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Method for improving strength of low-carbon magnesium-carbon material

A magnesium-carbon, high-strength technology, applied in the field of refractory materials, can solve problems such as insufficient strength of magnesium-carbon materials, and achieve the effects of improving mechanical properties, increasing costs, and reducing costs

Inactive Publication Date: 2020-06-30
营口石兴耐火材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The present invention focuses on the shortcomings of the above-mentioned low-carbon magnesium-carbon materials, and aims to solve the defects of insufficient strength of magnesium-carbon materials after low carbonization

Method used

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  • Method for improving strength of low-carbon magnesium-carbon material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A method for improving the strength of low-carbon magnesia-carbon materials, made by the following steps:

[0026] (1) Mixing. Add magnesia (85%), carbon (5%), antioxidant (4%), binder (4%), silicon-rich waste (2%) raw materials step by step according to the mass fraction and mix them in the mixer .

[0027] (2) Forming. Pour the above configured powder into a stainless steel mold and press it on a hydraulic press at 150 MPa.

[0028] (3) Heat treatment. Insulated at 180 °C for 15 h to make non-burning low-carbon magnesium-carbon materials.

[0029] Among them, the carbon is 3% flake graphite and 2% nano-carbon black; the antioxidant is aluminum powder; the binder is tar pitch; the silicon-rich waste consists of Si (50%), SiC (30%), SiO 2 (8%), other impurities (12%).

[0030] The relevant performance indicators of this embodiment are as follows:

[0031] The apparent porosity is 8.76%, and the bulk density is 3.02 g cm -3 , The compressive strength at room temp...

Embodiment 2

[0033] A method for improving the strength of low-carbon magnesia-carbon materials, made by the following steps:

[0034] (1) Mixing. Add magnesia (86%), carbon (8%), antioxidant (1%), binder (1%), silicon-rich waste (4%) raw materials step by step according to the mass fraction and mix them in the mixer .

[0035] (2) Forming. Pour the above configured powder into a stainless steel mold and press it on a hydraulic press at 200 MPa.

[0036] (3) Heat treatment. The sintered carbon-magnesium-carbon material was prepared at 1400 °C for 6 h.

[0037] Among them, the carbon is flake graphite; the antioxidant is aluminum powder; the binder is tar pitch; the silicon-rich waste consists of Si (60%), SiC (20%), SiO 2 (10%), other impurities (10%).

[0038] The relevant performance indicators of this embodiment are as follows:

[0039] The apparent porosity is 7.52%, and the bulk density is 3.09 g cm -3 , The compressive strength at room temperature is 62.17 MPa, the flexural s...

Embodiment 3

[0041] A method for improving the strength of low-carbon magnesia-carbon materials, made by the following steps:

[0042] (1) Mixing. Add magnesia (90%), carbon (6%), antioxidant (2%), binder (1%), silicon-rich waste (1%) raw materials step by step according to the mass fraction and mix them in the mixer .

[0043] (2) Forming. Pour the above configured powder into a stainless steel mold and press it on a hydraulic press at 200 MPa.

[0044] (3) Heat treatment. Insulated at 230 °C for 10 h to make unburned carbon-magnesium-carbon materials.

[0045] Among them, the carbon is 3% flake graphite and 3% nano-carbon black; the antioxidant is silicon powder; the binder is tar pitch; the silicon-rich waste consists of Si (54%), SiC (26%), SiO 2 (7%), other impurities (13%).

[0046] The relevant performance indicators of this embodiment are as follows:

[0047] The apparent porosity is 7.61%, and the bulk density is 3.08 g cm -3 , The compressive strength at room temperature ...

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Abstract

The invention particularly relates to a method for improving the strength of a low-carbon magnesium-carbon material. The method comprises steps: magnesia, carbon, an antioxidant and a binder are mixedaccording to a certain ratio, a silicon-rich waste is introduced during mixing, and the low-carbon magnesium-carbon material is prepared through pressing and heat treatment (including a low-temperature type and a high-temperature type). Due to the introduction of the silicon-rich waste, the mechanical properties of the low-carbon magnesium-carbon material can be enhanced in two modes of low-temperature mechanical integration and high-temperature ceramic combination. Meanwhile, the introduced material is an industrial waste, so that almost no extra cost is caused, and the method has very goodindustrial popularization and application prospects.

Description

technical field [0001] The invention belongs to the technical field of refractory materials, and in particular relates to a method for improving the strength of low-carbon magnesium-carbon materials. Background technique [0002] Magnesium carbon refractory is a new type of basic refractory developed by Japan Kyushu Refractory Company in the late 1970s. It has good slag resistance and thermal shock resistance, and can effectively increase the service life of refractory materials. It has been widely used in key parts such as converter and electric furnace lining, ladle slag line and so on. The reason why magnesium carbon materials have such excellent comprehensive performance is mainly due to the introduction of carbon. Because carbon is almost non-wetting with slag at high temperature, so slag and molten steel cannot enter the interior of the refractory. In this way, the loss of refractory materials during service can be greatly reduced, and its service life can be effecti...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/043
CPCC04B35/043C04B2235/402C04B2235/424C04B2235/425C04B2235/428C04B2235/5427C04B2235/5436C04B2235/602C04B2235/656C04B2235/6567C04B2235/77C04B2235/96
Inventor 马北越任鑫明石明东高陟
Owner 营口石兴耐火材料科技有限公司