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Single-component high-heat-resistance vacuum forming adhesive and preparation method thereof

A vacuum suction, high heat resistance technology, applied in the direction of adhesives, adhesive types, polymer adhesive additives, etc., can solve the problems of insufficient heat resistance, waste of glue, limitations of on-site construction operations, etc., to achieve good surface effects , saving man-hours, good atomization effect

Inactive Publication Date: 2020-09-29
顶立新材料科技股份有限公司 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, adhesives with low activation temperature often have insufficient heat resistance. In vacuum blistering of high-gloss films and thicker PVC films, curing agents are often used to enhance the adhesive force of the adhesive.
The heat resistance can be improved to 70-75°C by adding a curing agent through two components, but due to the limitation of the active period of the two components, it can only be used for two hours after deployment, which brings operational restrictions and glue waste to the on-site construction.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] The present invention provides a one-component high heat-resistant vacuum plastic absorber, which is obtained by the following method:

[0021] Take by weighing 50 parts by weight of the VAE emulsion whose solid content is 50wt%, the model is Wacker VAE706k, its pH is 7.1, add 5 parts by weight of the VAE emulsion with a solid content of 50wt%, the model is Celanese modified VAE emulsion, and then Add 40 parts by weight of PUD emulsion with a solid content of 44wt%, the model is Covestro U66 PUD emulsion, mix and stir evenly, and then add 5 parts by weight of Sendy Chemical's water-based blocked isocyanate curing agent BI522, 3 parts by weight with a viscosity of 50 -200mPa·S Japanese Kelisi polycarbodiimide resin CARBODILITE V-02, 0.1 parts by weight of Digo 800 mineral oil defoamer, 0.3 parts by weight of Dow rm-12W associative polyurethane thickener , 0.1 parts by weight of Tego 650 polycarboxylate sodium salt dispersant, after stirring evenly, vacuum-absorbing plast...

Embodiment 2

[0023] (1) Weigh 40 parts by weight of Wacker VAE 706k with a solid content of 57wt%, 40 parts by weight of Covestro U66 PUD emulsion with a solid content of 52wt%, and 10 parts by weight of Celanese modified with a solid content of 57wt%. VAE emulsion, 8 parts by weight of Sendy Chemical's water-based blocked isocyanate curing agent BI522, 5 parts by weight of Japanese Kelisi polycarbodiimide resin CARBODILITE V-02 with a viscosity of 50-200mPa·S, 0.01 parts by weight of pH adjustment Agent, 0.2 parts by weight of Digo 800 mineral oil defoamer, 0.2 parts by weight of Digo 650 polycarboxylate sodium salt dispersant, 0.5 parts by weight of Dow rm-12W associative polyurethane thickener.

[0024] (2) Use a pH regulator to adjust the pH of WACKER VAE 706k to 7.7, then add Celanese modified VAE emulsion, then add PUD emulsion and mix well, then add water-based blocked isocyanate, polycarbodiimide resin, Defoamer, thickener, dispersant, after stirring evenly, make vacuum suction pla...

Embodiment 3

[0026] (1) Weigh 30 parts by weight of Wacker VAE 706k with a solid content of 54wt%, 55 parts by weight of Covestro U66 PUD emulsion with a solid content of 46wt%, and 7 parts by weight of Celanese modified with a solid content of 54wt%. VAE emulsion, 5 parts by weight of Sendy Chemical's water-based blocked isocyanate curing agent BI522, 2 parts by weight of Japanese Kelisi polycarbodiimide resin CARBODILITE V-02 with a viscosity of 50-200mPa·S, 0.1 part by weight of pH adjustment Agent, 0.1 parts by weight of Tego 800 mineral oil defoamer, 0.1 parts by weight of Tego 650 polycarboxylate sodium salt dispersant, 0.3 parts by weight of Dow rm-12W associative polyurethane thickener.

[0027] (2) Use a pH regulator to adjust the pH of WACKER VAE 706k to 9, then add Celanese modified VAE emulsion, then add PUD emulsion and mix well, then add water-based blocked isocyanate, polycarbodiimide resin, Defoamer, thickener, dispersant, after stirring evenly, make vacuum suction plastic....

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Abstract

The invention discloses a single-component high-heat-resistance vacuum forming adhesive and a preparation method thereof. The vacuum forming adhesive comprises the following components in parts by weight: 20 to 50 parts of a VAE emulsion, 40 to 60 parts of a PUD emulsion, 2 to 10 parts of a modified VAE emulsion, 5 to 8 parts of waterborne blocked isocyanate, 2 to 5 parts of polycarbodiimide resin, 0 to 0.1 part of a pH regulator, 0.1 to 0.2 part of a defoaming agent, 0.1 to 0.2 part of a dispersing agent and 0.3 to 0.5 part of a thickening agent. The vacuum forming adhesive can be used and stored in a single-component manner, has no active period limitation and is convenient to operate; after closed isocyanate is heated, activated and unsealed, a final product has heat resistance of 80 DEG C, which exceeds the heat resistance temperature of a double-component vacuum forming adhesive. The activation temperature of the single-component high-heat-resistance vacuum forming adhesive is about 55 DEG C, so heating and cooling discharging time of a workpiece is saved in practical application, and working hours are reduced. The single-component high-heat-resistance vacuum forming adhesiveis small in particle size, good in atomization effect and good in the surface effect of formed highlight PVC.

Description

technical field [0001] The invention belongs to the technical field of adhesives, and in particular relates to a single-component high heat-resistant vacuum-absorbing adhesive and a preparation method thereof. Background technique [0002] With the improvement of people's material level, the level of interior decoration requirements continues to increase. The whole house customization that has emerged in recent years and the popularity of customized furniture have prompted explosive growth in panel furniture decoration. Among them, the panel furniture of PVC molded board is favored by many people. Its base material is density board, and the surface is formed by vacuum plastic absorption or a seamless PVC film pressing molding process. The advantage of this kind of furniture is that it is environmentally friendly. It does not need to use paint, and it is replaced by environmentally friendly PVC materials. There will be no release of harmful substances VOC in the later stage,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J175/04C09J131/04C09J11/08C09J11/06
CPCC09J175/04C09J131/04C09J11/08C09J11/06C08L2205/025C08L2205/035C08L2201/08
Inventor 万江阮灿伟张向阳赵飞戴启鹏钟冬芸傅耀
Owner 顶立新材料科技股份有限公司
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