Waterproof spraying agent as well as preparation method and application thereof
A spray and initiator technology, applied in the field of waterproof spray, can solve the problems of complex application process, poor waterproof effect and poor aging effect, and achieve the effects of simple operation, long waterproof aging, and improved adhesion and film-forming properties.
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Embodiment 1
[0035] A waterproof spray, comprising the following raw materials in parts by weight:
[0036]
[0037] The fluorocarbon resin is a mixture of fluoroether resin and acrylic fluorinated resin at a weight ratio of 5:1.5; the weight average molecular weight of the fluoroether resin is 8000, and the weight average molecular weight of the acrylic fluorinated resin is 15000 .
[0038] The fluorinated ether resin is a trifluoroethylene-vinyl ether copolymer.
[0039] Described acrylic acid fluorinated resin is made by following method:
[0040] (R1), 26 parts by weight of butyl acrylate, 35 parts of styrene, 8 parts of glycidyl methacrylate, 18 parts of hydroxypropyl acrylate, 2 parts of acrylic acid, 2.5 parts of initiator, 18 parts of fluorine-containing acrylic acid monomer Body and 90 parts of organic solvent B, standby;
[0041](R2), butyl acrylate, styrene, glycidyl methacrylate, hydroxypropyl acrylate, acrylic acid, a part of the initiator and a part of the organic solve...
Embodiment 2
[0055] A waterproof spray, comprising the following raw materials in parts by weight:
[0056] Fluorocarbon resin 20 parts
[0057] 1 part polysilazane
[0058] 55 parts of organic solvent A.
[0059] The fluorocarbon resin is a mixture of fluoroether resin and acrylic fluorinated resin at a weight ratio of 5:1; the weight average molecular weight of the fluoroether resin is 5000, and the weight average molecular weight of the acrylic fluorinated resin is 5000 .
[0060] The fluorinated ether resin is tetrafluoroethylene-vinyl ether copolymer.
[0061] Described acrylic acid fluorinated resin is made by following method:
[0062] (R1), 25 parts by weight of butyl acrylate, 30 parts of styrene, 5 parts of glycidyl methacrylate, 10 parts of hydroxypropyl acrylate, 1 part of acrylic acid, 2 parts of initiator, 10 parts of fluorine-containing acrylic acid mono Body and 80 parts of organic solvent B, standby;
[0063] (R2), butyl acrylate, styrene, glycidyl methacrylate, hydr...
Embodiment 3
[0075] A waterproof spray, comprising the following raw materials in parts by weight:
[0076]
[0077] The fluorocarbon resin is a mixture of fluoroether resin and acrylic fluorinated resin at a weight ratio of 5:2; the weight average molecular weight of the fluoroether resin is 20,000, and the weight average molecular weight of the acrylic fluorinated resin is 20,000 .
[0078] The fluorinated ether resin is a trifluoroethylene-vinyl ether copolymer.
[0079] Described acrylic acid fluorinated resin is made by following method:
[0080] (R1), take by weight 28 parts of butyl acrylate, 40 parts of styrene, 10 parts of glycidyl methacrylate, 25 parts of hydroxypropyl acrylate, 3 parts of acrylic acid, 3 parts of initiator, 25 parts of fluorine-containing acrylic acid mono Body and 100 parts of organic solvent B, standby;
[0081] (R2), butyl acrylate, styrene, glycidyl methacrylate, hydroxypropyl acrylate, acrylic acid, a part of the initiator and a part of the organic s...
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