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Environment-friendly PVC decorative color film and preparation method thereof

A PVC resin and color film technology, which is applied in the field of PVC film production, can solve the problems of retention time intra-batch color difference, film batch color difference, and no color difference can not be satisfied, and achieve the effects of low cost, reduced discoloration, and increased input-output rate

Pending Publication Date: 2020-12-11
CHANGZHOU BAIJIA NIANDAI FILM TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] With the improvement of environmental protection requirements, all raw materials are required to be non-toxic. The use of non-toxic calcium-zinc or low-toxic barium-zinc stabilized system and PVC semi-rigid film high temperature molding will easily lead to color difference in the film batch, which cannot meet the large orders of customers. No color difference in the batch Deficiencies in the requirements
The original technical solution is a composite barium-zinc stabilizer and epoxy ester mixed synergistic system, but when the production equipment fails briefly or other factors change the residence time of the material, the color difference within the batch will be caused

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] An environmentally friendly PVC decorative color film, comprising the following components by weight: 100 parts of PVC resin, 15 parts of DOTP, 5 parts of epoxy soybean oil, 2.2 parts of liquid barium zinc, 0.3 part of powdered barium zinc, and 0.6 part of methyl tin , 15 parts of superfine activated calcium, 1 part of coloring agent.

[0025] The preparation process of the environmental protection PVC decorative color film of above-mentioned embodiment 1 is as follows:

[0026] (1) Accurately weigh 100 parts of PVC resin, 15 parts of DOTP, 5 parts of epoxy soybean oil, 2.2 parts of liquid barium zinc, 0.3 parts of powdered barium zinc, 0.6 parts of methyl tin, and 15 parts of superfine activated calcium according to the above formula 1 part of coloring agent;

[0027] (2) Stir the above-mentioned components at a rate of 800 rpm for 12 minutes, then continue to stir at a rate of 200 rpm for 3 minutes, and cool to room temperature after stirring to obtain a mixed materi...

Embodiment 2

[0031] An environmentally friendly PVC decorative color film, comprising the following components by weight: 100 parts of PVC resin, 22 parts of DOTP, 5.5 parts of epoxy soybean oil, 2.3 parts of liquid barium zinc, 0.5 part of powdered barium zinc, and 0.7 part of methyl tin , 25 parts of superfine activated calcium, and 1.5 parts of coloring agent.

[0032] The preparation process of the environmental protection PVC decorative color film of above-mentioned embodiment 2 is as follows:

[0033] (1) Accurately weigh 100 parts of PVC resin, 22 parts of DOTP, 5.5 parts of epoxy soybean oil, 2.3 parts of liquid barium zinc, 0.5 parts of powdered barium zinc, 0.7 parts of methyl tin, and 25 parts of ultrafine activated calcium according to the above formula 1.5 parts of colorant;

[0034] (2) Stir the above-mentioned components at a rate of 700 rpm for 15 minutes, then continue to stir at a rate of 100 rpm for 5 minutes, and cool to room temperature after stirring to obtain a mixe...

Embodiment 3

[0038] An environmentally friendly PVC decorative color film, comprising the following components by weight: 100 parts of PVC resin, 24 parts of DOTP, 6 parts of epoxy soybean oil, 2 parts of liquid barium zinc, 0.4 part of powdered barium zinc, and 0.6 part of methyl tin , 30 parts of superfine activated calcium, 2 parts of coloring agent.

[0039] The preparation process of the environmental protection PVC decorative color film of above-mentioned embodiment 3 is as follows:

[0040] (1) Accurately weigh 100 parts of PVC resin, 24 parts of DOTP, 6 parts of epoxy soybean oil, 2 parts of liquid barium zinc, 0.4 parts of powdered barium zinc, 0.6 parts of methyl tin, and 30 parts of superfine activated calcium according to the above formula , 2 parts of colorant;

[0041] (2) Stir the above-mentioned components at a rate of 900 rpm for 10 minutes, then continue to stir at a rate of 150 rpm for 4 minutes, and cool to room temperature after stirring to obtain a mixed material;

...

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PUM

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Abstract

The invention discloses an environment-friendly PVC decorative color film and a preparation method thereof. The environment-friendly PVC decorative color film comprises the components in parts by weight: 100 parts of PVC resin, 14-24 parts of DOTP, 4-6 parts of epoxidized soybean oil, 2-2.6 parts of liquid barium and zinc, 0.3-0.5 part of powdery barium and zinc, 0.5-0.9 part of a stabilizer, 10-30 parts of superfine activated calcium and 1-2 parts of a coloring agent. The preparation comprises the steps: (1) weighing the components according to the formula; (2) stirring and mixing the components, and then cooling to obtain a mixed material; (3) plasticizing the mixed material, and then extruding; and (4) calendering the material extruded in the step (3), stretching, embossing, cooling andshaping, and finally packaging to obtain a finished product. By changing a mixed material formula system, the color stability of the product is improved, the first-pass yield of the finished productis ensured, the material loss is reduced, and the input-output rate is increased; the method has the advantages of mild preparation conditions, low requirements on equipment and low cost, and is suitable for industrial batch production.

Description

technical field [0001] The invention relates to the field of PVC film production, in particular to an environment-friendly PVC decorative color film and a preparation method thereof. Background technique [0002] Environmentally friendly color film is a new type of decorative material made of high molecular polymer (PVC), adding various additives, calendering, compounding and printing. It can be used with wood, plastic boards, aluminum boards, iron boards and other It is widely used in household appliances, audio surface decoration, interior decoration, interior decoration of airplanes, ships and trains, and can also be used for billboards and so on. It is characterized by realistic lines, which can completely imitate the appearance of any desired item to achieve the effect of "disgusting the real". It can be composited on uneven substrates to solve the problem that large-area curved surfaces are difficult to solve with ordinary printing technology. The surface of the envir...

Claims

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Application Information

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IPC IPC(8): C08L27/06C08L91/00C08K13/02C08K5/12C08K5/57C08K3/26C08J5/18
CPCC08J5/18C08J2327/06C08J2491/00C08K13/02C08K5/12C08K5/57C08K2003/265
Inventor 魏斌茹正伟伍秉还刘文泉陈宇辉
Owner CHANGZHOU BAIJIA NIANDAI FILM TECH CO LTD
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