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Preparation method and application of adsorbent

A technology of adsorbent and pore-forming agent, which is applied in the field of preparation of SF6 and its derivative toxic gas protection adsorbents, can solve the problem that the adsorption capacity cannot meet the adsorption of various types of toxic gases, the inability to adsorb derived toxic gases, and the poisoning of staff. problem, to achieve the effect of wide adsorption range, fast adsorption rate and enhanced adsorption capacity

Active Publication Date: 2020-11-13
STATE GRID HUNAN ELECTRIC POWER +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The adsorption capacity of the existing protective equipment adsorbent cannot meet the adsorption of various types of toxic gases, so it cannot absorb all derivative toxic gases, and there is a possibility of staff poisoning, especially when inspecting and repairing equipment that has suffered serious failures

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] a SF 6 The preparation method of the adsorbent for derivation gas protection thereof comprises the following steps:

[0029] (1) Mix 1g of methyl cellulose with 9g of kaolin (SiO 2 and Al 2 o 3 The total content is greater than 99%) and fully mixed with 10ml of deionized water, and then granulated (with a particle size of 1 mm to 1.5 mm) to obtain a green body.

[0030] (2) Dry the green body at 110°C, then roast at 800°C for 1 hour, then age in 10mol / L NaOH solution for 4 hours (ageing temperature is 50°C), and then raise the temperature to 90°C After crystallization for 3 hours, the crystallized product was finally washed with deionized water until the pH was 7.5, and dried to obtain the final synthesized product as a support.

[0031] (3) The mass concentration is 8% Zn (NO 3 ) 2 The solution was mixed with the product synthesized in step (2) in equal volumes, then ultrasonically vibrated for 8 hours, then dried at 105° C. for 2 hours, and finally calcined at 6...

Embodiment 2

[0036] a SF 6 The preparation method of the adsorbent for derivation gas protection thereof comprises the following steps:

[0037] (1) Mix 1.5g of methyl cellulose with 9g of kaolin (SiO 2 and Al 2 o 3 The total content is greater than 99%), fully mixed with 10ml of deionized water, and then granulated and shaped (the particle size of the calcined body is 1mm-1.5mm) to obtain a green body.

[0038] (2) Dry the green body at 110°C, then calcinate at 750°C for 2h, then age in 8mol / L NaOH solution for 3h (aging temperature: 60°C), then raise the temperature to 95°C for 2h to crystallize, Finally, the crystalline product was washed with deionized water until the pH was 8.0, and dried to obtain the final synthesized product as a carrier.

[0039] (3) The concentration is 15% Zn (NO 3 ) 2 It was mixed with the product synthesized in step (2) in equal volume, then ultrasonically vibrated for 6 hours, then dried at 110°C for 2 hours, and finally calcined at 650°C for 3 hours to...

Embodiment 3

[0044] a SF 6 The preparation method of the adsorbent for derivation gas protection thereof comprises the following steps:

[0045] (1) Mix 1.2g methyl cellulose with 8.8g kaolin (SiO 2 and Al 2 o 3 The total content is greater than 99%) is fully mixed with 10ml of deionized water, and then granulated (with a particle size of 1 mm to 1.5 mm) to obtain a green body.

[0046] (2) Dry the green body at 110°C, then bake it at 780°C for 1.5h, then age it in 9mol / L NaOH solution for 2h (aging temperature 60°C), then raise the temperature to 95°C to crystallize After 3 h, the crystalline product was washed with deionized water until the pH was 8.0, and dried to obtain the synthesized product.

[0047] (3) The concentration is 20% Zn (NO 3 ) 2 The solution was mixed with the synthetic product prepared in step (1) in equal volumes, then ultrasonically vibrated for 7 hours, dried at 110°C for 2 hours, and finally calcined at 650°C for 4 hours to obtain a metal zinc modified adsorb...

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Abstract

The invention discloses a preparation method of an adsorbent. The preparation method comprises the following steps: (1) mixing a pore-forming agent, kaolin and water to prepare a carrier; (2) modifying the carrier by using a soluble zinc salt solution to obtain a metal zinc modified adsorbent; and (3) compounding a metal skeleton organic matter with the metal zinc adsorbent to obtain a metal skeleton organic matter and metal zinc composite modified adsorbent. The adsorbent is applied to protection of SF6 and derivative gas thereof. The obtained modified adsorption material also has the characteristics of strong adsorption capacity, high adsorption rate, wide adsorption range, large adsorption capacity and the like, adsorption of the SF6 and all toxic gas derivatives thereof is met, the adsorption efficiency of the SF6 and all toxic gas derivatives thereof is greater than 99%, and the protection time is greater than 15 hours.

Description

technical field [0001] The invention belongs to the field of adsorbents, in particular to a SF 6 The preparation method and application of the adsorbent for toxic gas protection derived from the same. Background technique [0002] Sulfur hexafluoride gas (SF 6 ) has good insulation and arc extinguishing properties, and is widely used as an insulating medium in insulating power equipment, such as high-voltage circuit breakers, high-voltage transformers, high-voltage switches, high-voltage transmission lines, gas-enclosed combined capacitors, and transformers. SF 6 Under the action of overheating, electric arc, electric spark and corona discharge, it will decompose, and its decomposition products may also react with trace moisture, electrodes and solid insulating materials in the equipment. The products are more complex, mainly including SO 2 , HF, H 2 S, CF 4 , CO, C 3 f 8 , SO 2 f 2 、SOF 2 , SF 4 、CS 2 , S 2 f 10 O and S 2 f 10 , and these gas derivatives are...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/22B01J20/30B01D53/02
CPCB01J20/226B01J20/12B01J20/0244B01D53/02B01D2257/204B01D2257/30
Inventor 魏加强龚尚昆万涛吴俊杰徐松刘奕奕胡旭
Owner STATE GRID HUNAN ELECTRIC POWER