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Scale inhibition particle and preparation method and application thereof

A particle and scale-inhibiting technology, applied in chemical instruments and methods, earth-moving drilling, cleaning appliances, etc., can solve the problems of short dosing cycle, affecting production and efficiency, and difficult management, and achieve the effect of inhibiting scaling.

Active Publication Date: 2020-12-15
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] (1) Oil and gas wells have a large amount of fluid production. With the recovery of the production fluid, the added liquid scale inhibitor is easily carried out, and the effective protection period of the scale inhibitor is short;
[0004] (2) The liquid antiscalant adheres to the oil pipe wall, and the utilization rate of the agent is low
When dosing chemicals, due to the high labor intensity and short dosing cycle, the production and benefits are affected;
[0005] (3) The dosing of liquid antiscalants requires the use of ground equipment and facilities such as high-pressure liquid injection pumps, containers, and pump trucks, which makes management difficult
However, the concentrated burst release and short validity period of the scale inhibitor caused by the dissolution of the polymer are the main problems that need to be improved at present.

Method used

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  • Scale inhibition particle and preparation method and application thereof
  • Scale inhibition particle and preparation method and application thereof

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preparation example Construction

[0057] A preparation method of antiscaling particles, comprising the following steps:

[0058] S1. Preparation of sustained-release core layer

[0059] First prepare slow-release core particles with a particle size of 1-3mm;

[0060] S2. Preparation of antiscaling particles

[0061] Put the slow-release core particles in the rolling ball machine, then spray the outer layer adhesive into the rolling ball machine, add solid scale inhibitor particles, and then add the outer layer cross-linking agent in the formulated amount until the particle diameter reaches 2~ 4mm, stop wrapping, and then dry at a temperature of 55~65°C for 24h~48h to obtain scale inhibitor particles with different release rates.

[0062] Further, the preparation of the S1 sustained-release core layer comprises the following steps:

[0063] S101. First modify the surface of the inorganic carrier with acid, then dry it at 105-115°C and make it into powder for later use;

[0064] S102. Add a liquid scale inhi...

Embodiment 1

[0072] A kind of antiscaling granule preparation material comprises:

[0073] Amino trimethylene phosphonic acid (ATMP solid powder) 500g

[0074] 2-Phospho-1,2,4-butane tricarboxylate (PBTCA liquid) 300g

[0075] Attapulgite 300g

[0076] Lignin 20g

[0077] Polyvinyl alcohol 400g

[0078] Boric acid 60g

[0079] The preparation steps of the anti-scaling particles described in this embodiment are as follows:

[0080] Step 1: Sustained-release core layer preparation

[0081] Use 3% HCl to modify the surface of attapulgite and then dry it. Add 300g of liquid scale inhibitor 2-phosphate-1,2 to 300g of attapulgite at 35°C and a stirring speed of 400r / min. 4-Butane tricarboxylate (PBTCA), keep stirring for 3 hours to fully mix the two; dry in an oven at 60°C for 24 hours, wait until the attapulgite is in a state of agglomeration and dispersibility, the adsorption is close to saturation, and crushed Machine pulverization (5min) into a dry powder with a diameter of micron.

...

Embodiment 2

[0086] A kind of antiscaling granule preparation material comprises:

[0087] Hydroxyethylidene diphosphonic acid (HEDP) 650g

[0088] Ethylenediaminetetramethylenephosphonic acid (EDTMPA) 450g

[0089] Attapulgite 450g

[0090] Lignin 150g

[0091] Polyvinyl alcohol 650g

[0092] Boric acid 130g

[0093] The preparation steps of the anti-scaling particles described in this embodiment are as follows:

[0094] Step 1: Sustained-release core layer preparation

[0095] Use 3% HCl to modify the surface of attapulgite and then dry it. Add 450g of liquid scale inhibitor ethylenediamine tetramethylene phosphonic acid ( EDTMPA), keep stirring for 3 hours to fully mix the two; dry in an oven at 60°C for 24 hours, when the attapulgite is in a state of agglomeration and dispersibility, the adsorption is close to saturation, and it is pulverized by a pulverizer (10min) into a diameter of Micron-sized dry powder.

[0096] Mix the attapulgite powder and 150g of lignin filler in a hi...

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Abstract

The invention provides a scale inhibition particle and a preparation method and application thereof; the scale inhibition particle comprises a slow release core layer and a quick release outer layer,and the quick release outer layer wraps the slow release core layer. The slow release core layer comprises the following components, by mass: 30%-45% of a liquid scale inhibitor, 30%-45% of an inorganic carrier, 2%-15% of a filler, 10%-20% of a slow-release core layer adhesive and 1%-5% of a slow-release core layer cross-linking agent. And the quick release outer layer comprises the following components, by mass: 50%-65% of a solid scale inhibitor, 30%-45% of an outer-layer adhesive and 5-8% of an outer-layer cross-linking agent. According to the invention, a certain proportion of solid and liquid scale inhibitors are added into matrixes of the quick release layer and the slow release layer to control the release speed of the scale inhibitor, and after the prepared scale inhibitor productis added into a wellbore, the high-concentration scale inhibitor can be quickly released at the early stage to be chelated with scale forming ions in water, so that scaling is basically inhibited. Andthen the scale inhibitor with a certain concentration is slowly released to maintain the concentration of the agent in the wellbore so as to achieve the purpose of long-term scale prevention.

Description

technical field [0001] The invention belongs to the field of oilfield chemistry, and in particular relates to a scale-inhibiting granule and a preparation method and application thereof. Background technique [0002] At present, most oil fields in my country have entered the middle and late stages of oil development, and the water content in the produced fluid is relatively high, and some oil fields have a water content as high as 90%. With the increase of water content, scaling problems in wellbores follow one after another. Among the numerous antiscaling processes, adding liquid antiscalants to oil and gas wells is the most commonly used and most economical and effective antiscaling measure, but there are the following problems: [0003] (1) Oil and gas wells have a large amount of fluid production. With the recovery of the production fluid, the added liquid scale inhibitor is easily carried out, and the effective protection period of the scale inhibitor is short; [0004...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/52C09K8/528E21B37/06
CPCC09K8/528C09K8/52E21B37/06
Inventor 刘宁李琼玮戚建晶苑慧莹姜毅董俊刘爱华周佩杨会丽何淼
Owner PETROCHINA CO LTD