Preparation method of proton exchange film fuel cell film electrode

A proton exchange membrane, fuel cell membrane technology, applied in fuel cells, battery electrodes, circuits, etc., can solve the problems of affecting the stability and life of fuel cells, increasing the difficulty of catalyst preparation, and prone to reverse polarity phenomenon, etc. Electrode and perforation phenomenon, good catalytic activity and corrosion resistance, the effect of reducing the occurrence of perforation phenomenon

Active Publication Date: 2019-12-03
先进储能材料国家工程研究中心有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] During the actual operation of the fuel cell, various operating conditions will inevitably occur. During the start-up and shutdown of the battery, especially in the state of high-current instantaneous loading, the membrane electrodes will be damaged due to reasons such as unreasonable gas distribution and gas supply lag. There are short-term abnormal working conditions in the area, and the local and surface of the catalyst are prone to voltage dips and even reverse polarity, especially at the edge of the membrane electrode, which is a multi-interface contact point, and insufficient gas supply is more likely to occur, and reverse polarity is very prone to occur. Affect the

Method used

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Examples

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Comparison scheme
Effect test

Embodiment 1

[0012] A preparation method of a membrane electrode of a proton exchange membrane fuel cell is carried out according to the following steps:

[0013] (a) Preparation of CCM membrane semi-finished products: Prepare Pt / C catalyst slurry according to the existing process, and spray the Pt / C catalyst slurry on both sides of the proton exchange membrane according to the existing process to form Pt / C cathode and anode catalyst layers respectively, A semi-finished CCM membrane of 5cm×5cm was prepared, and the Pt loading on the cathode side of the semi-finished CCM membrane was controlled to 0.35mg / cm 2 , the Pt load on the anode side of the CCM film semi-finished product is controlled to 0.1mg / cm 2 ;

[0014] (b) Preparation of anti-reverse electrode slurry: rubidium dioxide RnO 2 Add to deionized water and magnetically stir for 0.5h to form a mixed solution, isopropanol and a proton exchange membrane resin solution with a mass content of 10% are magnetically stirred for 0.5h to fo...

Embodiment 2

[0017] A method for preparing a proton exchange membrane fuel cell membrane electrode, the steps of which are basically the same as those of the method for preparing a proton exchange membrane fuel cell membrane electrode in Example 1, except that:

[0018] 1. In step (a), the size of the semi-finished CCM membrane is 8cm×8cm, and the Pt load on the cathode side of the semi-finished CCM membrane is controlled to 0.4mg / cm 2 , the Pt load on the anode side of the CCM film semi-finished product is controlled to 0.15mg / cm 2 ;

[0019] 2. In step (b), the anti-reverse substance is cobalt trioxide Co 2 o 3 , the organic solvent is ethanol, the mass concentration of the proton exchange membrane resin solution is 20%, dicobalt trioxide Co 2 o 3 The mass ratio to the proton exchange membrane resin is 5:1, the mass ratio of ethanol to deionized water is 5:1, and the solid content of the anti-reverse electrode slurry is controlled to 4%;

[0020] 3. In step (c), 10mm is left around ...

Embodiment 3

[0022] A method for preparing a proton exchange membrane fuel cell membrane electrode, the steps of which are basically the same as those of the method for preparing a proton exchange membrane fuel cell membrane electrode in Example 1, except that:

[0023] 1. In step (a), the size of the semi-finished CCM membrane is 10cm×10cm, and the Pt loading on the cathode side of the semi-finished CCM membrane is controlled to be 0.2mg / cm 2 , the Pt loading on the anode side of the CCM film semi-finished product is controlled to 0.05mg / cm 2 ;

[0024] 2. In step (b), the anti-reverse material is iridium dioxide IrO 2 , the organic solvent is n-propanol, the mass concentration of the proton exchange membrane resin solution is 25%, iridium dioxide IrO 2 The mass ratio to the proton exchange membrane resin is 4:1, the mass ratio of n-propanol to deionized water is 1:1, and the solid content of the anti-reverse electrode slurry is controlled to 2%;

[0025] 3. In step (c), 10mm is left a...

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Abstract

The invention provides a preparation method of a proton exchange film fuel cell film electrode. Pt/C catalyst layers are coated on two sides of a proton exchange film respectively to obtain a CCM filmsemi-finished product, and anti-reverse pole slurry layers are coated on peripheral edges of anode surfaces of the CCM film semi-finished product; the preparation process of the anti-reverse pole slurry specifically comprises steps of adding an antipole substance into deionized water, uniformly mixing the mixture to form mixed solution, adding mixed solution of organic solvent and proton exchangefilm resin solution into the mixed solution, and uniformly mixing the mixture to obtain anti-reverse pole slurry; the solid content of the anti-reverse pole slurry is controlled to be 1-4%, the anti-reverse pole substance is one or more of iridium, rubidium, tin, cobalt metal and metal oxide thereof, and the organic solvent is one or more of ethanol, isopropanol, tert-butyl alcohol and n-propyl alcohol. The method is simple in process, can reduce the probability of occurrence of a reverse pole phenomenon of a fuel cell in the operation process, and reduces a perforation phenomenon.

Description

technical field [0001] The invention relates to the field of fuel cells, in particular to a method for preparing membrane electrodes of proton exchange membrane fuel cells. Background technique [0002] During the actual operation of the fuel cell, various operating conditions will inevitably occur. During the start-up and shutdown of the battery, especially in the state of high-current instantaneous loading, the membrane electrodes will be damaged due to reasons such as unreasonable gas distribution and gas supply lag. There are short-term abnormal working conditions in the area, and the local and surface of the catalyst are prone to voltage dips and even reverse polarity, especially at the edge of the membrane electrode, which is a multi-interface contact point, and insufficient gas supply is more likely to occur, and reverse polarity is very prone to occur. It will affect the stability and life of the fuel cell. In severe cases, the membrane electrode will be perforated a...

Claims

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Application Information

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IPC IPC(8): H01M8/1004H01M4/88H01M4/92
CPCH01M8/1004H01M4/8828H01M4/921H01M4/926H01M2008/1095Y02E60/50
Inventor 钟发平贺凤倪江鹏杨涵邓宇飞尹涛
Owner 先进储能材料国家工程研究中心有限责任公司
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