Low-sintering-temperature and low-dielectric-constant microwave dielectric ceramic and preparation method thereof
A technology of microwave dielectric ceramics and low sintering temperature, which is applied in the field of electronic ceramics and its preparation, can solve the problems of high sintering temperature and difficulty in sintering into porcelain, and achieve the effects of reducing sintering temperature, improving sinterability and low loss
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[0025] The present invention also provides a method for preparing low-sintering temperature and low-medium microwave dielectric ceramics, comprising the following steps:
[0026] Step 1, prepare the main material of this microwave dielectric ceramic: first MgO, SiO 2 、TiO 2 , SrCO 3 According to the composition expression (1-x-y)MgSiO 3 -xMg 2 TiO 4 -ySrSiTiO 5 The molar ratio of the corresponding elements in the ingredients, the MgO, SiO 2 、TiO 2 , SrCO 3 Fully ball mill after mixing, dry and sieve after ball milling, and then put into a corundum crucible for roasting to obtain the main material, the composition expression (1-x-y)MgSiO 3 -xMg 2 TiO 4 -ySrSiTiO 5 Among them, x, y, (1-x-y) all represent the molar ratio, x=0.3, 0<y≤0.035;
[0027] Step 2, preparing auxiliary materials for the microwave dielectric ceramic: mixing ZnO and CuO fully, then ball milling, drying, sieving after ball milling, and then putting them into a corundum crucible for roasting to obt...
Embodiment 1
[0036] The preparation method of the low sintering temperature and low dielectric microwave dielectric ceramic of the present embodiment 1 comprises the following steps:
[0037] (1) prepare the main material of this microwave dielectric ceramic: first MgO, SiO 2 、TiO 2 , SrCO 3 According to the composition expression 0.695MgSiO 3 -0.3Mg 2 TiO 4 -0.005SrSiTiO 5 The molar ratio of the corresponding elements in the ingredients, the MgO, SiO 2 、TiO 2 , SrCO 3 After mixing, fully ball mill, dry and sieve after ball milling, then put into a corundum crucible, and roast at 1000°C for 4 hours to obtain the main material;
[0038] (2) Preparation of low sintering temperature and low-medium microwave dielectric ceramics: Weigh the main material without adding auxiliary materials, mix the main materials and fully ball mill, then dry, granulate and sieve, and press the sieved mixed powder Form a cylinder with a diameter of 10 mm and a height of 6 mm, and sinter at 1250° C. for 4 h...
Embodiment 2
[0041] The preparation method of the low sintering temperature and low dielectric microwave dielectric ceramic of the present embodiment 2 comprises the following steps:
[0042] (1) prepare the main material of this microwave dielectric ceramic: first MgO, SiO 2 、TiO 2 , SrCO 3 According to the composition expression 0.69MgSiO 3 -0.3Mg 2 TiO 4 -0.01SrSiTiO 5 The molar ratio of the corresponding elements in the ingredients, the MgO, SiO 2 、TiO 2 , SrCO 3 After mixing, fully ball mill, dry and sieve after ball milling, then put into a corundum crucible, and roast at 1000°C for 4 hours to obtain the main material;
[0043] (2) Preparation of low sintering temperature and low-medium microwave dielectric ceramics: Weigh the main material without adding auxiliary materials, mix the main materials and fully ball mill, then dry, granulate and sieve, and press the sieved mixed powder Form a cylinder with a diameter of 10 mm and a height of 6 mm, and sinter at 1250° C. for 4 h...
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