Moisture-proof, non-marking and movable high-strength viscose glue and preparation method thereof
A high-strength, adhesive technology, applied in the direction of non-polymer adhesive additives, adhesives, adhesive types, etc., can solve the problem of poor oil and moisture resistance, short stickiness maintenance time, poor load-bearing adhesion, etc. No problem, to achieve the effect of sticking and removing without leaving traces, good ductility and elasticity, simple and easy to stick and remove
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Embodiment 1
[0055] 1. Accurately weigh 29 parts of cyanate ester resin, 11 parts of butyl rubber, and 10 parts of chlorinated butyl rubber, and fully mix them in a rubber mixer at 50-70°C for 2-3 hours to form component A.
[0056] 2. Accurately weigh 3 parts of diphenylmethane diisocyanate and 2 parts of toluene diisocyanate, add them into the reactor equipped with a water separator, then add 7 parts of trimethylolpropane, stir for 1 to 2 hours, and form Component B.
[0057] 3. Add component A, component B, 10 parts of 2-dimethylol butyric acid and 2 parts of 1,2-propanediol in sequence, adjust the temperature of the reaction system to 60-80 ° C, and pass in dry nitrogen, Slowly add 8 parts of dodecanedioic acid and 6 parts of sebacic acid, stir evenly, and drop in 1 part of aminotriethanol. Keep the temperature constant at 65-70°C, and react for 3-4 hours.
[0058] 4. Lower the temperature of the reaction system to 30-40°C, add 9 parts of nano-calcium carbonate, and react for 0.5 hou...
Embodiment 2
[0061] 1. Accurately weigh 27 parts of cyanate ester resin, 15 parts of butyl rubber, and 12 parts of chlorinated butyl rubber, and fully mix them in a rubber mixer at 50-70°C for 2-3 hours to form component A.
[0062] 2. Accurately weigh 3 parts of diphenylmethane diisocyanate and 1 part of toluene diisocyanate, add them into the reactor equipped with a water separator, then add 8 parts of trimethylolpropane, stir for 1 to 2 hours, and form Component B.
[0063] 3. Add component A, component B, 8 parts of 2-dimethylolbutyric acid and 2 parts of 1,2-propanediol in sequence, adjust the temperature of the reaction system to 60-80°C, and pass in dry nitrogen, Slowly add 7 parts of dodecanedioic acid and 6 parts of sebacic acid, stir evenly, and drop in 2 parts of aminotriethanol. Keep the temperature constant at 65-70°C, and react for 3-4 hours.
[0064] 4. Lower the temperature of the reaction system to 30-40°C, add 8 parts of nano-calcium carbonate, and react for 0.5 hours. ...
Embodiment 3
[0067] 1. Accurately weigh 26 parts of cyanate ester resin, 15 parts of butyl rubber, and 11 parts of chlorinated butyl rubber, and fully mix them in a rubber mixer at 50-70°C for 2-3 hours to form component A.
[0068] 2. Accurately weigh 2 parts of diphenylmethane diisocyanate and 1 part of toluene diisocyanate, add them into the reactor equipped with a water separator, then add 9 parts of trimethylolpropane, stir for 1 to 2 hours, and form Component B.
[0069] 3. Add component A, component B, 8 parts of 2-dimethylol butyric acid, and 3 parts of 1,2-propanediol in sequence, adjust the temperature of the reaction system to 60-80 ° C, and pass in dry nitrogen, Slowly add 6 parts of dodecanedioic acid and 8 parts of sebacic acid, stir evenly, and drop in 1 part of aminotriethanol. Keep the temperature constant at 65-70°C, and react for 3-4 hours.
[0070] 4. Lower the temperature of the reaction system to 30-40°C, add 7 parts of nano-calcium carbonate, and react for 0.5 hour...
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