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Regeneration method of waste oil

A technology of waste grease and waste oil, which is applied in chemical instruments and methods, preparation of organic compounds, organic chemistry, etc., can solve problems such as food waste oil pollution, difficulty in sanitation work, and blockage of sewage pipe network, so as to achieve wide application and avoid Pollution problem, effect of reducing raw material cost

Inactive Publication Date: 2020-01-07
徐小四
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Catering waste oil produced by a large amount of edible oil consumption has always been a headache. Waste catering oil is seriously polluted, and oily wastewater often leads to blockage of sewage pipe networks, which brings difficulties to sanitation work. Environmental ecology is extremely unfavorable

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] A kind of regeneration method of waste oil of the present embodiment comprises the following steps:

[0017] Step 1 Pretreatment process of waste oil

[0018] After heating the swill oil to 60°C, filter it with a sand core to remove impurities such as soil, food residues, detergents, etc., then use vacuum distillation at 110°C to remove the water in the oil, and finally, add acid clay for Adsorption and decolorization can obtain the treated swill oil.

[0019] The second step is the synthesis process of waste oil-based polyol

[0020] Stir and mix the pretreated swill oil and 3-amino-1,2-propanediol, control the mass ratio of waste oil to amino alcohol to 1:0.5, heat and stir at 140°C for 3 h, and distill under reduced pressure to remove the by-products. The product water was cooled, and the insolubles were filtered out to obtain swill oil 3-amino-1,2-propanediol polyol with a hydroxyl value of 283 mgKOH / g.

[0021] This embodiment has the following characteristics: ...

Embodiment 2

[0023] A kind of regeneration method of waste oil of the present embodiment comprises the following steps:

[0024] Step 1 Pretreatment process of waste oil

[0025] After heating the waste frying oil to 60°C, filter it with a sand core to remove impurities such as soil, food residues, detergents, etc., and then use vacuum distillation at 110°C to remove the moisture in the oil, and finally, add acid The white clay is adsorbed and decolorized to obtain the treated waste oil for frying.

[0026] The second step is the synthesis process of waste oil-based polyol

[0027] Stir and mix the pretreated waste oil from frying with tris(hydroxymethyl)aminomethane, control the mass ratio of waste oil to amino alcohol to 1:0.4, heat and stir at 160°C for 12 h, then distill under reduced pressure The by-product is cooled in water, and the insoluble matter is filtered out to obtain the tris(hydroxymethyl)aminomethane polyol product of frying waste oil, with a hydroxyl value of 325 mgKOH / ...

Embodiment 3

[0030] A kind of regeneration method of waste oil of the present embodiment comprises the following steps:

[0031] Step 1 Pretreatment process of waste oil

[0032] After heating the waste oil to 60°C, filter it with a sand core to remove impurities such as soil, food residues, detergents, etc., and then use a vacuum distillation method at 110°C to remove the water in the oil, and finally, add acid white clay for cleaning. Adsorption decolorization, that is, the treated waste oil.

[0033] The second step is the synthesis process of waste oil-based polyol

[0034] Stir and mix the pretreated waste oil and 3,4-pyrrolidinediol, control the mass ratio of waste oil to amino alcohol to 1:0.7, heat and stir at 120°C for 15 hours, and distill off the by-product water under reduced pressure After cooling, the insolubles were filtered off to obtain the waste oil 3,4-pyrrolidinediol polyol product with a hydroxyl value of 343 mgKOH / g.

[0035] This embodiment has the following chara...

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Abstract

The invention relates to the technical field of organic synthesis, and discloses a regeneration method of waste oil, wherein the method comprises: carrying out simple pretreatment of filtration, dehydration and decolorization on waste oil, carrying out a heating stirring reaction on the pretreated waste oil and an amino alcohol compound, carrying out amidation on the free fatty acid in the waste oil under a heating condition based on the high reaction activity of amino, and carrying out a transesterification reaction with glyceride to form the corresponding bio-oil-based polyol.

Description

technical field [0001] The invention relates to the technical field of organic synthesis, in particular to a method for regenerating waste oil. Background technique [0002] Catering waste oil produced by a large amount of edible oil consumption has always been a headache. Waste catering oil is seriously polluted, and oily wastewater often leads to blockage of sewage pipe networks, which brings difficulties to sanitation work. Environmental ecology is extremely unfavorable. Therefore, it is particularly important to effectively utilize these waste oils. In order to solve the above problems, the present invention considers the use of waste oil raw materials, and after simple pretreatment, reacts with suitable amino alcohol compounds to synthesize bio-based polyols, avoiding the pollution of waste oil and reducing the cost of raw materials. Contents of the invention [0003] The object of the present invention is to provide an environment-friendly polyol, which realizes tu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C231/02C07C233/18C07C233/20C07D207/36
CPCC07C231/02C07D207/36C07C233/18C07C233/20
Inventor 徐小四
Owner 徐小四