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A kind of mixing and slurrying method of positive electrode material

A positive electrode material and pulping technology, which is applied in the field of positive electrode material mixing and pulping, can solve the problems of poor slurry coating performance, poor slurry stability, and influence on coating, and achieve simple mixing process and improved stability , increase the effect of stability

Active Publication Date: 2020-12-11
泰州纳新新能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Existing electric vehicle batteries generally use a positive electrode blended with lithium cobaltate and ternary materials, but due to the different particle sizes of lithium cobaltate and ternary materials, the coating performance of the slurry is poor, and it is easy to occur during the drying process. Cracking, the inventor found that the reason for the above defects is mainly due to the poor stability of the slurry of the mixed positive electrode, which leads to a more serious chromatography phenomenon, which affects the coating and drying effect, and then affects the electrochemical performance of the battery. performance

Method used

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  • A kind of mixing and slurrying method of positive electrode material
  • A kind of mixing and slurrying method of positive electrode material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] 1) Add PVDF to NMP, stir for 2 hours, then add conductive carbon black, stir for 4 hours, add lithium cobaltate A with an average particle size of 80nm, stir for 8 hours, and obtain the first slurry, in which lithium cobaltate, PVDF and conductive The ratio of carbon black is 100:6:4, and the solid content is 62%;

[0029] 2) Add PVDF to NMP, stir for 2 hours, then add conductive carbon black, stir for 4 hours, add lithium cobaltate B with an average particle size of 1.2 μm, stir for 6 hours, and obtain the second slurry, in which lithium cobaltate, PVDF and The ratio of conductive carbon black is 100:6:4, and the solid content is 60%;

[0030] 3) Add PVDF to NMP, stir for 2 hours, then add conductive carbon black, stir for 4 hours, add lithium nickel manganese cobaltate with an average particle size of 2 μm, stir for 4 hours to obtain the third slurry, in which lithium nickel manganese cobaltate, The ratio of PVDF and conductive carbon black is 100:6:4, and the solid ...

Embodiment 2

[0033] 1) Add PVDF to NMP, stir for 2 hours, then add conductive carbon black, stir for 4 hours, add lithium cobaltate A with an average particle size of 200nm, stir for 8 hours, and obtain the first slurry, in which lithium cobaltate, PVDF and conductive The ratio of carbon black is 100:7:5, and the solid content is 65%;

[0034] 2) Add PVDF to NMP, stir for 2 hours, then add conductive carbon black, stir for 4 hours, add lithium cobaltate B with an average particle size of 1.5 μm, stir for 6 hours, and obtain the second slurry, in which lithium cobaltate, PVDF and The ratio of conductive carbon black is 100:7:5, and the solid content is 62%;

[0035] 3) Add PVDF to NMP, stir for 2 hours, then add conductive carbon black, stir for 4 hours, add lithium nickel manganese cobaltate with an average particle size of 2.5 μm, stir for 4 hours to obtain the third slurry, in which lithium nickel manganese cobaltate , the ratio of PVDF and conductive carbon black is 100:7:5, and the so...

Embodiment 3

[0038] 1) Add PVDF to NMP, stir for 2 hours, then add conductive carbon black, stir for 4 hours, add lithium cobaltate A with an average particle size of 80nm, stir for 8 hours, and obtain the first slurry, in which lithium cobaltate, PVDF and conductive The ratio of carbon black is 100:6:5, and the solid content is 63%;

[0039] 2) Add PVDF to NMP, stir for 2 hours, then add conductive carbon black, stir for 4 hours, add lithium cobaltate B with an average particle size of 1.4 μm, stir for 6 hours, and obtain the second slurry, in which lithium cobaltate, PVDF and The ratio of conductive carbon black is 100:6:5, and the solid content is 61%;

[0040] 3) Add PVDF to NMP, stir for 2 hours, then add conductive carbon black, stir for 4 hours, add lithium nickel manganese cobaltate with an average particle size of 2.2 μm, stir for 4 hours to obtain the third slurry, in which lithium nickel manganese cobaltate , the ratio of PVDF and conductive carbon black is 100:6:5, and the sol...

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Abstract

The invention provides a method for mixing and slurrying positive electrode materials. The positive electrode material includes a first active material and a second active material, and the first active material is selected from lithium cobaltate or modified lithium cobaltate; the second active material It is selected from lithium nickel manganese cobaltate or modified lithium nickel manganese cobaltate. The first active material includes first particles with an average particle diameter of 80-200nm and second particles with an average particle diameter of 1.2-1.5 μm; the average particle diameter of the second active material is 2-2.5 μm; wherein according to The total mass of the first particle, the second particle and the second active material is 100% of the reference value, the first particle accounts for 8-12%, the second particle accounts for 20-25%, and the second active material accounts for 65-70% ; In the present invention, the first particle, the second particle and the second active material are respectively made into slurry, and then mixed in batches, so that the obtained slurry has high stability and good coating performance.

Description

technical field [0001] The invention relates to the technical field of lithium ion battery production, in particular to a method for mixing and making slurry of positive electrode materials. Background technique [0002] Power batteries have the advantages of high energy density, high power, and environmental protection, and are often used in the field of electric vehicles. Existing electric vehicle batteries generally use a positive electrode blended with lithium cobaltate and ternary materials, but due to the different particle sizes of lithium cobaltate and ternary materials, the coating performance of the slurry is poor, and it is easy to occur during the drying process. Cracking, the inventor found that the cause of the above defects is mainly due to the poor stability of the slurry of the mixed positive electrode, which leads to a more serious chromatography phenomenon, which affects the coating and drying effect, and then affects the electrochemical performance of the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/131H01M4/36H01M4/505H01M4/525H01M4/62H01M10/0525B01F3/12
CPCH01M4/525H01M4/505H01M4/364H01M4/625H01M10/0525H01M4/131H01M2004/028B01F23/511Y02E60/10
Inventor 袁永华
Owner 泰州纳新新能源科技有限公司