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A protective coating material resistant to high temperature silicide corrosion and coating preparation method

A protective coating and silicide technology, applied in the field of surface engineering, can solve the problems of reducing product quality and production efficiency, reducing the service life of components, affecting the quality of glass products, etc., to slow down the corrosion rate, avoid corrosion, and combine dense effects.

Active Publication Date: 2021-12-21
NORTHWESTERN POLYTECHNICAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

On the one hand, the harsh high-temperature corrosion environment will reduce the service life of the above-mentioned components, causing early cracks and structural deformation, forcing frequent replacement of parts and increasing production costs; on the other hand, alloy corrosion failure will also affect the quality of glass products, such as Metal ions produced by alloy dissolution will contaminate glass components, and deformation of formed parts will increase glass defective rate and reduce product quality and production efficiency

Method used

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  • A protective coating material resistant to high temperature silicide corrosion and coating preparation method
  • A protective coating material resistant to high temperature silicide corrosion and coating preparation method
  • A protective coating material resistant to high temperature silicide corrosion and coating preparation method

Examples

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Effect test

Embodiment 1

[0052] The invention provides a method for cold spraying on the outer surface of a workpiece, using In718 as the substrate (see Table 1 for the composition), the length of the workpiece is 100 mm, the width is 50 mm, and the spraying powder is Nb, Ni, mixed powder after Si ball milling, specifically comprising the following steps :

[0053] Step 1: ball milling Nb, Ni, Si elemental powders for later use, figure 1 , 2, 3 give the original powder morphology of Nb, Ni and Si used, and the ball milling process is as follows:

[0054] (1) Take 500g, 1500g, and 200g of 6mm, 10mm, and 20mm steel balls respectively, wash the ball mill jar and steel balls with a volume of 1L, and dry them in air.

[0055] (2) The elemental Nb, Ni, and Si powders are respectively 65g, 110g, and 23g into ball milling tanks according to the mass ratio of Nb accounting for 32.8%, Ni accounting for 55.6%, and Si accounting for 11.6%. Get stearic acid 4g and add ball mill jar again.

[0056] (3) The ball ...

Embodiment 2

[0077] The invention provides a method for cold spraying on the outer surface of a workpiece, using In718 as the substrate (see Table 1 for the composition), the length of the workpiece is 100 mm, the width is 50 mm, and the spraying powder is Nb, Ni, mixed powder after Si ball milling, specifically comprising the following steps :

[0078] Step 1: The Nb, Ni, Si simple substance powders are ball milled for later use, the ball milling process is as follows:

[0079] (1) Take 500g, 1500g, and 200g of 6mm, 10mm, and 20mm steel balls respectively, wash the ball mill jar and steel balls with a volume of 1L, and dry them in air.

[0080] (2) With elemental Nb, Ni, Si powder according to mass ratio, Nb accounts for 30%, Ni accounts for 50%, Si accounts for 10%, get respectively 60g, 100g, 20g and pack in the ball mill jar. Get stearic acid 4g and add ball mill jar again.

[0081] (3) The ball mill jar is sealed, and argon gas is introduced after vacuumizing. This process is repea...

Embodiment 3

[0102] The invention provides a method for cold spraying on the outer surface of a workpiece, using In718 as the substrate (see Table 1 for the composition), the length of the workpiece is 100 mm, the width is 50 mm, and the spraying powder is Nb, Ni, mixed powder after Si ball milling, specifically comprising the following steps :

[0103] Step 1: The Nb, Ni, Si simple substance powders are ball milled for later use, the ball milling process is as follows:

[0104] (1) Take 500g, 1500g, and 200g of 6mm, 10mm, and 20mm steel balls respectively, wash the ball mill jar and steel balls with a volume of 1L, and dry them in air.

[0105] (2) With elemental Nb, Ni, Si powder according to mass ratio, Nb accounts for 25%, Ni accounts for 50%, Si accounts for 25%, get 50g, 100g, 50g respectively and pack in the ball mill jar. Get stearic acid 4g and add ball mill jar again.

[0106] (3) The ball mill jar is sealed, and argon gas is introduced after vacuumizing. This process is repea...

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Abstract

The invention relates to a protective coating material and coating preparation method resistant to high temperature silicide corrosion. The coating is made of Nb 3 Ni 2 Si, Nb 0.1 Ni 0.9 and NbNi 3 main phase structure. Experiments have confirmed that the corrosion rate of the substrate is greatly reduced in the simulated molten glass environment, and it has excellent corrosion resistance. In addition, the present invention also provides a method for preparing the coating: Nb-Ni-Si intermetallic compound coating is prepared by mechanical ball milling of Nb, Ni and Si elemental powders and then adopting cold spraying technology and subsequent heat treatment. It has the characteristics of low cost, simple and easy to control, fast speed, uniform thickness and high coating quality.

Description

technical field [0001] The invention belongs to the field of surface engineering, and relates to a high-temperature silicide corrosion-resistant protective coating material and a preparation method for the coating, in particular to a protective coating material and a preparation method for the outer wall of a workpiece in direct contact with molten silicide. Background technique [0002] As an important class of inorganic non-metallic materials, glass is closely related to important industrial sectors such as construction, electrical appliances, and automobiles, as well as people's lives. Glass products are formed in a high-temperature molten state. Because the melt is extremely corrosive, many links in the product manufacturing process involve corrosion failure of alloy parts. For example, in the glass fiber manufacturing process, high-temperature molten glass (1000-1200 ° C) enters the high-speed rotating alloy nozzle, and is sprayed out through the micropores on the surfa...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C24/04C22C19/03C22F1/10C22F1/02
CPCC23C24/04C22C19/03C22F1/10C22F1/02
Inventor 徐雅欣纪白金李文亚杨夏炜
Owner NORTHWESTERN POLYTECHNICAL UNIV