Core-shell microneedle devices and uses thereof
A technology of microneedle and microneedle patch, which is applied in the direction of microneedle, needle, and other medical devices, and can solve long-term biocompatibility concerns and other issues
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example 1
[0207] Example 1: Core-shell microneedle gels for autoregulated insulin delivery.
[0208] result
[0209] TSPBA was synthesized by the quaternization of N1,N1,N3,N3-tetramethylpropane-1,3-diamine with excess 4-(bromomethyl)phenylboronic acid (Scheme 1). The quaternary ammonium groups on TSPBA greatly improved its water solubility (approximately 100 mg / mL), which facilitated the gel formation of PVA aqueous solution in the absence of organic solvents. in 10mM H 2 o 2 When oxidized in the presence, 70% of TSPBA liberated p-quinone methide (p-hydroxymethylenephenol) and converted to tertiary amine within 2 hours, as shown by H1-NMR analysis results (Fig. 7). [18] in DMSO and 10mM NaHCO 3 Insulin-NBC was prepared in the presence of a slight excess of NBC in a mixed solvent consisting of an aqueous solution. [19] Purified the product using preparative high-performance liquid chromatography (HPLC), [13] and used MALDI-TOF mass spectrometry to confirm that the product was a con...
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