Scratch-resistant agent for highlight spraying-free PMMA and preparation method thereof

A scratch-resistant agent and spray-free technology, which is applied in the field of polymer materials, can solve the problems of poor compatibility, reduce the surface gloss of high-gloss materials, etc., achieve good compatibility, long-term excellent surface gloss, and improve scratch resistance performance effect

Inactive Publication Date: 2021-01-05
ZHEJIANG JAVA SPECIALTY CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Silicone is a commonly used scratch-resistant agent. Generally, the scratch-resistant performance of materials is improved by reducing the friction coefficient. Ordinary silicone-based scratch-resistant agents have poor compatibility with materials and will reduce the surface gloss of high-gloss materials.

Method used

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  • Scratch-resistant agent for highlight spraying-free PMMA and preparation method thereof
  • Scratch-resistant agent for highlight spraying-free PMMA and preparation method thereof
  • Scratch-resistant agent for highlight spraying-free PMMA and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A scratch-resistant agent for high-gloss spray-free PMMA, comprising the following components in parts by weight: 50 parts of nano-zirconia; 15 parts of modified polysiloxane; 35 parts of long-chain alkyl polysiloxane .

[0033] The preparation method includes the following steps: first weigh the modified polysiloxane and the long-chain alkyl polysiloxane in proportion, melt them in a melting tank at 100-120°C and mix them for 30 minutes, then add nano zirconium dioxide, stir and mix After 60 minutes, the mixed material was prepared; the mixed material was cooled by a steel belt fed with cooling water, then pulverized, and passed through a 6-mesh sieve to obtain a finished scratch-resistant agent.

[0034] A kind of PMMA composite material, in parts by weight, 3 parts of anti-scratch agents that embodiment 1 makes, 1 part of high-gloss black masterbatch, 0.3 part of antioxidant and Mitsubishi PMMA MF-001 are mixed homogeneously in mixer, then in Melting and blending ex...

Embodiment 2

[0036] A scratch-resistant agent for high-gloss spray-free PMMA, comprising the following components in parts by weight: 50 parts of nano-zirconia; 20 parts of modified polysiloxane; 30 parts of long-chain alkyl polysiloxane .

[0037] The preparation method includes the following steps: first weigh the modified polysiloxane and the long-chain alkyl polysiloxane in proportion, melt them in a melting tank at 100-120°C and mix them for 30 minutes, then add nano zirconium dioxide, stir and mix After 60 minutes, the mixed material was prepared; the mixed material was cooled by a steel belt fed with cooling water, then pulverized, and passed through a 6-mesh sieve to obtain a finished scratch-resistant agent.

[0038] A kind of PMMA composite material, in parts by weight, the anti-scratch agent that 3 parts of embodiment 2 are made, 1 part of high-gloss black masterbatch, 0.3 part of antioxidant and Mitsubishi PMMA MF-001 are mixed homogeneously in mixer, then in Melting and blend...

Embodiment 3

[0040] A scratch-resistant agent for high-gloss spray-free PMMA, comprising the following components in parts by weight: 40 parts of nano-zirconia; 20 parts of modified polysiloxane; 40 parts of long-chain alkyl polysiloxane .

[0041] The preparation method includes the following steps: first weigh the modified polysiloxane and the long-chain alkyl polysiloxane in proportion, melt them in a melting tank at 100-120°C and mix them for 30 minutes, then add nano zirconium dioxide, stir and mix After 60 minutes, the mixed material was prepared; the mixed material was cooled by a steel belt fed with cooling water, then pulverized, and passed through a 6-mesh sieve to obtain a finished scratch-resistant agent.

[0042] A kind of PMMA composite material, in parts by weight, the anti-scratch agent that 3 parts of embodiment 3 are made, 1 part of high-gloss black masterbatch, 0.3 part of antioxidant and Mitsubishi PMMA MF-001 are mixed homogeneously in mixer, then in Melting and blend...

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Abstract

The invention discloses a scratch-resistant agent for highlight spraying-free PMMA and a preparation method of the scratch-resistant agent. The scratch-resistant agent for highlight spraying-free PMMAcomprises the following components in parts by weight: 40-70 parts of nano zirconium dioxide, 10-30 parts of modified polysiloxane; and 20-50 parts of long-chain alkyl polysiloxane. The invention further discloses a scratch-resistant PMMA composite material. The scratch-resistant agent can effectively improve the scratch resistance of the PMMA surface, and has high long-acting stability, so thatthe workpiece maintains long-lasting excellent surface gloss, and in addition, other comprehensive properties such as demolding of PMMA can be effectively improved.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular to a scratch-resistant agent for high-gloss spray-free PMMA and a preparation method thereof. Background technique [0002] Polymethyl methacrylate (PMMA) is a highly transparent amorphous thermoplastic polymer. It is currently the best polymer transparent material with high mechanical strength and good weather resistance. It is widely used in optical materials, medicine, automobiles, electrical appliances, etc. field, but the surface hardness of PMMA is low, it is easy to be scratched by hard objects, rubbed and loses luster, and its scratch resistance is poor, which has a significant impact on the appearance of the workpiece. With the development of spray-free technology, high-gloss spray-free PMMA is more used in the surface decoration of products, such as automobile grilles, pillars and other parts, which have better aesthetics, so the requirements for surface scratch resistance...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/04C08L83/10C08K9/06C08K3/22C08L33/12
CPCC08L83/04C08L83/10C08K9/06C08K3/22C08L33/12C08K2201/011C08K2003/2244C08L2205/02C08L2205/03C08L2310/00
Inventor 徐力群刘飞彭文平任杰义贤富陈双彬邱里勇陈欣杰
Owner ZHEJIANG JAVA SPECIALTY CHEM CO LTD
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