A kind of decarbonization filter device and the method for preparing aminolevulinic acid hydrochloride
A filter device and filter plate technology, applied in the separation method, filter separation, filter circuit, etc., can solve the problems of affecting the progress, poor filtration efficiency, slow speed, etc., and achieve the effect of good quality, short process and simple operation steps
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Embodiment 1
[0048] Embodiment 1: a kind of decarbonization filtering device, such as figure 1 As shown, it includes a frame 1, and a casing 2 fixedly installed on the frame 1 with an open upper end and a hollow interior. The casing 2 is in the form of a cylindrical barrel, and a cover 3 is detachably connected to the opening. The above-mentioned cover body 3 can be sealed and closed on the casing 2, and the casing 2 is provided with a material inlet 5 and a material outlet 6 sequentially from bottom to top.
[0049] like figure 1 As shown, in order to increase the retention of activated carbon, a filter plate 7 arranged horizontally is rotatably connected to the housing 2 . The filter plate 7 is disc-shaped, and there is a gap between it and the inner wall of the housing 2 . There is a filter cavity 8 between the filter plate 7 and the feed port 5. The filter plate 7 communicates with a central tube 9 on the side away from the filter cavity 8, and the central tube 9 communicates with a p...
Embodiment 2
[0056] Embodiment 2: a kind of method for preparing aminolevulinic acid hydrochloride comprises the following steps:
[0057] Step 1. Add 5-phthalimide levulinic acid to 400ml of 5mol / L hydrochloric acid solution, reflux for 4 hours, cool slightly, add activated carbon, and decolorize through the decarbonization filter device of Example 1 at 80°C. Cool to 5°C and filter. Concentrate the filtrate, cool at 5°C, precipitate crystals, filter, and vacuum-dry the filter cake for 4 hours under a vacuum of 0.8 MPa to obtain the crude product.
[0058] Wherein, the molecular formula of 5-phthalimide levulinic acid: C13H11O5N, its chemical structural formula is as follows:
[0059]
[0060] Step 2, finish processing: add the water (60 ℃) of the same quantity as crude product feeding amount to dissolve crude product, filter, add the acetone of 50wt% of crude product feeding amount, cool to room temperature (20 ℃), place 4 ℃, after 3 hours put The solid-liquid mixture was filtered, a...
Embodiment 3
[0063] Embodiment 3: a kind of method for preparing aminolevulinic acid hydrochloride comprises the following steps:
[0064] Step 1. Add 5-phthalimide levulinic acid into 500ml of 8mol / L hydrochloric acid solution, reflux for 8 hours, cool slightly, add activated carbon, and decolorize through the decarbonization filter device of Example 1 at 90°C. Cool to 15°C and filter. Concentrate the filtrate, cool at 15°C, precipitate crystals, filter, and vacuum-dry the filter cake for 5 hours under a vacuum of 1.0 MPa to obtain the crude product.
[0065] Step 2, finishing: add the water (75 ℃) of the same quantity as crude product feeding amount to dissolve crude product, filter, add the acetone of 50wt% of crude product feeding rate, cool to room temperature (20 ℃), place 8 ℃, after 4 hours put The solid-liquid mixture was filtered, and the obtained crystal was vacuum-dried for 15 hours to obtain the fine product of aminolevulinic acid hydrochloride.
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