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Method for pre-lithiation of lithium-ion battery negative electrode and preparation method of pre-lithiation lithium-ion battery

A lithium-ion battery and negative electrode technology, which is applied in the direction of battery electrodes, electrolyte battery manufacturing, secondary batteries, etc., can solve the problem of low efficiency of lithium-ion batteries for the first time

Active Publication Date: 2021-05-11
NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem solved by the present invention is to provide a method for pre-lithiation of the negative electrode of lithium-ion batteries. The pre-lithiation method provided by the application can improve the problem of low initial efficiency of lithium-ion batteries, and can also improve the preparation of pre-lithiation cells efficiency

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  • Method for pre-lithiation of lithium-ion battery negative electrode and preparation method of pre-lithiation lithium-ion battery
  • Method for pre-lithiation of lithium-ion battery negative electrode and preparation method of pre-lithiation lithium-ion battery
  • Method for pre-lithiation of lithium-ion battery negative electrode and preparation method of pre-lithiation lithium-ion battery

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preparation example Construction

[0034] After the negative electrode of the lithium-ion battery is pre-lithiated, the application then proceeds to the preparation of the lithium-ion battery, specifically as follows figure 1 Shown, the application also provides a kind of preparation method of the lithium-ion battery through pre-lithiation, comprises the following steps:

[0035] A) pressing the lithium foil on the negative electrode sheet; the negative electrode sheet is in a semi-dry state;

[0036] B) placing the negative electrode sheet obtained in step A) in an airtight bag for vacuum treatment;

[0037] C) Assemble the negative electrode sheet and the positive electrode sheet obtained in step B), inject electrolyte solution, and then dissolve into volume after standing to obtain a lithium ion battery.

[0038] After the lithium-ion battery described in this application is pre-lithiated, conventional preparation is carried out. Steps A) and B) have been described in detail above, and will not be repeated ...

Embodiment 1

[0043] Lithium-rich manganese is used as the positive electrode material, and silicon carbon is used as the negative electrode material;

[0044]Coat the positive and negative electrodes on the current collector; after pressing and cutting, the negative electrode sheet (water content is 600-1000ppm) and the positive electrode sheet are obtained; the ultra-thin lithium foil (3-7μm) is pressed on the cut sheet by rolling Put the cut negative electrode sheet on the vacuum treatment and let it stand for 12 hours, then assemble the battery with the cut lithium-rich positive electrode sheet; then inject the electrolyte and let it stand at 20-45°C for 12-24 hours, and then perform chemical composition and volume to obtain Lithium Ion Battery.

[0045] figure 2 Be the photo before and after the pre-lithium of the negative electrode sheet of the present embodiment, by figure 2 It can be seen that the lithium foil on the surface of the negative electrode sheet has been used up after...

Embodiment 2

[0047] The preparation method is the same as in Example 1, except that: the negative electrode material is hard carbon; the water content of the negative electrode sheet is 1000ppm-1500ppm; the thickness of the lithium foil is 5-10 μm.

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Abstract

The invention provides a method for pre-lithiation of the negative electrode of a lithium ion battery, comprising the following steps: A) pressing lithium foil on the negative electrode sheet; the negative electrode sheet is in a semi-dry state; B) placing the negative electrode sheet obtained in step A) Vacuumize in an airtight bag. The present application also provides a preparation method of the pre-lithiated lithium ion battery. In this application, the SEI film can be produced by performing pre-lithiation on the negative electrode, so that the lithium released from the positive electrode will not be consumed in the formation of the SEI film during the formation process, and the active lithium consumed by the reaction with the electrolyte and other irreversible side reactions can also be reduced. Lithium, thereby reducing the irreversible capacity and improving the first efficiency and capacity of Li-ion batteries.

Description

technical field [0001] The invention relates to the technical field of high energy density lithium-ion battery manufacturing, in particular to a method for pre-lithiation of a negative electrode of a lithium-ion battery and a method for preparing a pre-lithiated lithium-ion battery. Background technique [0002] Lithium-ion batteries have the advantages of high energy density and good cycle performance, so they have received extensive attention. With the popularization of mobile Internet devices, the promotion of electric vehicles and other electric vehicles, and the development of aerospace technologies such as drones and space probes, the performance of lithium-ion batteries is facing higher development requirements. How to increase the volume of lithium-ion batteries Energy density and mass energy density have become the key breakthrough directions of high-performance lithium-ion batteries. [0003] Most researchers use silicon-based anode materials with high gram capaci...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/139H01M10/058H01M10/0525
CPCH01M4/139H01M10/0525H01M10/058Y02E60/10Y02P70/50
Inventor 云亮彭小强游江枫刘兆平
Owner NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI