The invention discloses a novel composite sludge activated carbon adsorbent which is characterized by being prepared from the following raw materials, by weight, 100-150 parts of sludge, 13-17 parts of corn straw, 15-24 parts of peanut shell, 10-15 parts of manganese ore powder, 30-50 parts of zinc chloride, 13-16 parts of magnesium silicate, 5-8 parts of silicon dioxide, 3-5 parts of polyvinyl alcohol, 3-5 parts of polyacrylamide, 6-9 parts of teflon powder, 5-7 parts of attapulgite powder, 7-9 parts of calcium sulphide and a proper amount of distilled water. with addition of the teflon powder, attapulgite powder and calcium sulphide, acidic and alkali resistance, bactericidal activity and adsorption capacity of the sludge activated carbon are greatly enhanced, and wear rate during the preparation process is reduced. The source of materials is wide, and cost is low. The preparation process is simple; production efficiency is high; and no secondary pollution is caused. The adsorbent is environmentally friendly, has a wide range of adsorption and is worthy of popularization.