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Digestion solution for digesting organic impurities in micro-plastics, preparation method of digestion solution and digestion method based on digestion solution

A technology of organic impurities and digestion solution, which is applied in the field of impurity treatment in microplastics. It can solve the problems of device system impact, ineffective application, and experimental danger, etc., achieve high digestion rate, and alleviate the difficulty of qualitative detection of microplastics.

Inactive Publication Date: 2020-07-10
OCEANOGRAPHIC INSTR RES INST SHANDONG ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, a large amount of gas and heat are often released during the violent reaction of the Fenton reagent, and the operation of the Fenton reagent method cannot be separated from manual work, which has potential experimental dangers; especially in the construction of in-situ automatic processing equipment for samples, It is easy to cause a large impact on the device system and cannot be used effectively; on the other hand, the solution generated by the Fenton reagent reaction is yellow and rich in a large amount of ferric ions. interference
It can be seen that there are certain defects in the existing methods for the digestion of organic impurities in the above two commonly used microplastics.

Method used

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  • Digestion solution for digesting organic impurities in micro-plastics, preparation method of digestion solution and digestion method based on digestion solution
  • Digestion solution for digesting organic impurities in micro-plastics, preparation method of digestion solution and digestion method based on digestion solution
  • Digestion solution for digesting organic impurities in micro-plastics, preparation method of digestion solution and digestion method based on digestion solution

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preparation example Construction

[0059] According to one aspect of the present invention, a kind of preparation method of above-mentioned digestion liquid, described preparation method comprises the following steps:

[0060] Mixing an aqueous solution of potassium persulfate and an aqueous solution of an alkaline compound to obtain a digestion solution, the concentration of potassium persulfate in the digestion solution is 0.1-0.35 mol / L, and the concentration ratio of potassium persulfate and alkaline compound is 1:1-3;

[0061] The preparation method of the above-mentioned digestion liquid provided by the present invention, the above-mentioned method is to mix potassium persulfate aqueous solution and alkaline compound aqueous solution to obtain digestion liquid, the concentration of potassium persulfate in the digestion liquid is 0.1~0.35mol / L, potassium persulfate Concentration ratio with basic compound is 1:1~3. The above preparation method has a simple process and is easy to operate.

[0062] In the ab...

Embodiment 1

[0087] A digestion solution for digesting organic impurities in microplastics, the preparation method of the digestion solution comprises the following steps:

[0088] (a) When preparing 1L of digestion solution, dissolve 27g of potassium persulfate in 700-800mL of deionized water at about 30°C, dissolve 8g of sodium hydroxide in 50-100mL of deionized water and cool to prepare persulfuric acid Potassium solution and sodium hydroxide solution;

[0089] (b), the potassium persulfate solution obtained in step (a) is mixed with sodium hydroxide solution to obtain a mixed solution, and the concentration of potassium persulfate in the mixed solution is adjusted to 0.1mol / L, and the concentration of sodium hydroxide is 0.2mol / L L, made the digestion solution;

[0090] The mixing temperature of the potassium persulfate solution and the alkaline compound solution in the step (b) is 10-30°C.

Embodiment 2

[0092] A digestion solution for digesting organic impurities in microplastics, the preparation method of the digestion solution comprises the following steps:

[0093] (a) When preparing 1L of digestion solution, dissolve 94.5g of potassium persulfate in 700-800mL of deionized water at about 30°C, dissolve 14g of sodium hydroxide in 50-100mL of deionized water and cool to prepare over Potassium sulfate solution and sodium hydroxide solution;

[0094](b), the potassium persulfate solution obtained in step (a) is mixed with sodium hydroxide solution to obtain a mixed solution, and the concentration of potassium persulfate in the mixed solution is adjusted to 0.35mol / L, and the concentration of sodium hydroxide is 0.35mol / L L, made the digestion solution;

[0095] The mixing temperature of the potassium persulfate solution and the alkaline compound solution in the step (b) is 10-30°C.

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Abstract

The invention provides a digestion solution for digesting organic impurities in micro-plastics, a preparation method of the digestion solution and a digestion method based on the digestion solution, and relates to the technical field of micro-plastic impurity treatment. The digestion solution comprises potassium persulfate and an alkaline compound, and the concentration ratio of the potassium persulfate to the alkaline compound in the digestion solution is 1: (1-3), wherein the concentration of potassium peroxodisulfate in the digestion solution is 0.1 to 0.35 mol / L. When the digestion solution containing the potassium peroxodisulfate with the specific concentration and the alkaline compound is used for digesting the organic impurities in the micro-plastic, high digestion rate of organic impurities in the micro-plastic is realized without damage to the micro-plastic or interference of the colorless reaction system on the subsequent qualitative detection of the micro-plastic, and effective alleviation of the difficult qualitative detection of the micro-plastic caused by the general mixing of a large amount of organic impurities in the micro-plastic sample in present environments canbe realized.

Description

technical field [0001] The invention relates to the technical field of impurity treatment in microplastics, in particular to a digestion solution for digesting organic impurities in microplastics, a preparation method thereof, and a digestion method based on the digestion solution. Background technique [0002] "Microplastics" refers to plastic fragments, particles, fibers or films with a particle size of less than 5 mm. With the development of modern science and technology, plastics are widely used around the world, and the distribution of microplastics with a particle size below 5mm shows a global trend and brings persistent pollution to the marine environment. Microplastics in the environment migrate to various places through different transport mechanisms, including surface water bodies, deep water bodies, sediments, and even Arctic sea ice. Therefore, research on the harm of microplastics to the marine environment and even the global ecology, and the establishment of a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N1/34
CPCG01N1/34
Inventor 高楠孔祥峰吕红敏王茜刘岩
Owner OCEANOGRAPHIC INSTR RES INST SHANDONG ACAD OF SCI
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