An online prediction method of dioxin emissions based on generative path clustering and box-cox transformation

A technology of box-cox and forecasting methods, applied in forecasting, data processing applications, instruments, etc., can solve problems such as inability to verify validity, and achieve the effect of stable extrapolation performance and fewer parameters

Active Publication Date: 2022-01-11
ZHEJIANG UNIV
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Problems solved by technology

Machine learning based on neural networks predicts dioxin emissions through a large number of observed variables and control variables other than indicators. However, the large number of parameters of machine learning with small sample and high-dimensional data sets limits the effectiveness of this method. characteristics, resulting in the limitation that it can only be applied in a specific situation of a specific incineration plant

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  • An online prediction method of dioxin emissions based on generative path clustering and box-cox transformation
  • An online prediction method of dioxin emissions based on generative path clustering and box-cox transformation
  • An online prediction method of dioxin emissions based on generative path clustering and box-cox transformation

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Embodiment 1

[0034] Example 1: See figure 2 , which is the experimental data of dioxin concentration and chlorobenzene indicator concentration during long-term operation of large-scale solid waste incinerator. Experiments were carried out in a large-scale solid waste incineration grate furnace system with a processing capacity of 750t / d, and samples were collected from the end chimney of the flue gas purification system. Twenty-one 15-minute dioxin samples were collected by the EPA 23 method in step S1 within three months, and were measured online every 15 minutes by thermal desorption + gas chromatography + tunable laser ionization coupled time-of-flight mass spectrometry1, The concentration of 2,4-TrCBz, and the high moisture content of the three-month solid waste (about 50 wt%) are consistent with the characteristics of raw materials for most solid waste incineration processes in China.

[0035] In step S2, after generating path identification clusters, it is found that the boundary v...

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Abstract

The invention discloses an online prediction method of dioxin discharge based on generation path clustering and Box-Cox transformation, relates to the field of dioxin prediction, and includes the following steps: S1, establishing a data set; S2, cluster analysis, according to different Different dioxin generation pathways play a leading role in the dioxin emission concentration area, and the initial data sets of different clusters are divided into different clusters; S3, the optimal transformation coefficient λ is obtained; S4, the final model is established, and the optimal transformation obtained in step S3 The coefficient λ is used as the conversion coefficient of the dioxin emission data, and the converted dioxin toxicity equivalent is calculated according to the least square method and the online measurement of the chlorobenzene concentration x i Between the linear model coefficients, a predictive model is built. The method has few parameters and stable extrapolation performance, making it an ideal predictive model, moreover, the developed method is beneficial to realize on-line measurement of dioxin emissions in similar incineration processes with dioxin emissions, and feedback control to limit emissions .

Description

technical field [0001] The invention relates to the field of dioxin prediction, in particular to an online dioxin emission prediction method based on generation path clustering and Box-Cox transformation. Background technique [0002] The conventional method detects dioxin emissions from the incineration process by sampling flue gas, followed by more than a week of laboratory pretreatment and high-resolution gas chromatography / high-resolution mass spectrometry analysis. Because the conventional method includes experimental processes such as Soxhlet extraction, purification and concentration, the detection cost is high and the cycle is long. Therefore, the frequency of dioxin monitoring for the incineration process should be at least once a year. Traditional measurement methods are difficult to meet the public's requirements for real-time access to dioxin emissions. A long detection period cannot control the operating conditions of the incineration plant and the fuel compos...

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G06Q10/04G06K9/62G06Q10/06G06Q50/26
CPCG06Q10/04G06Q10/06393G06Q50/26G06F18/23
Inventor 陆胜勇熊世剑李晓东彭亚旗严建华
Owner ZHEJIANG UNIV
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