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A method of improving the strength of molten salt phase change heat storage material by using phenolic resin

A technology of phase change heat storage material and phenolic resin, which is applied in the direction of heat exchange materials, chemical instruments and methods, can solve the problems of insufficient mechanical properties of heat storage materials and low impact on heat storage performance, and achieve the solution of insufficient mechanical properties, The effect of low cost and widening the scope of use

Active Publication Date: 2021-06-08
UNIV OF SCI & TECH BEIJING
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The present invention aims at the problem of insufficient mechanical properties of ceramic base (magnesia, diatomite) heat storage materials composed of molten salt phase change heat storage materials (nitrates, carbonates and multi-element eutectic salts), and uses phenolic resin bonding The original structure is more stable, and at the same time, the decomposition of phenolic resin during high temperature treatment can provide a carbon structure that makes the ceramic matrix more stable, making the mechanical properties of the phase change heat storage body more excellent, and the phenolic resin and its decomposed The carbon structure has a good thermal conductivity and has a low impact on the heat storage performance. Finally, a phase change heat storage body with excellent mechanical properties and heat storage performance can be prepared.

Method used

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  • A method of improving the strength of molten salt phase change heat storage material by using phenolic resin
  • A method of improving the strength of molten salt phase change heat storage material by using phenolic resin

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Embodiment 1

[0019] The method for improving the strength of molten salt phase change heat storage material by using phenolic resin provided in this embodiment includes the following steps:

[0020] 1. Preparation of molten salt particles

[0021] (1) Select Na 2 CO 3 with K 2 CO 3 As a heat storage medium, mix with a ratio of 52:48, and use a ball mill to mill at a ball-to-material ratio of 1:1 and a speed of 110 rpm for 30 minutes to make Na 2 CO 3 with K 2 CO 3 Mix well to prepare hydrated eutectic salt.

[0022] (2) dissolving the mixed mixture in water, stirring evenly, placing it in an oven, and drying it for 72 hours to prepare a hydrated eutectic salt;

[0023] (3) Crush and grind the prepared hydrated eutectic salt into powder, place the powder in spherical abrasives of different diameters, add a small amount of water, press at a pressure of 10Mpa, and sinter at 680°C to prepare Molten salt particles of different particle sizes are ready for use.

[0024] 2. Press and si...

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Abstract

The invention discloses a method for improving the strength of a molten salt phase-change heat storage material by using a phenolic resin, and belongs to the field of phase-change heat storage materials. The present invention is based on a preparation method of a stable molten salt phase change material, using ceramic materials as a matrix and phenolic resin as a binder to provide a stable structure through the ceramic matrix, and formability provided by the phenolic resin, plus the carbon structure produced by the high-temperature partial cracking of the phenolic resin Furthermore, a molten salt phase change heat storage body with excellent mechanical properties can be obtained. The preparation method of the invention is simple, low in cost and can be produced on a large scale, solves the currently common problem of insufficient mechanical properties of molten salt phase-change heat storage materials, and has great significance for expanding the application range of molten salt phase-change heat storage materials.

Description

technical field [0001] The invention belongs to the field of phase change heat storage materials, in particular to a method for improving the strength of molten salt phase change heat storage materials by using phenolic resin. Background technique [0002] As a national strategic emerging industry, energy storage technology is an important part of energy conversion and utilization technology. Choosing a suitable energy storage technology route is of great significance for improving the utilization efficiency of renewable energy, enhancing the peak-shaving capability of thermal power generation, and alleviating power grid dispatching. It is of great significance, and its large-scale application will have a major impact on energy transformation, power grid pattern, and power supply structure. Heat storage material is the core and key of heat storage technology. It collects and stores the excess energy that is temporarily unused for a period of time or in a certain space, and r...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K5/06
CPCC09K5/063
Inventor 郝俊杰张靖岑卢昀坤任中凯郭志猛陈存广
Owner UNIV OF SCI & TECH BEIJING
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