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Multi-scale layered flame-retardant material and preparation method thereof

A flame retardant material, multi-scale technology, applied in the direction of coating, can solve the problems of damage to the mechanical properties of the matrix, reduce the flame retardant effect, and high production costs, and achieve the goal of overcoming poor compatibility, improving flame retardant properties, and low production costs. Effect

Active Publication Date: 2019-11-08
XIHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the methods of coating and sheet lamination are relatively easy to realize the distribution of the flame retardant on the surface of the substrate, which can achieve a better flame retardant effect in theory, but the way of coating and sheet lamination makes the relative relationship between the substrate and the flame retardant The compatibility is very poor, which will lead to a decrease in the flame retardant effect; while the traditional melt blending makes the flame retardant well dispersed in the matrix, and the compatibility between the flame retardant and the matrix is ​​better, but due to the uniformity of the flame retardant Dispersion leads to the same flame retardant performance inside and outside the matrix. To achieve a better flame retardant effect, a higher amount of flame retardant needs to be added, which will also lead to the destruction of the mechanical properties of the matrix and high production costs.

Method used

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  • Multi-scale layered flame-retardant material and preparation method thereof
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  • Multi-scale layered flame-retardant material and preparation method thereof

Examples

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preparation example Construction

[0026] The invention provides a method for preparing a multi-scale layered flame retardant material, comprising the following steps: S1, preparing a layered flame retardant: ultrasonically dispersing a certain amount of graphene oxide in a solvent, and then adding graphene oxide dissolved thereto Add a certain amount of intumescent flame retardant to the solvent, continue ultrasonic dispersion, finally add water absorbent, stir and react to obtain a layered flame retardant; S2, prepare a multi-scale layered flame retardant material: the layer prepared in step S1 The multi-scale layered flame retardant material is prepared by mixing the shape flame retardant, a certain amount of intumescent flame retardant and a certain amount of polymer matrix in the injection molding machine under the specified injection molding process. The present invention utilizes the sheet structure of graphene oxide to disperse IFR between the sheets of graphene oxide with a certain concentration gradien...

Embodiment 1

[0037] This embodiment provides a method for preparing a multi-scale layered flame retardant material, which includes the following steps:

[0038] S1, preparation of layered flame retardant: Weigh 0.6g of graphene oxide and dissolve it in 0.3L of DMF solution, and disperse it ultrasonically for 30min at a temperature of 40°C; then add 1.156gIFR to the solution containing graphene oxide, and then ultrasonically Disperse for 30 minutes, and the ultrasonic temperature is still 40°C; after the mixing is completed, add 4.464g of DCC and react for 20 hours under magnetic stirrer stirring, then centrifuge, dry and grind to obtain a powdery layered flame retardant;

[0039] S2, preparation of multi-scale layered flame retardant materials: dry the polymer matrix and IFR in an electric constant temperature blast drying oven for 8h to 12h before weighing; then weigh 800g of polymer matrix and 200g of IFR and mix well in the bag , and add 3g of antioxidant, a little liquid paraffin and a...

Embodiment 2-5

[0046] The difference between the preparation method of Examples 2-5 and the preparation method of Example 1 is that the injection molding time of the injection molding process is different, and the injection molding times of Examples 2-5 are 3S, 5S, 10S, and 15S respectively.

[0047] Embodiments 2-5 also provide a multi-scale layered flame-retardant material, which is prepared by the preparation methods of Embodiments 2-5.

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Abstract

The invention provides a preparation method of a multi-scale layered flame-retardant material. The preparation method comprises the following steps that S1, the layered flame retardant is prepared, specifically, a certain amount of graphene oxide is dispersed in a solvent, then a certain amount of intumescent flame retardant is added into the solvent dissolved with graphene oxide, dispersing continues carrying out, finally a water absorbent is added, and the layered flame retardant is obtained after stirring and reacting; and S2, the multi-scale layered flame-retardant material is prepared, specifically, a certain amount of the layered flame retardant prepared in the step 1, a certain amount of intumescent flame retardant and a certain amount of polymer matrix are mixed, and the multi-scale layered flame-retardant material is prepared in an injection molding machine under a specified injection molding process. The invention further provides the multi-scale layered flame-retardant material prepared by the preparation method of the multi-scale layered flame-retardant material. The flame-retardant material prepared by the preparation method has the advantages of being good in flame-retardant effect, good in mechanical property, low in production cost, environmentally friendly, safe and the like.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to a multi-scale layered flame-retardant material and a preparation method thereof. Background technique [0002] Polymer materials have the advantages of light weight, high strength, good stability, good electrical insulation performance, and aging resistance. They are widely used in industries such as automobiles, electronic appliances, mechanical equipment, and construction. It is necessary to improve the flame retardancy of polymer materials. [0003] The traditional flame retardant modification of polymer materials is to add flame retardants to polymer materials. Among them, halogen-based flame retardants have high flame-retardant efficiency, but they will produce toxic substances during combustion, which is harmful to the environment; non-halogen-based flame retardants, such as intumescent flame retardants (IFR), graphene, etc., have Low smoke, low toxi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B29C45/00B29C45/76B29C45/78B29C45/77B29B9/06
CPCB29C45/00B29C45/76B29C45/78B29C45/77B29B9/06B29C2945/76498B29C2945/76561B29C2945/76531
Inventor 李正秋陈宝书赵天宝李见斌廖力冉隆昌吴婷
Owner XIHUA UNIV
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