Azeotrope or azeotropic composition, working medium for heat cycle, and heat cycle system
A technology of working medium and circulation system, applied in the direction of heat exchange materials, chemical instruments and methods, etc., can solve the problems of large temperature gradient, poor management of working medium, difficult recovery of working medium, etc., and achieve small composition change and good circulation performance Excellent, less environmental load effect
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[0175] Hereinafter, examples of the present invention will be described, but the present invention is not limited to these examples.
example 1~11
[0177] The azeotrope-like composition containing 1224yd(Z) and 1233zd(E) was prepared in the ratio shown in Table 4 as the working medium for thermal cycles in Examples 1-11. For the working medium for thermal cycle of each example, the cycle performance and temperature gradient were evaluated as follows.
[0178] (Evaluation of refrigeration cycle performance and temperature gradient)
[0179] exist figure 2 In the refrigerating cycle system 10, use the heat cycle working medium of each example respectively, to image 3 The thermal cycle shown, i.e. adiabatic compression using compressor 11 in process AB, isobaric cooling using condenser 12 in process BC, isenthalpic expansion using expansion valve 13 in process CD, and evaporation in process DA The refrigeration cycle performance (refrigeration capacity and efficiency coefficient) and the temperature gradient were evaluated as cycle performance (capacity and efficiency) when isobaric heating was performed by the container...
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