Numerical simulation method for electrodialysis mass transfer process
A mass transfer process and numerical simulation technology, applied in chemical process analysis/design, etc., can solve problems such as difficult monitoring, and achieve the effect of improving universality, high degree of agreement with reality, and directional optimization
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Embodiment 1
[0029] A numerical simulation method of an electrodialysis mass transfer process provided by an embodiment of the present invention specifically includes the following steps:
[0030] S1. Select the Nernst-Planck transfer equation It is used to describe the mass transfer flux in the electrodialysis process, and then related to the electric neutrality equation ∑z j c i = 0, Faraday's law Nernst-Einstein relation u i =D i / (RT) Simultaneously establish a mathematical model, where J i is the ion molar flux, D i is the diffusion coefficient, c i is the ion concentration, z i is the charge number, u i Is the ion migration number, Φ is the potential, the vector u is the fluid velocity, I is the current density, and F is the Faraday constant (96485C / mol).
[0031] S2. Select the secondary current distribution and tertiary current distribution physical fields in the electrochemical module in the Comsol software; specifically, define the model body, boundaries, fluid velocit...
Embodiment 2
[0037] The detailed description and concrete steps of Embodiment 2 of the present invention are as follows:
[0038] S1. Select the Nernst-Planck transfer equation It is used to describe the mass transfer flux in the electrodialysis process, and then related to the electric neutrality equation ∑z j ci = 0, Faraday's law Nernst-Einstein relation u i =D i / (KT) Simultaneously establish a mathematical model, where J i is the ion molar flux, D i is the diffusion coefficient, c i is the ion concentration, z i is the charge number, u i Is the ion migration number, Φ is the potential, the vector u is the fluid velocity, I is the current density, and F is the Faraday constant (96485C / mol).
[0039] S2. Select the secondary current distribution and tertiary current distribution physical fields in the electrochemical module in the Comsol software; specifically, define the model body, boundaries, fluid velocity variables in the compartment, and ion diffusion coefficients in the...
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