Scale inhibition particle and preparation method and application thereof
A particle and scale-inhibiting technology, applied in chemical instruments and methods, earth-moving drilling, cleaning appliances, etc., can solve the problems of short dosing cycle, affecting production and efficiency, and difficult management, and achieve the effect of inhibiting scaling.
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[0057] A preparation method of antiscaling particles, comprising the following steps:
[0058] S1. Preparation of sustained-release core layer
[0059] First prepare slow-release core particles with a particle size of 1-3mm;
[0060] S2. Preparation of antiscaling particles
[0061] Put the slow-release core particles in the rolling ball machine, then spray the outer layer adhesive into the rolling ball machine, add solid scale inhibitor particles, and then add the outer layer cross-linking agent in the formulated amount until the particle diameter reaches 2~ 4mm, stop wrapping, and then dry at a temperature of 55~65°C for 24h~48h to obtain scale inhibitor particles with different release rates.
[0062] Further, the preparation of the S1 sustained-release core layer comprises the following steps:
[0063] S101. First modify the surface of the inorganic carrier with acid, then dry it at 105-115°C and make it into powder for later use;
[0064] S102. Add a liquid scale inhi...
Embodiment 1
[0072] A kind of antiscaling granule preparation material comprises:
[0073] Amino trimethylene phosphonic acid (ATMP solid powder) 500g
[0074] 2-Phospho-1,2,4-butane tricarboxylate (PBTCA liquid) 300g
[0075] Attapulgite 300g
[0076] Lignin 20g
[0077] Polyvinyl alcohol 400g
[0078] Boric acid 60g
[0079] The preparation steps of the anti-scaling particles described in this embodiment are as follows:
[0080] Step 1: Sustained-release core layer preparation
[0081] Use 3% HCl to modify the surface of attapulgite and then dry it. Add 300g of liquid scale inhibitor 2-phosphate-1,2 to 300g of attapulgite at 35°C and a stirring speed of 400r / min. 4-Butane tricarboxylate (PBTCA), keep stirring for 3 hours to fully mix the two; dry in an oven at 60°C for 24 hours, wait until the attapulgite is in a state of agglomeration and dispersibility, the adsorption is close to saturation, and crushed Machine pulverization (5min) into a dry powder with a diameter of micron.
...
Embodiment 2
[0086] A kind of antiscaling granule preparation material comprises:
[0087] Hydroxyethylidene diphosphonic acid (HEDP) 650g
[0088] Ethylenediaminetetramethylenephosphonic acid (EDTMPA) 450g
[0089] Attapulgite 450g
[0090] Lignin 150g
[0091] Polyvinyl alcohol 650g
[0092] Boric acid 130g
[0093] The preparation steps of the anti-scaling particles described in this embodiment are as follows:
[0094] Step 1: Sustained-release core layer preparation
[0095] Use 3% HCl to modify the surface of attapulgite and then dry it. Add 450g of liquid scale inhibitor ethylenediamine tetramethylene phosphonic acid ( EDTMPA), keep stirring for 3 hours to fully mix the two; dry in an oven at 60°C for 24 hours, when the attapulgite is in a state of agglomeration and dispersibility, the adsorption is close to saturation, and it is pulverized by a pulverizer (10min) into a diameter of Micron-sized dry powder.
[0096] Mix the attapulgite powder and 150g of lignin filler in a hi...
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