Aluminum-titanium-boron-strontium-rare earth alloy wire rod and preparation method

A rare earth alloy, aluminum titanium boron technology, applied in the field of aluminum alloy, can solve the problems of insufficient deterioration of the casting billet, linear stripe defects, alloy surface defects, etc., and achieve the effects of better distribution, uniform distribution and low production efficiency.

Active Publication Date: 2020-06-30
永城金联星铝合金有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, AlSr10 furnace modification treatment and AlTi5B1 on-line refinement treatment have obvious shortcomings, because the furnace treatment of AlSr10 alloy will produce a large amount of Sr loss, and the Sr loss will continue to oxidize and burn with the prolongation of the standing time, especially It is more serious when the molten aluminum is stirred or tumbled
With the prolongation of time, the strontium content in the slab gradually decreases, resulting in insufficient deterioration of some slabs, and the oxidation and burning of strontium is accompanied by severe gas absorption of molten aluminum.
In the process of adding AlTi5B1 to the online thinning launder, the typical disadvantage of AlTi5B1 is that Ti and B elements sink and deposit in places such as the launder, filter box and the bottom of the flow plate. The serious accumulation of Ti and B leads to surface defects of the alloy. Both rolled and extruded products have problems such as linear streak defects

Method used

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  • Aluminum-titanium-boron-strontium-rare earth alloy wire rod and preparation method
  • Aluminum-titanium-boron-strontium-rare earth alloy wire rod and preparation method

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Experimental program
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Effect test

Embodiment 1

[0034] Embodiment 1 A kind of preparation method of aluminum-titanium-boron-strontium-rare earth alloy wire rod

[0035] An aluminum-titanium-boron-strontium-rare earth alloy wire rod, the weight ratio of its components is: metal aluminum: potassium fluorotitanate: potassium fluoroborate: lanthanum cerium mixed rare earth: metal strontium = 100:25:12:5:5 ; Composition by weight percentage in lanthanum-cerium mixed rare earth: lanthanum 35%, cerium 65%.

[0036] The preparation method of the aluminum-titanium-boron-strontium-rare earth alloy wire rod comprises the following steps:

[0037] (1) Put 5000kg of aluminum ingot into the melting furnace to melt, then discharge 2000kg of molten aluminum into the electromagnetic induction furnace and heat to 750°C for later use;

[0038] (2) After fully mixing 500kg of potassium fluotitanate and 240kg of potassium fluoborate, add it into the molten aluminum while stirring, and continue to mechanically stir for 10 minutes after the addi...

Embodiment 2

[0046] Performance analysis and application test of embodiment 2 products of the present invention

[0047] 1. Metallographic analysis

[0048] Compare the metallographic pictures of the product of the present invention and the existing AlTi5B1 aluminum alloy product, as figure 1 shown.

[0049] The results show that the present invention adds rare earth elements in the alloy wire, so that TiAl in the modified and refined material 3 Size reduction, TiB 2 The distribution is more uniform and dispersed, which greatly improves the refining effect of the product and prolongs the refining time. Ti in the alloy wire during use 2 al 20 RE particles can quickly dissolve and release rare earth elements in molten aluminum, increasing the viscosity of molten aluminum and nucleating particles TiB 2 The surface activity of , promotes fast nucleation and hinders TiB 2 Coagulation and precipitation, so as to achieve better refinement effect.

[0050] By studying the influence of the ...

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Abstract

The invention provides an aluminum-titanium-boron-strontium-rare earth alloy wire rod and a preparation method. The aluminum-titanium-boron-strontium-rare earth alloy wire rod is prepared from, by weight, 90-110 parts of metallic aluminum, 20-30 parts of potassium fluotitanate, 10-15 parts of potassium fluoborate, 3-8 parts of lanthanum-cerium mixed rare earth and 3-8 parts of metallic strontium.The alloy wire can replace alloys needing to be refined and modified respectively, homogenization and extrusion treatment are used in the preparation process, product crystal grains are finer and moreuniform in distribution through multiple actions of heat treatment and external force, and the alloy wire rod is more efficient than a traditional product.

Description

technical field [0001] The invention relates to an aluminum-titanium-boron-strontium-rare earth alloy wire and a preparation method thereof, belonging to the technical field of aluminum alloys. Background technique [0002] Refinement and modification of aluminum alloy structure are necessary means to obtain excellent aluminum alloy properties. In order to refine the α grains, refiners with different elements such as Al-Ti, Al-Ti-B, Al-Ti-C and different element contents have been developed (such as AlTi10, AlTi5B1, AlTi5B0.2, AlTi5C0.2, etc. ) to adapt to the refinement of different aluminum alloy products. At the same time, in order to change the morphology and size of the second phase in the aluminum alloy, it is necessary to modify the aluminum alloy, for example, the hypoeutectic Al-Si alloy is modified by strontium. For this reason, people have developed AlSr alloy modifiers of different compositions (such as AlSr5, AlSr10, etc.) to modify the Al-Si eutectic phase in...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C21/00B21C37/04C22C1/06C22C1/10C22C1/03
CPCB21C37/04C22C1/06C22C1/1036C22C21/003
Inventor 陈勇刚陈闻天陈建春陈欢
Owner 永城金联星铝合金有限公司
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