing bacteria However, the polyurethane material has the following problems: (1) The density is single, and there are only two states of floating and sinking. In the dynamic system of water body changes, it cannot be effectively used for a long time. Suspended in water; (2) Polyurethane has no sites on the surface and is not suitable for establishing sites, so it is not suitable for selective adsorption of sulfur oxidizing bacteria; (3) Polyurethane has a single pore size and only has irregular macropores , although the large pores are good for adsorption, the specific surface area is extremely small, the fixation effect is poor, and the stability is somewhat improved; (3) Polyurethane, as an organic high polymer, will cause serious pollution. A cube with a length of 3‐5mm, a cuboid with a length, width and height of 3‐5mm, a cylinder with a diameter of 3‐5mm and a height of 3‐5mm, etc., are similar to the carrier of particles. After purifying large areas of water such as lakes and oceans, There are huge problems in recycling, which can easily cause pollution
However, the polyurethane material has the following problems: (1) the carrier is complex, and it is difficult to mix evenly, which makes it impossible to achieve homogeneous mixing, resulting in poor stability of the adsorption effect of the entire adsorbent; (2) no effective adsorption vacancies, only relying on the Sequential macroporous adsorption of bacteria, single adsorption

Method used

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  • A high-efficiency water purifier

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Experimental program
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Effect test

Embodiment 1

[0037] A macroporous mesoporous silica carrier is prepared by a template method, and the carrier has a pore structure interconnected with each other.

[0038] Reduction-sulfurization of the carrier: place the carrier in a corundum cup in a vacuum tube furnace, evacuate it with argon, and then switch the gas path to 3vol.H 2 / Ar mixture, warm up to 570 o C, the time is 1.3h, naturally cool down to 250 o After C, after argon is evacuated, CS is introduced 2 gas to 13 o C / min increased to 700 o C, keep the temperature for 1.5h, cool down to room temperature naturally, form sulfur-oxygen bonds on the surface of the silica carrier, and serve as the adsorption sites for the culture medium sulfur bacteria.

[0039] The sulfur oxidizing bacteria culture medium includes KH 2 P0 4 , NaHP0 4 , MgSO 4 , KCl, and deionized water, and Cu 2+ , Zn 2+ , Ca 2+ , Fe 3+ ,Mn 2+ Trace elements, autoclaved at 121 °C for 20 min, inoculated with sulfur-oxidizing bacteria under sterile con...

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Abstract

The invention provides a high-efficiency water body purifying agent, which includes a carrier and sulfur-oxidizing bacteria carried in the pores of the carrier. The carrier has an interconnected and penetrating macropore structure, and connected pore windows of 1-10 μm are attached to the pore wall. The wall is composed of mesoporous structure. The shrinking water purifier has a large load of bacteria, a high survival rate, a large bacterial flora advantage, high purification efficiency, and high stability and timeliness.

Description

technical field [0001] The invention belongs to the field of water body purification, and in particular relates to a sulfur-oxidizing bacteria bioactive purifying agent based on a macroporous mesoporous silica carrier, a preparation method thereof, and an application thereof. Background technique [0002] Studies have shown that in today's aquaculture process, due to the low bait utilization rate, excessive discharge of residual bait, and excessive discharge of farmed animal feces, eutrophication of water bodies, C, N, and P enrichment pollution of sediments and sediment oxidation are caused. The reduction potential is lowered. Increased eutrophication of water bodies will lead to excessive ammonia nitrogen and nitrite, which will have a toxic effect on aquatic animals. The discharge of a large amount of aquaculture wastewater has caused a huge impact on the surrounding environment. The water environment has deteriorated, red tides have occurred frequently, and ecological b...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F3/34C02F103/20
Inventor 白洋洋
Owner 浙江友创环境技术有限公司
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